Production of Olefin Dimers
    5.
    发明申请

    公开(公告)号:US20190002366A1

    公开(公告)日:2019-01-03

    申请号:US15948323

    申请日:2018-04-09

    IPC分类号: C07C2/32 B01J31/22

    摘要: A process for producing alpha-olefin dimers comprises contacting, at a temperature of 80° C. or more, a feedstock comprising at least one C8+ (linear) alpha-olefin with a catalyst system comprising activator and one or more catalyst compounds represented by the formula: where M is a Group 4 metal; n is 1, 2, or 3; RA is hydrogen or a C1 to C10 alkyl; each of R1, R2, R3, R4, R5, R6, R7, and R8 is independently selected from hydrogen and C1 to C10 alkyl; each X is independently selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, and a combination thereof, (two X's may form a part of a fused ring or a ring system), the contacting being conducted under conditions effective to oligomerize at least part of C8+ alpha-olefin to produce an oligomerized product containing at least 30 wt % of the alpha-olefin dimer and at least 80 mol % of vinylidene unsaturation, where the conversion of the alpha olefin is at least 10 wt %, based upon the weight of the alpha olefin monomer entering the reactor and the weight of dimer produced.

    Production of olefin dimers
    7.
    发明授权

    公开(公告)号:US10358397B2

    公开(公告)日:2019-07-23

    申请号:US15948323

    申请日:2018-04-09

    IPC分类号: C07C2/32 B01J31/22 C10G50/00

    摘要: A process for producing alpha-olefin dimers comprises contacting, at a temperature of 80° C. or more, a feedstock comprising at least one C8+ (linear) alpha-olefin with a catalyst system comprising activator and one or more catalyst compounds represented by the formula: where M is a Group 4 metal; n is 1, 2, or 3; RA is hydrogen or a C1 to C10 alkyl; each of R1, R2, R3, R4, R5, R6, R7, and R8 is independently selected from hydrogen and C1 to C10 alkyl; each X is independently selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, and a combination thereof, (two X's may form a part of a fused ring or a ring system), the contacting being conducted under conditions effective to oligomerize at least part of C8+ alpha-olefin to produce an oligomerized product containing at least 30 wt % of the alpha-olefin dimer and at least 80 mol % of vinylidene unsaturation, where the conversion of the alpha olefin is at least 10 wt %, based upon the weight of the alpha olefin monomer entering the reactor and the weight of dimer produced.