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公开(公告)号:US20230097049A1
公开(公告)日:2023-03-30
申请号:US17782732
申请日:2020-12-11
Applicant: ExxonMobil Chemical Patents Inc,
Inventor: Rue Xie , Krishnan Arantha Narays and Iyer , Shanshan Zhang , Iverel Gerard E. Tumbaga , Ying Ying Sun , Antonios K. Doufas , Peijun Jiang , Jun Shi , Narayanaswami Dharmarajan
IPC: C08L23/16
Abstract: The present disclosure provides compositions comprising propylene-based elastomer, articles thereof, and methods thereof. In at least one embodiment, a composition includes a propylene-based elastomer having an Mw of about 300,000 g/mol to about 600,000 g/mol and a melt flow rate of less than about 3 g/10 min, according to ASTM D-1238 (2.16 kg weight @ 230° C.). The composition includes a thermoplastic resin. In at least one embodiment, a roofing material includes a membrane. The membrane includes a composition. The composition includes a propylene-based elastomer having an Mw of about 300,000 g/mol to about 600,000 g/mol and a melt flow rate of less than about 3 g/10 min, according to ASTM D-1238 (2.16 kg weight @ 230° C.). The roofing material further includes a base material adhered to the membrane or affixed to the membrane.
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公开(公告)号:US10344152B2
公开(公告)日:2019-07-09
申请号:US15551838
申请日:2015-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Xin Chen , Ying Ying Sun , Yi Ping Ni , Pei Te Bao , Li Yuan , Jie Hui Xu
Abstract: The present invention is related to a propylene-based injection molded composition made from a polymer blend comprising from 45 to 85 wt % of a polymer blend modifier having a weight average molecular weight of 10,000 to 100,000 g/mole and from 15 to 55 wt % of a propylene-based elastomer having a weight average molecular weight of from 100,000 to 300,000 g/mole, where the weight percent of the polymer blend modifier and the propylene-based elastomer are based on the total weight of the polymer blend. The polymer blend modifier comprises a first propylene-based polymer and a second propylene-based polymer, where the first and second propylene-based polymers are different and are individually selected from a homopolymer of propylene or a copolymer of propylene and ethylene or a C4 to C10 alpha-olefin.
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公开(公告)号:US20180044514A1
公开(公告)日:2018-02-15
申请号:US15651323
申请日:2017-07-17
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Alexander I. Norman , Gregory K. Hall , John R. Hagadorn , Andy H. Tsou , Peijun Jiang , Ying Ying Sun , Sarah J. Mattler , Arturo Leyva
IPC: C08L23/16 , C08F210/16
CPC classification number: C08L23/16 , C08F210/16 , C08F2500/01 , C08F2500/02 , C08L23/14 , C08L2205/025 , C08F4/64148 , C08F4/65925 , C08F210/06 , C08F2500/12 , C08F2500/15
Abstract: Provided is a composition having 70 wt % to 90 wt % of a first propylene-olefin copolymer component having an ethylene content of 15 to 21 wt %; and 10 wt % to 30 wt % of a second propylene-olefin copolymer component having an ethylene content of 6 to 10 wt %; wherein the weight average molecular weight of the first component is 250,000 to 1,780,000 g/mol higher than the weight average molecular weight of the second component; wherein the reactivity ratio product of the first component is less than 0.75; wherein the reactivity ratio product of the second component is greater than or equal to 0.75.
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公开(公告)号:US20180030258A1
公开(公告)日:2018-02-01
申请号:US15551838
申请日:2015-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Xin Chen , Ying Ying Sun , Yi Ping Ni , Pei Te Bao , Li Yuan , Jie Hui Xu
CPC classification number: C08L23/14 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2314/06 , C08L23/10
Abstract: The present invention is related to a propylene-based injection molded composition made from a polymer blend comprising from 45 to 85 wt % of a polymer blend modifier having a weight average molecular weight of 10,000 to 100,000 g/mole and from 15 to 55 wt % of a propylene-based elastomer having a weight average molecular weight of from 100,000 to 300,000 g/mole, where the weight percent of the polymer blend modifier and the propylene-based elastomer are based on the total weight of the polymer blend. The polymer blend modifier comprises a first propylene-based polymer and a second propylene-based polymer, where the first and second propylene-based polymers are different and are individually selected from a homopolymer of propylene or a copolymer of propylene and ethylene or a C4 to C10 alpha-olefin.
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公开(公告)号:US20230118464A1
公开(公告)日:2023-04-20
申请号:US17905222
申请日:2021-03-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Shanshan Zhang , Peijun Jiang , Ying Ying Sun , Yujie Sheng , Saifudin M. Abubakar , Guangdi Chen , Hongchao Wang
IPC: C08F293/00 , C08L53/00
Abstract: The present disclosure relates to comb-block copolymers and methods thereof. In some embodiments, a copolymer includes a first block comprising an ethylene-propylene copolymer; and a second block comprising a high density polyethylene. In some embodiments, a polyethylene composition includes the copolymer and a branched vinyl/vinylidene-terminated high density polyethylene. In some embodiments, a process for producing a polyethylene composition includes polymerizing ethylene, at a temperature of at least 100° C., by introducing the ethylene to a first catalyst system having a first catalyst compound and a first activator to form a branched vinyl/vinylidene-terminated high density polyethylene. The process includes introducing the branched vinyl/vinylidene-terminated high density polyethylene to additional ethylene, propylene, and a second catalyst system having a second catalyst compound and a second activator. The process includes obtaining the polyethylene composition.
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公开(公告)号:US20230098921A1
公开(公告)日:2023-03-30
申请号:US17785152
申请日:2020-12-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Ying Ying Sun , Liang LI , Shanshan Zhang , Bin Zhao , Zhen Yu Gong , Yi Ping NI , Qingyun Qian , Peite BAO
Abstract: A composition comprising a C2-C12 polyalphaolefin and a functionalized propylene-based elastomer comprising from about 4 to about 25 wt % units derived from one or more C2 or C4-C12 alpha-olefins; a triad tacticity greater than about 90%; a heat of fusion less than about 75 J/g; and a plurality of oxygen containing functional groups selected from carboxylic acids, anhydrides, ketones, carbonates, esters, ethers, lactones, and combinations thereof. Compositions containing the functionalized propylene-based elastomer and methods to produce the same are also disclosed.
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公开(公告)号:US11186753B2
公开(公告)日:2021-11-30
申请号:US16334107
申请日:2017-08-01
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Wanli Wang , Michael W. Bednarik , Peite Bao , Yi Ping Ni , Ying Ying Sun
Abstract: A process of heat shrinking an article is provided. The process includes shaping a thermoplastic vulcanizate (TPV) into an article, the TPV having: a partially vulcanized rubber dispersed in a continuous thermoplastic phase, wherein more than 5 wt % of the rubber is extractable in boiling xylene, and wherein the thermoplastic phase comprises a thermoplastic resin having a Tm>110° C. and a propylene-based elastomer (PBE) having a Tm
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公开(公告)号:US10662325B2
公开(公告)日:2020-05-26
申请号:US15995351
申请日:2018-06-01
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Ying Ying Sun , Yi Ping Ni , Pei Te Bao , Yi Zhou Shi , Xiaoyun Wang
Abstract: The present invention relates to a polymer composition comprising a thermoplastic polyester and a propylene-based elastomer, wherein the propylene-based elastomer comprises propylene-derived units and 5 to 30 wt % of α-olefin-derived units, and has a melting temperature of less than 120° C. and a heat of fusion of less than 75 J/g.
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公开(公告)号:US20190256746A1
公开(公告)日:2019-08-22
申请号:US16334107
申请日:2017-08-01
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Wanli Wang , Michael W. Bednarik , Peite Bao , Yi Ping Ni , Ying Ying Sun
Abstract: A process of heat shrinking an article is provided. The process includes shaping a thermoplastic vulcanizate (TPV) into an article, the TPV having: a partially vulcanized rubber dispersed in a continuous thermoplastic phase, wherein more than 5 wt % of the rubber is extractable in boiling xylene, and wherein the thermoplastic phase comprises a thermoplastic resin having a Tm>110° C. and a propylene-based elastomer (PBE) having a Tm
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公开(公告)号:US20190016882A1
公开(公告)日:2019-01-17
申请号:US15995351
申请日:2018-06-01
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Ying Ying Sun , Yi Ping Ni , Pei Te Bao , Yi Zhou Shi , Xiaoyun Wang
CPC classification number: C08L67/02 , C08J3/005 , C08J5/18 , C08J2323/16 , C08J2367/02 , C08L23/16 , C08L67/00 , C08L2203/16 , C08L23/14
Abstract: The present invention relates to a polymer composition comprising a thermoplastic polyester and a propylene-based elastomer, wherein the propylene-based elastomer comprises propylene-derived units and 5 to 30 wt % of α-olefin-derived units, and has a melting temperature of less than 120° C. and a heat of fusion of less than 75 J/g.
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