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公开(公告)号：US5264878A
公开(公告)日：1993-11-23
申请号：US6085
申请日：1993-01-19
IPC分类号： C08F220/22 , C08F230/08 , C08F290/06 , G02B1/04 , G02C7/04
CPC分类号： G02B1/043 , C08F220/22 , C08F230/08 , C08F290/068
摘要： The present invention relates to novel polymers, to processes for the preparation thereof, to contact lenses consisting substantially of those polymers and to processes for the manufacture thereof and to the use of the novel polymers for the manufacture of contact lenses. The polymers according to the invention are especially the copolymerisation products of monomer mixtures comprising the following monomers:______________________________________ a) 20-60% siloxane monovinyl component b) 1-25% siloxane oligovinyl component c) 10-55% fluorine-containing vinyl component d) 3-30% hydrophobic vinyl component having a bulky hydrocarbon radical, e) 0-10% hydrophilic vinyl component f) 0-15% additional cross-linking vinyl component. ______________________________________ The novel polymers and the contact lenses made therefrom are distinguished by a high degree of hardness while at the same time being highly permeable to oxygen.
摘要翻译： 本发明涉及新型聚合物，其制备方法，基本上由这些聚合物组成的隐形眼镜及其制造方法以及用于制造隐形眼镜的新型聚合物的用途。 根据本发明的聚合物特别是包含以下单体的单体混合物的共聚产物：-a）20-60％硅氧烷单乙烯基组分-b）1-25％硅氧烷低聚乙烯基组分-c）10-55％含氟乙烯基 组分-d）具有大体积烃基的3-30％疏水性乙烯基组分，-e）0-10％亲水性乙烯基组分-f）0-15％额外的交联乙烯基组分。 - 由其制成的新型聚合物和隐形眼镜的特征在于高度的硬度，同时对氧具有高度可渗透性。
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公开(公告)号：US5196493A
公开(公告)日：1993-03-23
申请号：US691626
申请日：1991-04-25
IPC分类号： C08F220/18 , C08F20/10 , C08F20/22 , C08F30/08 , C08F220/22 , C08F230/08 , C08F290/06 , G02B1/04 , G02C7/04
CPC分类号： G02B1/043 , C08F220/22 , C08F230/08 , C08F290/068
摘要： The present invention relates to novel polymers, to processes for the preparation thereof, to contact lenses consisting substantially of those polymers and to processes for the manufacture thereof and to the use of the novel polymers for the manufacture of contact lenses. The polymers according to the invention are especially the copolymerisation products of monomer mixtures comprising the following monomers:a) 20-60% siloxane monovinyl componentb) 1-25% siloxane oligovinyl componentc) 10-55% fluorine-containing vinyl componentd) 3-30% hydrophobic vinyl component having a bulky hydrocarbon radical,e) 0-10% hydrophilic vinyl componentf) 0-15% additional cross-linking vinyl component.The novel polymers and the contact lenses made therefrom are distinguished by a high degree of hardness while at the same time being highly permeable to oxygen.
摘要翻译： 本发明涉及新型聚合物，其制备方法，基本上由这些聚合物组成的隐形眼镜及其制造方法以及用于制造隐形眼镜的新型聚合物的用途。 根据本发明的聚合物特别是包含以下单体的单体混合物的共聚产物：a）20-60％硅氧烷单乙烯基组分b）1-25％硅氧烷低聚乙烯基组分c）10-55％含氟乙烯基组分d） 3-30％具有大体积烃基的疏水乙烯基组分，e）0-10％亲水性乙烯基组分f）0-15％额外的交联乙烯基组分。 新型聚合物和由其制成的隐形眼镜的特征在于高度的硬度，同时对氧气具有高度透气性。
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公开(公告)号：US5408280A
公开(公告)日：1995-04-18
申请号：US805733
申请日：1991-12-09
摘要： The invention relates to a process for rendering contact lenses hydrophilic, which comprises treating a contact lens with a compound of formula IAr--Z--Ar' (I)wherein Ar and Ar' are each independently of the other an aromatic radical that may be substituted by lower alkoxy and/or by lower alkyl and wherein one of the radicals Ar and Ar' or both radicals Ar and Ar' contain one or more substituents X selected independently of one another from a polar functional group Y, lower alkyl substituted by a polar functional group Y, and lower alkoxy substituted by a polar functional group Y, and wherein Z is a divalent group that separates Ar and Ar' from each other by from one to six atoms. The invention relates also to contact lenses treated according to the invention and to the use of compounds of formula I in the process according to the invention.
摘要翻译： 本发明涉及一种使隐形眼镜亲水化的方法，其包括用式I Ar-Z-Ar'（I）化合物处理隐形眼镜，其中Ar和Ar'各自独立地为可以是芳族基团 被低级烷氧基和/或被低级烷基取代，并且其中一个基团Ar和Ar'或两个基团Ar和Ar'含有一个或多个从极性官能团Y彼此独立选择的取代基X，被 极性官能团Y和被极性官能团Y取代的低级烷氧基，其中Z是使Ar和Ar'彼此分开1至6个原子的二价基团。 本发明还涉及根据本发明处理的隐形眼镜和根据本发明的方法中式I化合物的用途。
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公开(公告)号：US5198477A
公开(公告)日：1993-03-30
申请号：US841920
申请日：1992-02-25
CPC分类号： G02B1/043
摘要： The invention relates to contact lenses made from a polymer comprising macrocycles that are made up of units of formula I--(--CR.sup.1 .dbd.CR.sup.2 --A--)-- (I)wherein A is alkylene or alkenylene each having from 3 to 10 carbon atoms and each of which may be substituted by one or more R.sup.3 radicals, each of R.sup.1 and R.sup.2, independently of the other, is hydrogen or lower alkyl, and R.sup.3 is lower alkyl, fluorinated lower alkyl or a siloxane radical.They exhibit a combination of a high degree of hardness and oxygen permeability. They can be produced in an especially advantageous manner, that is to say by hot compression moulding.
摘要翻译： 本发明涉及由包含大环的聚合物制成的隐形眼镜，其由式I - （ - CR1 = CR2-A - ） - （I）单元组成，其中A为具有3至10个碳原子的亚烷基或亚烯基， 其各自可被一个或多个R 3基团取代，R 1和R 2各自独立地为氢或低级烷基，R 3为低级烷基，氟化低级烷基或硅氧烷基。 它们表现出高硬度和透氧性的组合。 它们可以以特别有利的方式制造，也就是说通过热压缩成型。
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