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公开(公告)号:US11701645B2
公开(公告)日:2023-07-18
申请号:US17284636
申请日:2019-10-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Larry L. Iaccino , Jeremy W. Bedard , Xiaoying Bao , Andrew P. Palermo , Nitish Mittal , Maria Milina , Doron Levin , William R. Gunther , Wenyih F. Lai , Tilman W. Beutel
IPC: B01J29/44 , B01J6/00 , B01J8/02 , B01J29/46 , B01J37/00 , B01J37/02 , B01J37/04 , B01J37/08 , C07C5/373
CPC classification number: B01J29/44 , B01J6/002 , B01J8/0285 , B01J29/46 , B01J37/0009 , B01J37/0207 , B01J37/04 , B01J37/082 , C07C5/373 , C07C2529/44 , C07C2529/46
Abstract: A catalyst comprising a microporous crystalline metallosilicate having a Constraint Index of 12, or 10, or 8, or 6 or less, a binder, a Group 1 alkali metal or a compound thereof and/or a Group 2 alkaline earth metal or a compound thereof, a Group 10 metal or a compound thereof, and, optionally, a Group 11 metal or a compound thereof; wherein the catalyst is calcined in a first calcining step before the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof; and wherein the first calcining step includes heating the catalyst to first temperatures of greater than 500° C.; and wherein the catalyst is calcined in a second calcining step after the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof wherein the second calcining step includes heating the catalyst to temperatures of greater than 400° C.
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公开(公告)号:US20230365479A1
公开(公告)日:2023-11-16
申请号:US18044584
申请日:2021-09-01
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor: Eric D. Metzger , Ali A. Kheir , Maria Milina , Kathleen M. Keville
CPC classification number: C07C5/2708 , B01J29/40 , B01J35/1019 , B01J35/1023 , B01J2229/42 , C07C2529/40
Abstract: Processes for converting C8 aromatic hydrocarbons. In some embodiments, a process for converting a hydrocarbon feed that can include C8 aromatic hydrocarbons can include feeding the hydrocarbon feed into a conversion zone and contacting the hydrocarbon feed at least partly in a liquid phase with an isomerization catalyst composition in the conversion zone under conversion conditions to effect isomerization of at least a portion of the C8 aromatic hydrocarbons to produce a conversion product rich in para-xylene. In some embodiments, the isomerization catalyst composition can include a zeolite (preferably a ZSM-5 zeolite) that can have a silica (SiO2) to alumina (AI2O3) molar ratio of 10 to 100, a total surface area of 200 m2/g to 700 m2/g, a micropore surface area of 50 m2/g to 600 m2/g, and an external surface area of 55 m2/g to 550 m2/g.
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公开(公告)号:US20240268381A1
公开(公告)日:2024-08-15
申请号:US18561642
申请日:2022-05-17
Applicant: Nan HU , Maria MILINA , Chunzhao LI , Virginia VANCE , Anna TANCORRA , Aaron Eberle , ExxonMobil Chemical Patents Inc.
Inventor: Nan Hu , Maria Milina , Chunzhao Li , Virginia Vance , Anna Tancorra , Aaron Eberle
Abstract: Provided herein is an agrochemical composition suitable for use as an emulsifiable concentrate, comprising one or more active ingredients; one or more solvents selected from specific amides and esters; and optionally, one or more surfactants.
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公开(公告)号:US20210394163A1
公开(公告)日:2021-12-23
申请号:US17284636
申请日:2019-10-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Larry L. Iaccino , Jeremy W. Bedard , Xiaoying Bao , Andrew P. Palermo , Nitish Mittal , Maria Milina , Doron Levin , William R. Gunther , Wenyih F. Lai , Tilman W. Beutel
IPC: B01J29/44 , B01J29/46 , B01J37/08 , B01J37/04 , B01J37/00 , B01J37/02 , B01J6/00 , B01J8/02 , C07C5/373
Abstract: A catalyst comprising a microporous crystalline metallosilicate having a Constraint Index of 12, or 10, or 8, or 6 or less, a binder, a Group 1 alkali metal or a compound thereof and/or a Group 2 alkaline earth metal or a compound thereof, a Group 10 metal or a compound thereof, and, optionally, a Group 11 metal or a compound thereof; wherein the catalyst is calcined in a first calcining step before the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof; and wherein the first calcining step includes heating the catalyst to first temperatures of greater than 500° C.; and wherein the catalyst is calcined in a second calcining step after the addition of the Group 10 metal or compound thereof and optionally the Group 11 metal or compound thereof wherein the second calcining step includes heating the catalyst to temperatures of greater than 400° C.
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