公开(公告)号：US20130123557A1

公开(公告)日：2013-05-16

申请号：US13652660

申请日：2012-10-16

Applicant: ExxonMobil Research and Engineering Company

Inventor： STEPHEN J. McCARTHY ,  GUANG CAO ,  PATRICIA A. BIELENBERG ,  Beau Waldrup

IPC: B01J29/83 ,  C07C1/22

CPC classification number: B01J29/40 ,  B01J21/04 ,  B01J29/00 ,  B01J29/83 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/1004 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/06 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  B82Y30/00 ,  B82Y40/00 ,  C01B39/54 ,  C07C1/20 ,  C07C1/22 ,  C07C1/24 ,  C07C2/864 ,  C07C41/09 ,  C10G3/49 ,  C10G2400/02 ,  C10G2400/04 ,  Y02P20/125 ,  Y02P30/20 ,  C07C43/043

Abstract: In a process for producing a phosphorus-modified zeolite catalyst, zeolite crystals can be formed into a shaped catalyst body either in the absence of a separate inorganic oxide binder or in the presence of a separate inorganic oxide binder that is substantially free of aluminum. After converting the zeolite crystals to the hydrogen form and removing any organic directing agent employed in the synthesis of the zeolite crystals, the shaped catalyst body can be treated with an aqueous solution of a phosphorus compound, and the treated catalyst body can be heated to remove the water and to convert the phosphorus compound to an oxide form.

Abstract translation: 在制备磷改性沸石催化剂的方法中，沸石晶体可以在不存在分开的无机氧化物粘合剂的情况下或在基本上不含铝的单独的无机氧化物粘合剂的存在下形成成型的催化剂体。 在将沸石晶体转化为氢形式并除去合成沸石晶体中的任何有机导向剂后，可以用磷化合物的水溶液处理成型的催化剂体，并且可以加热处理的催化剂体以除去 水并将磷化合物转化为氧化物形式。

公开(公告)号：US20130102824A1

公开(公告)日：2013-04-25

申请号：US13652681

申请日：2012-10-16

Applicant: ExxonMobil Research and Engineering Company

Inventor： TILMAN W. BEUTEL ,  STEPHEN J. McCARTHY ,  BEAU WALDRUP ,  MICHEL DAAGE ,  KARLTON J. HICKEY

IPC: B01J29/83 ,  C07C1/22

CPC classification number: B01J29/40 ,  B01J21/04 ,  B01J29/00 ,  B01J29/83 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/1004 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/06 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  B82Y30/00 ,  B82Y40/00 ,  C01B39/54 ,  C07C1/20 ,  C07C1/22 ,  C07C1/24 ,  C07C2/864 ,  C07C41/09 ,  C10G3/49 ,  C10G2400/02 ,  C10G2400/04 ,  Y02P20/125 ,  Y02P30/20 ,  C07C43/043

Abstract: A bound phosphorus-modified catalyst composition comprises a zeolite having a silica to alumina molar ratio of at least 40, phosphorus in an amount between about 0.1 wt % and about 3 wt % of the total catalyst composition, and a binder essentially free of aluminum. The bound catalyst composition can advantageously exhibit at least one of: (a) microporous surface area of at least 340 m2/g; (b) an alpha value after steaming in ˜100% steam for ˜96 hours at ˜1000° F. (˜538° C.) of at least 40; and (c) a coke deactivation rate constant ˜1.5×10−2 sec−1 measured at ˜120° C. and ˜60 torr (˜8 kPa) and (ii) a coke deactivation rate constant

Abstract translation: 结合的磷改性的催化剂组合物包含二氧化硅与氧化铝摩尔比为至少40的沸石，其量为总催化剂组合物的约0.1重量％至约3重量％的磷，以及基本上不含铝的粘合剂。 结合的催化剂组合物可以有利地显示以下至少一种：（a）至少340m 2 / g的微孔表面积; （b）约〜100°C（〜538°C）~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ （c）在约1000°F（〜538℃）〜100％蒸汽蒸煮约96小时后焦炭失活速率常数<0.05。 煅烧后的结合催化剂有利地还可以显示（i）在〜120℃和〜60托（〜8kPa）下测量的2,2-二甲基丁烷扩散系数>〜1.5×10-2秒-1和（ii） 焦炭失活速率常数<〜0.15。