公开(公告)号：US20180119045A1

公开(公告)日：2018-05-03

申请号：US15384443

申请日：2016-12-20

Applicant: ExxonMobil Research and Engineering Company

Inventor： Abhimanyu O. Patil ,  Satish Bodige ,  Stephen Zushma ,  Kyle G. Lewis ,  Mark P. Hagemeister

IPC: C10M129/70

CPC classification number: C10M129/70 ,  C10M105/34 ,  C10M2203/024 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2207/281 ,  C10M2207/2815 ,  C10M2207/2845 ,  C10N2220/022 ,  C10N2220/028 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2230/70 ,  C10N2230/74 ,  C10N2240/04 ,  C10N2240/10

Abstract: A composition including one or more monomethyl ester compounds represented by the formula: R1 is a monomethyl branched C15 to C19 alkyl group and R2 is an unsubstituted C2 to C30 linear alkyl group. The composition has a viscosity (Kv100) from 1 cSt to 10 cSt at 100° C. as determined by ASTM D445, a viscosity index (VI) from −100 to 300 as determined by ASTM D2270, a pour point from 0° C. to −50° C. as determined by ASTM D97, and a Noack volatility of no greater than 50 percent as determined by ASTM D5800. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of cold flow properties, thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the composition.

公开(公告)号：US09580571B2

公开(公告)日：2017-02-28

申请号：US14100694

申请日：2013-12-09

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Colle Karla Schall ,  Allen David Godwin ,  Diana S. Smirnova ,  Jorg Friedrich Wilhelm Weber ,  Stephen Zushma

IPC: C07C69/738 ,  C08K5/10 ,  C07C69/732 ,  C08K5/12 ,  C07C51/31 ,  C07C67/31 ,  C07C69/73 ,  C07C67/08

CPC classification number: C08K5/12 ,  C07C51/31 ,  C07C67/08 ,  C07C67/31 ,  C07C69/73 ,  C07C69/732 ,  C07C69/738 ,  C07C2602/10 ,  C08K5/10 ,  C07C59/84 ,  C07C59/86

Abstract: Provided is a process for making non-phthalate plasticizers, by acylating an aromatic compound with a succinic anhydride to form a keto-acid, and then esterifying the keto-acid with C4-C13 OXO-alcohols to form a plasticizer compound. The aromatic rings of the aromatic compound may also be optionally hydrogenated.

Abstract translation: 提供了制备非邻苯二甲酸酯增塑剂的方法，通过用琥珀酸酐酰化芳族化合物以形成酮酸，然后用C4-C13OXO-醇酯化酮酸以形成增塑剂化合物。 芳族化合物的芳环也可以任选氢化。

公开(公告)号：US09512296B2

公开(公告)日：2016-12-06

申请号：US14100768

申请日：2013-12-09

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Karla Schall Colle ,  Allen David Godwin ,  Diana S. Smirnova ,  Jorg Friedrich Wilhelm Weber ,  Stephen Zushma

IPC: C08K5/12 ,  C07C51/31 ,  C07C67/08 ,  C07C67/31 ,  C07C69/73 ,  C07C69/738 ,  C08K5/10 ,  C07C69/732

CPC classification number: C08K5/12 ,  C07C51/31 ,  C07C67/08 ,  C07C67/31 ,  C07C69/73 ,  C07C69/732 ,  C07C69/738 ,  C07C2602/10 ,  C08K5/10 ,  C07C59/84 ,  C07C59/86

Abstract: Provided is a process for making non-phthalate plasticizers, by acylating an aromatic compound with a succinic anhydride to form a keto-acid, and then esterifying the keto-acid with C4-C13 OXO-alcohols to form a plasticizer compound. The aromatic rings of the aromatic compound may also be optionally hydrogenated.

公开(公告)号：US20140179845A1

公开(公告)日：2014-06-26

申请号：US13723553

申请日：2012-12-21

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

Inventor： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Stephen Zushma

IPC: C07C67/08 ,  C07C69/017 ,  C07C69/76 ,  C07C69/753

CPC classification number: C07C69/76 ,  C07C69/24 ,  C07C69/753 ,  C07C2602/10 ,  C08K5/0016 ,  C08K5/10

Abstract: Provided are compounds and processes of making compounds of the formula: wherein x=4 to 8, R is H, C1 to C4 alkyl, —C(O)OR1 or —OC(O)R1, y=4 to 8, R′ is H, C1 to C4 alkyl, and at least one R′ is —C(O)OR1 or —OC(O)R1, wherein R1 is a branched C4 to C14 alkyl, and their use in polymer compositions.

Abstract translation: 提供下列化合物的化合物和方法：其中x = 4至8，R为H，C 1至C 4烷基，-C（O）OR 1或-OC（O）R 1，y = 4至8，R' 是H，C 1至C 4烷基，并且至少一个R'是-C（O）OR 1或-OC（O）R 1，其中R 1是支链C 4至C 14烷基，并且它们在聚合物组合物中的用途。

公开(公告)号：US20140100384A1

公开(公告)日：2014-04-10

申请号：US14100768

申请日：2013-12-09

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Colle Karla Schall ,  Allen David Godwin ,  Diana S. Smirnova ,  Jorg Friedrich Wilhelm Weber ,  Stephen Zushma

IPC: C08K5/12

CPC classification number: C08K5/12 ,  C07C51/31 ,  C07C67/08 ,  C07C67/31 ,  C07C69/73 ,  C07C69/732 ,  C07C69/738 ,  C07C2602/10 ,  C08K5/10 ,  C07C59/84 ,  C07C59/86

Abstract: Provided is a process for making non-phthalate plasticizers, by acylating an aromatic compound with a succinic anhydride to form a keto-acid, and then esterifying the keto-acid with C4-C13 OXO-alcohols to form a plasticizer compound. The aromatic rings of the aromatic compound may also be optionally hydrogenated.

Abstract translation: 提供了制备非邻苯二甲酸酯增塑剂的方法，通过用琥珀酸酐酰化芳族化合物以形成酮酸，然后用C4-C13OXO-醇酯化酮酸以形成增塑剂化合物。 芳族化合物的芳环也可以任选氢化。

公开(公告)号：US20130171385A1

公开(公告)日：2013-07-04

申请号：US13723513

申请日：2012-12-21

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

Inventor： Jihad Mohammed Dakka ,  Stephen Zushma ,  Edmund John Mozeleski ,  Diana S. Smirnova ,  Lisa Saunders Baugh ,  Allen David Godwin

IPC: C07C67/08 ,  C07C69/753 ,  C08K5/12

CPC classification number: C07C67/08 ,  C07C69/753 ,  C07C2602/42 ,  C08K5/12 ,  Y10T428/1334 ,  Y10T428/139 ,  Y10T442/2369

Abstract: Multi-esters of the formula: wherein each R1 is the hydrocarbon residue of a C4 to C13 OXO-alcohol averaging from 0.2 to 5.0 branches per residue, and R2 is hydrogen or an ester group, processes of making the multi-esters, use of the multi-esters as plasticizers, polymer compositions containing such plasticizers, and articles containing such plasticizers.

Abstract translation: 下式的多酯：其中每个R 1是C 4至C 13 O XO-醇的烃残基，平均每个残基0.2至5.0个支链，R2是氢或酯基，制备多酯的方法，使用 作为增塑剂的多酯，含有这种增塑剂的聚合物组合物和含有这种增塑剂的制品。

公开(公告)号：US10322991B2

公开(公告)日：2019-06-18

申请号：US15829060

申请日：2017-12-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Michael P. Lanci ,  Joshua W. Allen ,  Jarid M. Metz ,  Victor DeFlorio ,  Jihad M. Dakka ,  Bryan A. Patel ,  Michael Salciccioli ,  Michael W. Weber ,  Stephen Zushma

IPC: B01J31/04 ,  C07C25/13 ,  C07C47/23 ,  C07C51/16 ,  C07C57/30 ,  C07C67/05 ,  C07C67/08 ,  C07C51/265 ,  C07C63/331 ,  C07C63/333

Abstract: A process for selective oxidation of dimethyl-1,1′-biphenyl to form methyl-1,1′-biphenyl mono-carboxylic acid(s), comprising contacting a solution of dimethyl-1,1′-biphenyl in acetic acid solvent in the presence of a Co(II) acetate catalyst and air, and optionally adding a co-solvent, or adding sodium or potassium acetate, and oxidizing the dimethyl-1,1′-biphenyl under time and temperature conditions sufficient to form one or more methyl-1,1′-biphenyl mono-carboxylic acid(s). The mono-carboxylic acids are advantageously isolated and esterified to form biphenyl mono-esters for use as plasticizers.

公开(公告)号：US10287230B2

公开(公告)日：2019-05-14

申请号：US15829008

申请日：2017-12-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Michael P. Lanci ,  Joshua W. Allen ,  Jarid M. Metz ,  Victor DeFlorio ,  Jihad M. Dakka ,  Bryan A. Patel ,  Michael Salciccioli ,  Michael W. Weber ,  Stephen Zushma

IPC: C07C57/30 ,  C07C67/05 ,  C07C25/13 ,  C07C47/23 ,  B01J31/04 ,  C07C51/265 ,  C07C51/16 ,  C07C67/08

Abstract: A process for selective oxidation of dimethyl-1,1′-biphenyl(s) to form methyl-1,1′-biphenyl mono-carboxylic acid(s), which can be esterified to form plasticizers, comprising contacting a solution of dimethyl-1,1′-biphenyl(s) in acetic acid in the presence of an oxidation catalyst and air under time and temperature conditions sufficient to oxidize the dimethyl-1,1′-biphenyl(s) into one or more methyl-1,1′-biphenyl mono-carboxylic acid(s) products, conducting at least one of (i) adding an antisolvent, or (ii) optimizing a total conversion of dimethyl-1,1′-biphenyl(s) by oxidation based upon a molar ratio of dimethyl-1,1′-biphenyl isomers, or (iii) precipitating the methyl-1,1′-biphenyl mono-carboxylic acid(s) products by lowering the temperature, or (iv) decreasing the oxidation reaction temperature to enhance conversion of aldehydes over methyl functional groups, so as to limit over-oxidation of the dimethyl-1,1′-biphenyl(s), wherein the oxidation reaction is conducted in the absence of bromide-containing catalysts.

公开(公告)号：US10233403B2

公开(公告)日：2019-03-19

申请号：US15384443

申请日：2016-12-20

Applicant: ExxonMobil Research and Engineering Company

Inventor： Abhimanyu O. Patil ,  Satish Bodige ,  Stephen Zushma ,  Kyle G. Lewis ,  Mark P. Hagemeister

IPC: C10M129/70 ,  C10M105/34

Abstract: A composition including one or more monomethyl ester compounds represented by the formula: R1 is a monomethyl branched C15 to C19 alkyl group and R2 is an unsubstituted C2 to C30 linear alkyl group. The composition has a viscosity (Kv100) from 1 cSt to 10 cSt at 100° C. as determined by ASTM D445, a viscosity index (VI) from −100 to 300 as determined by ASTM D2270, a pour point from 0° C. to −50° C. as determined by ASTM D97, and a Noack volatility of no greater than 50 percent as determined by ASTM D5800. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of cold flow properties, thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the composition.

公开(公告)号：US09422227B2

公开(公告)日：2016-08-23

申请号：US13723553

申请日：2012-12-21

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Stephen Zushma

IPC: C07C69/76 ,  C07C69/753 ,  C07C69/24 ,  C08K5/10 ,  C08K5/00

CPC classification number: C07C69/76 ,  C07C69/24 ,  C07C69/753 ,  C07C2602/10 ,  C08K5/0016 ,  C08K5/10

Abstract: Provided are compounds and processes of making compounds of the formula: wherein x=4 to 8, R is H, C1 to C4 alkyl, —C(O)OR1 or —OC(O)R1, y=4 to 8, R′ is H, C1 to C4 alkyl, and at least one R′ is —C(O)OR1 or —OC(O)R1, wherein R1 is a branched C4 to C14 alkyl, and their use in polymer compositions.

Abstract translation: 提供下列化合物的化合物和方法：其中x = 4至8，R为H，C 1至C 4烷基，-C（O）OR 1或-OC（O）R 1，y = 4至8，R' 是H，C 1至C 4烷基，并且至少一个R'是-C（O）OR 1或-OC（O）R 1，其中R 1是支链C 4至C 14烷基，并且它们在聚合物组合物中的用途。