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公开(公告)号：US11325106B2
公开(公告)日：2022-05-10
申请号：US16512688
申请日：2019-07-16
IPC分类号： B01J21/04 , B01J21/06 , B01J21/08 , B01J21/10 , B01J21/12 , B01J21/14 , B01J23/70 , B01J23/72 , B01J23/74 , B01J23/75 , B01J23/755 , B01J23/78 , B01J23/83 , B01J23/86 , B01J23/889 , B01J35/00 , B01J35/04 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/14 , B01J37/16 , C10G35/06 , C10J3/72
摘要： Ceramic compositions with catalytic activity are provided, along with methods for using such catalytic ceramic compositions. The ceramic compositions correspond to compositions that can acquire increased catalytic activity by cyclic exposure of the ceramic composition to reducing and oxidizing environments at a sufficiently elevated temperature. The ceramic compositions can be beneficial for use as catalysts in reaction environments involving swings of temperature and/or pressure conditions, such as a reverse flow reaction environment. Based on cyclic exposure to oxidizing and reducing conditions, the surface of the ceramic composition can be converted from a substantially fully oxidized state to various states including at least some dopant metal particles supported on a structural oxide surface.
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公开(公告)号：US11859133B2
公开(公告)日：2024-01-02
申请号：US17496644
申请日：2021-10-07
发明人： Wesley Sattler , Keith R. Hajkowski , Changmin Chun , Partha Nandi , Vera Grankina , Joseph E. Gatt , Ning Ma , Anastasios Skoulidas , William R. Gunther , Everett J. O'Neal
IPC分类号： C10G11/04 , C10G11/22 , B01J35/04 , B01J21/04 , B01J23/755 , B01J38/12 , B01J8/00 , B01J23/00 , B01J23/10 , B01J23/46 , B01J29/74 , B01J35/00 , B01J35/10 , B01J37/03 , B01J37/04 , B01J37/08 , C01B3/38 , C01B3/40
CPC分类号： C10G11/04 , B01J8/008 , B01J21/04 , B01J23/002 , B01J23/10 , B01J23/464 , B01J23/755 , B01J29/74 , B01J35/0006 , B01J35/04 , B01J35/1009 , B01J35/1014 , B01J37/038 , B01J37/04 , B01J37/082 , B01J38/12 , C01B3/382 , C01B3/384 , C01B3/40 , C10G11/22 , B01J2208/00017 , B01J2208/00548 , C01B2203/0233 , C01B2203/0811 , C01B2203/1058 , C01B2203/1064 , C10G2300/70
摘要： Systems and methods are provided for using size-reversing materials in vessels where direct heating is used to at least partially provide heat for reforming reactions under cyclic reforming conditions. An example of a size-reversing material is the combination of NiO and Al2O3. It has been discovered that size-reversing materials can undergo a phase transition that can assist with re-dispersion of metal at elevated temperatures. This can assist with maintaining catalytic activity for reforming over longer time periods in the presence of cyclic reforming conditions.
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公开(公告)号：US20240116817A1
公开(公告)日：2024-04-11
申请号：US18481377
申请日：2023-10-05
CPC分类号： C04B35/10 , B01J23/755 , B01J35/04 , C01B3/26 , C01B3/382 , C01B3/40 , C04B38/0006 , C04B38/0051 , C04B38/0067 , C01B2203/1082 , C01B2203/1604 , C01B2203/1614 , C04B2235/3217 , C04B2235/3418
摘要： Ceramic monolith compositions are provided with improved stability under reaction conditions involving elevated temperatures. Such monoliths can be used, for example, in reverse flow reactors under high temperature reforming conditions, where the interior components of the reaction zone can be exposed to average temperatures of 1000° C. or higher while also being exposed to rapid oscillations in temperature of 100° C. or more in the presence of alternating oxidizing and reducing chemistries. The ceramic monolith compositions can be composed of materials that have improved ability to withstand conditions in severe reaction environments. Additionally or alternately, the ceramic monolith compositions can have structural features that reduce or minimize the tendency for the monolith to suffer structural failure under the conditions in severe reaction environments.
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公开(公告)号：US11926795B2
公开(公告)日：2024-03-12
申请号：US17496592
申请日：2021-10-07
发明人： Changmin Chun , Wesley Sattler , Joseph E. Gatt , Keith R. Hajkowski , Everett J. O'Neal , William R. Gunther , Anastasios Skoulidas
IPC分类号： C01B3/38 , B01J8/00 , B01J21/04 , B01J23/00 , B01J23/10 , B01J23/46 , B01J23/755 , B01J29/74 , B01J35/00 , B01J35/04 , B01J35/10 , B01J37/03 , B01J37/04 , B01J37/08 , B01J38/12 , C01B3/40 , C10G11/04 , C10G11/22
CPC分类号： C10G11/04 , B01J8/008 , B01J21/04 , B01J23/002 , B01J23/10 , B01J23/464 , B01J23/755 , B01J29/74 , B01J35/0006 , B01J35/04 , B01J35/1009 , B01J35/1014 , B01J37/038 , B01J37/04 , B01J37/082 , B01J38/12 , C01B3/382 , C01B3/384 , C01B3/40 , C10G11/22 , B01J2208/00017 , B01J2208/00548 , C01B2203/0233 , C01B2203/0811 , C01B2203/1058 , C01B2203/1064 , C10G2300/70
摘要： Catalyst systems are provided for reforming of hydrocarbons, along with methods for using such catalyst systems. The catalyst systems can be deposited or otherwise coated on a surface or structure, such as a monolith, to achieve improved activity and/or structural stability. The metal oxide support layer can correspond to a thermally stable metal oxide support layer, such as a metal oxide support layer that is thermally phase stable at temperatures of 800° C. to 1600° C. The catalyst systems can be beneficial for use in cyclical reaction environments, such as reverse flow reactors or other types of reactors that are operated using flows in opposing directions and different times within a reaction cycle.
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公开(公告)号：US11773335B2
公开(公告)日：2023-10-03
申请号：US17643044
申请日：2021-12-07
发明人： Brian M. Weiss , Sophie Liu , Michael R. Harper, Jr. , Herbert W. Barry , Changmin Chun , Barrington S. Goldson , Justin R. Johnson , Faria Nusrat
CPC分类号： C10G11/182 , C10G11/12 , C10G2300/703
摘要： Systems and methods are provided for using a reverse flow reactor (or another reactor with flows in opposing directions at different parts of a process cycle) for pyrolysis of hydrocarbons. The systems and methods can include a reactor that includes a combustion catalyst to initiate and/or maintain combustion within the reactor in a controlled manner during the heating and/or regeneration portion(s) of the reaction cycle. A fuel can also be used that has a greater resistance to auto-combustion, such as a fuel that is composed primarily of methane and/or other hydrocarbons. During operation, the temperature in at least an initial portion of the reactor can be maintained at a temperature so that auto-ignition of the auto-combustion resistant fuel injected during the heating step(s) is reduced or minimized. This can allow combustion to be initiated when the auto-combustion resistant fuel comes into contact with the catalyst. Additionally, the amount and positioning of the catalyst within the reactor can be controlled so that combustion of the fuel takes place over a substantially longer period of time than combustion during a conventional reactor heating step. Because the fuel is moving within the reactor during combustion, extending the combustion time results in a substantial expansion of the volume where combustion occurs. Optionally in combination with an improved reaction cycle, this can expand the portion of the reactor that is directly heated by combustion, allowing for an improved temperature distribution within the reactor during the pyrolysis step.
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