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公开(公告)号：US20180044514A1
公开(公告)日：2018-02-15
申请号：US15651323
申请日：2017-07-17
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Alexander I. Norman , Gregory K. Hall , John R. Hagadorn , Andy H. Tsou , Peijun Jiang , Ying Ying Sun , Sarah J. Mattler , Arturo Leyva
IPC: C08L23/16 , C08F210/16
CPC classification number: C08L23/16 , C08F210/16 , C08F2500/01 , C08F2500/02 , C08L23/14 , C08L2205/025 , C08F4/64148 , C08F4/65925 , C08F210/06 , C08F2500/12 , C08F2500/15
Abstract: Provided is a composition having 70 wt % to 90 wt % of a first propylene-olefin copolymer component having an ethylene content of 15 to 21 wt %; and 10 wt % to 30 wt % of a second propylene-olefin copolymer component having an ethylene content of 6 to 10 wt %; wherein the weight average molecular weight of the first component is 250,000 to 1,780,000 g/mol higher than the weight average molecular weight of the second component; wherein the reactivity ratio product of the first component is less than 0.75; wherein the reactivity ratio product of the second component is greater than or equal to 0.75.
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公开(公告)号：US10787564B2
公开(公告)日：2020-09-29
申请号：US16209686
申请日：2018-12-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Gregory K. Hall , Stefan B. Ohlsson , Yong Yang
Abstract: Described is a polyethylene composition comprising at least one polyethylene having a crystallinity of less than 60, or 55, or 50% and within a range from 0.2 wt % to 15 wt % of cyclic-olefin copolymer and within a range from 0.2 wt % to 15 wt % of hydrocarbon resin, by weight of the polyethylene composition. The polyethylene compositions can be formed into useful articles such as films and injection molded and thermoformed articles.
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Patent Agency Ranking
3.发明申请Process of Making Crosslinked Polyolefin Polymer Blends and Compositions Prepared Thereof 有权制备交联聚烯烃聚合物共混物和组合物的方法公开(公告)号：US20160090452A1
公开(公告)日：2016-03-31
申请号：US14961997
申请日：2015-12-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Sunny Jacob , Michael J. Goncy , Gregory K. Hall
CPC classification number: C08L51/04 , C08F255/06 , C08J3/246 , C08J2323/16 , C08J2351/06 , C08J2423/16 , C08L2205/025 , C08F210/02 , C08F210/06 , C08F236/20 , C08L23/12
Abstract: Provided herein is a process for making a grafted cross-linked polymer blend, by polymerizing a first and second polymer solution (each having 75 to 99 wt % propylene-derived units, 1 to 25 wt % ethylene-derived units, and 0.05 to 6 wt % diene-derived units); combining the first and second polymer solution to produce a polymer blend solution; removing solvent from the polymer blend solution to produce a polymer blend; mixing the polymer blend with a coagent and a vinyl-terminated silane compound; subjecting the polymer blend to electron beam irradiation to grafting the vinyl-terminated silane compound to either or both of the first polymer and the second polymer to form a grafted polymer blend; and moisture curing the grafted polymer blend to form a grafted cross-linked polymer blend, wherein the grafted cross-linked polymer blend is substantially free of peroxide.
Abstract translation: 本文提供了通过聚合第一和第二聚合物溶液（各自具有75至99重量％的丙烯衍生的单元，1至25重量％的来自乙烯的单元和0.05至6个）的方法制备接枝交联的聚合物共混物的方法 重量％二烯衍生的单元）; 组合第一和第二聚合物溶液以产生聚合物共混物溶液; 从聚合物共混物溶液中除去溶剂以产生聚合物共混物; 将聚合物共混物与助洗剂和乙烯基封端的硅烷化合物混合; 将聚合物共混物进行电子束照射以将乙烯基封端的硅烷化合物接枝到第一聚合物和第二聚合物中的任一种或两者以形成接枝聚合物共混物; 并湿润固化接枝聚合物共混物以形成接枝的交联聚合物共混物，其中接枝的交联聚合物共混物基本上不含过氧化物。
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4.发明授权Process of making crosslinked polyolefin polymer blends and compositions prepared thereof 有权制备交联聚烯烃聚合物共混物及其制备的组合物的方法公开(公告)号：US09487653B2
公开(公告)日：2016-11-08
申请号：US14961997
申请日：2015-12-08
Applicant: ExxonMobil Chemical Patents Inc. , Keli Jackson
Inventor： Sunny Jacob , Michael J. Goncy , Gregory K. Hall
CPC classification number: C08L51/04 , C08F255/06 , C08J3/246 , C08J2323/16 , C08J2351/06 , C08J2423/16 , C08L2205/025 , C08F210/02 , C08F210/06 , C08F236/20 , C08L23/12
Abstract: Provided herein is a process for making a grafted cross-linked polymer blend, by polymerizing a first and second polymer solution (each having 75 to 99 wt % propylene-derived units, 1 to 25 wt % ethylene-derived units, and 0.05 to 6 wt % diene-derived units); combining the first and second polymer solution to produce a polymer blend solution; removing solvent from the polymer blend solution to produce a polymer blend; mixing the polymer blend with a coagent and a vinyl-terminated silane compound; subjecting the polymer blend to electron beam irradiation to grafting the vinyl-terminated silane compound to either or both of the first polymer and the second polymer to form a grafted polymer blend; and moisture curing the grafted polymer blend to form a grafted cross-linked polymer blend, wherein the grafted cross-linked polymer blend is substantially free of peroxide.
Abstract translation: 本文提供了通过聚合第一和第二聚合物溶液（各自具有75至99重量％的丙烯衍生的单元，1至25重量％的来自乙烯的单元和0.05至6个）的方法制备接枝交联的聚合物共混物的方法 重量％二烯衍生的单元）; 组合第一和第二聚合物溶液以产生聚合物共混物溶液; 从聚合物共混物溶液中除去溶剂以产生聚合物共混物; 将聚合物共混物与助洗剂和乙烯基封端的硅烷化合物混合; 将聚合物共混物进行电子束照射以将乙烯基封端的硅烷化合物接枝到第一聚合物和第二聚合物中的任一种或两者以形成接枝聚合物共混物; 并湿润固化接枝聚合物共混物以形成接枝的交联聚合物共混物，其中接枝的交联聚合物共混物基本上不含过氧化物。
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公开(公告)号：US11441023B2
公开(公告)日：2022-09-13
申请号：US16344692
申请日：2018-04-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Keran Chen , Yong Yang , Ling Ge , Xiao-Chuan Wang , Zhen-Yu Zhu , LeiLei Ma , Xin Hao Cai , Gregory K. Hall , Caiguo Gong , Jean-Marc C. De Koninck , Robert J. Wittenbrink
Abstract: A film, preferably, a multi-layered film, including a polymer composition, wherein the polymer composition includes: within a range from 1 wt % to 25 wt % of a cyclic olefin copolymer based on the weight of the polymer composition, and within a range from 75 wt % to 99 wt % (the remainder of material) of a polyethylene based on the weight of the polymer composition, wherein the cyclic olefin copolymer has a glass transition temperature (T.sub.g) of at least 80.degree. C. The films may be used in shrink packaging application.
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公开(公告)号：US20190211192A1
公开(公告)日：2019-07-11
申请号：US16209686
申请日：2018-12-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Gregory K. Hall , Stefan B. Ohlsson , Yong Yang
Abstract: Described is a polyethylene composition comprising at least one polyethylene having a crystallinity of less than 60, or 55, or 50% and within a range from 0.2 wt % to 15 wt % of cyclic-olefin copolymer and within a range from 0.2 wt % to 15 wt % of hydrocarbon resin, by weight of the polyethylene composition. The polyethylene compositions can be formed into useful articles such as films and injection molded and thermoformed articles.
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公开(公告)号：US20210363336A1
公开(公告)日：2021-11-25
申请号：US16344692
申请日：2018-04-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Keran Chen , Yong Yang , Ling Ge , Xiao-Chuan Wang , Zhen-Yu Zhu , LeiLei Ma , Xin Hao Cai , Gregory K. Hall , Caiguo Gong , Jean-Marc C. De Koninck , Robert J. Wittenbrink
Abstract: A film, preferably, a multi-layered film, comprising a polymer composition, wherein the polymer composition comprises: within a range from 1 wt % to 25 wt % of a cyclic olefin copolymer based on the weight of the polymer composition, and within a range from 75 wt % to 99 wt % (the remainder of material) of a polyethylene based on the weight of the polymer composition, wherein the cyclic olefin copolymer has a glass transition temperature (Tg) of at least 80° C. The films may be used in shrink packaging application.
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