公开(公告)号：US11926795B2

公开(公告)日：2024-03-12

申请号：US17496592

申请日：2021-10-07

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Changmin Chun ,  Wesley Sattler ,  Joseph E. Gatt ,  Keith R. Hajkowski ,  Everett J. O'Neal ,  William R. Gunther ,  Anastasios Skoulidas

IPC: C01B3/38 ,  B01J8/00 ,  B01J21/04 ,  B01J23/00 ,  B01J23/10 ,  B01J23/46 ,  B01J23/755 ,  B01J29/74 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  B01J38/12 ,  C01B3/40 ,  C10G11/04 ,  C10G11/22

CPC classification number: C10G11/04 ,  B01J8/008 ,  B01J21/04 ,  B01J23/002 ,  B01J23/10 ,  B01J23/464 ,  B01J23/755 ,  B01J29/74 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/038 ,  B01J37/04 ,  B01J37/082 ,  B01J38/12 ,  C01B3/382 ,  C01B3/384 ,  C01B3/40 ,  C10G11/22 ,  B01J2208/00017 ,  B01J2208/00548 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1058 ,  C01B2203/1064 ,  C10G2300/70

Abstract: Catalyst systems are provided for reforming of hydrocarbons, along with methods for using such catalyst systems. The catalyst systems can be deposited or otherwise coated on a surface or structure, such as a monolith, to achieve improved activity and/or structural stability. The metal oxide support layer can correspond to a thermally stable metal oxide support layer, such as a metal oxide support layer that is thermally phase stable at temperatures of 800° C. to 1600° C. The catalyst systems can be beneficial for use in cyclical reaction environments, such as reverse flow reactors or other types of reactors that are operated using flows in opposing directions and different times within a reaction cycle.

公开(公告)号：US11859133B2

公开(公告)日：2024-01-02

申请号：US17496644

申请日：2021-10-07

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Wesley Sattler ,  Keith R. Hajkowski ,  Changmin Chun ,  Partha Nandi ,  Vera Grankina ,  Joseph E. Gatt ,  Ning Ma ,  Anastasios Skoulidas ,  William R. Gunther ,  Everett J. O'Neal

IPC: C10G11/04 ,  C10G11/22 ,  B01J35/04 ,  B01J21/04 ,  B01J23/755 ,  B01J38/12 ,  B01J8/00 ,  B01J23/00 ,  B01J23/10 ,  B01J23/46 ,  B01J29/74 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C01B3/38 ,  C01B3/40

CPC classification number: C10G11/04 ,  B01J8/008 ,  B01J21/04 ,  B01J23/002 ,  B01J23/10 ,  B01J23/464 ,  B01J23/755 ,  B01J29/74 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/038 ,  B01J37/04 ,  B01J37/082 ,  B01J38/12 ,  C01B3/382 ,  C01B3/384 ,  C01B3/40 ,  C10G11/22 ,  B01J2208/00017 ,  B01J2208/00548 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1058 ,  C01B2203/1064 ,  C10G2300/70

Abstract: Systems and methods are provided for using size-reversing materials in vessels where direct heating is used to at least partially provide heat for reforming reactions under cyclic reforming conditions. An example of a size-reversing material is the combination of NiO and Al2O3. It has been discovered that size-reversing materials can undergo a phase transition that can assist with re-dispersion of metal at elevated temperatures. This can assist with maintaining catalytic activity for reforming over longer time periods in the presence of cyclic reforming conditions.