公开(公告)号：US20180030244A1

公开(公告)日：2018-02-01

申请号：US15724705

申请日：2017-10-04

Applicant: Fina Technology, Inc.

Inventor： Giovanni Trimino ,  Carlos DeAnda ,  David W. Knoeppel

IPC: C08K5/524 ,  C08L25/06 ,  C08K5/17 ,  C08K5/105 ,  C08L51/00 ,  C08L51/04 ,  C08K5/353 ,  C08K5/3492 ,  C08K5/20

Abstract: High impact polystyrene may be formed with increased swell index and reduced or eliminated discoloration. A process of forming high impact polystyrene may include providing a polymerization system including a polymerization reactor and a devolatilizer. High impact polystyrene may be formed in the polymerization reactor, and sent to the devolatilizer. A polar antioxidant having a hindered phenol structure and an aliphatic amine group, and with a phosphite antioxidant may be added to the polymerization system. In another process, a chemical retarder and a fluorescent whitening agent may be added to the polymerization system. In another process, a chemical retarder that inhibits free radical rubber crosslinking may be added to the polymerization system.

公开(公告)号：US09809699B2

公开(公告)日：2017-11-07

申请号：US14927528

申请日：2015-10-30

Applicant: FINA TECHNOLOGY, INC.

Inventor： Giovanni Trimino ,  Carlos DeAnda ,  David W. Knoeppel

IPC: C08L25/06 ,  C08K5/524 ,  C08L51/00 ,  C08L51/04 ,  C08K5/105 ,  C08K5/17 ,  C08K5/20 ,  C08K5/3492 ,  C08K5/353

CPC classification number: C08K5/524 ,  C08K5/105 ,  C08K5/17 ,  C08K5/20 ,  C08K5/3492 ,  C08K5/353 ,  C08L25/06 ,  C08L51/003 ,  C08L51/04

Abstract: High impact polystyrene may be formed with increased swell index and reduced or eliminated discoloration. A process of forming high impact polystyrene may include providing a polymerization system including a polymerization reactor and a devolatilizer. High impact polystyrene may be formed in the polymerization reactor, and sent to the devolatilizer. A polar antioxidant having a hindered phenol structure and an aliphatic amine group, and with a phosphite antioxidant may be added to the polymerization system. In another process, a chemical retarder and a fluorescent whitening agent may be added to the polymerization system. In another process, a chemical retarder that inhibits free radical rubber crosslinking may be added to the polymerization system.

公开(公告)号：US09527945B2

公开(公告)日：2016-12-27

申请号：US14794209

申请日：2015-07-08

Applicant: FINA TECHNOLOGY, INC.

Inventor： Carlos DeAnda ,  Graciela Morales ,  Jose M. Sosa ,  David Knoeppel

IPC: C08F279/02 ,  C08F285/00 ,  C08F297/04 ,  C08F299/02

CPC classification number: C08F279/02 ,  C08F285/00 ,  C08F297/044 ,  C08F299/02 ,  C08F212/08

Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.

公开(公告)号：US09120889B2

公开(公告)日：2015-09-01

申请号：US14328342

申请日：2014-07-10

Applicant: FINA TECHNOLOGY, INC.

Inventor： Carlos DeAnda ,  Graciela Morales ,  Jose M. Sosa ,  David Knoeppel

IPC: C08F279/02 ,  C08F285/00 ,  C08F297/04

CPC classification number: C08F279/02 ,  C08F285/00 ,  C08F297/044 ,  C08F299/02 ,  C08F212/08

Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.

Abstract translation: 一种制备具有增加的橡胶相体积的橡胶改性聚合物的方法，包括将乙烯基芳族单体和弹性体加入到聚合反应器中以形成反应混合物，使反应混合物聚合，将共聚物与聚合的反应混合物结合形成 混合物，使组合的混合物进一步聚合，并从进一步的聚合中获得橡胶改性的聚合物产物。

公开(公告)号：US10550245B2

公开(公告)日：2020-02-04

申请号：US15724705

申请日：2017-10-04

Applicant: Fina Technology, Inc.

Inventor： Giovanni Trimino ,  Carlos DeAnda ,  David W Knoeppel

IPC: C08K5/524 ,  C08L25/06 ,  C08L51/00 ,  C08L51/04 ,  C08K5/105 ,  C08K5/17 ,  C08K5/20 ,  C08K5/3492 ,  C08K5/353

Abstract: High impact polystyrene may be formed with increased swell index and reduced or eliminated discoloration. A process of forming high impact polystyrene may include providing a polymerization system including a polymerization reactor and a devolatilizer. High impact polystyrene may be formed in the polymerization reactor, and sent to the devolatilizer. A polar antioxidant having a hindered phenol structure and an aliphatic amine group, and with a phosphite antioxidant may be added to the polymerization system. In another process, a chemical retarder and a fluorescent whitening agent may be added to the polymerization system. In another process, a chemical retarder that inhibits free radical rubber crosslinking may be added to the polymerization system.

公开(公告)号：US20170121501A1

公开(公告)日：2017-05-04

申请号：US14927528

申请日：2015-10-30

Applicant: FINA TECHNOLOGY, INC.

Inventor： Giovanni Trimino ,  Carlos DeAnda ,  David W. Knoeppel

IPC: C08K5/524 ,  C08K5/17 ,  C08K5/20 ,  C08K5/105 ,  C08K5/353 ,  C08K5/3492

CPC classification number: C08K5/524 ,  C08K5/105 ,  C08K5/17 ,  C08K5/20 ,  C08K5/3492 ,  C08K5/353 ,  C08L25/06 ,  C08L51/003 ,  C08L51/04

Abstract: High impact polystyrene may be formed with increased swell index and reduced or eliminated discoloration. A process of forming high impact polystyrene may include providing a polymerization system including a polymerization reactor and a devolatilizer. High impact polystyrene may be formed in the polymerization reactor, and sent to the devolatilizer. A polar antioxidant having a hindered phenol structure and an aliphatic amine group, and with a phosphite antioxidant may be added to the polymerization system. In another process, a chemical retarder and a fluorescent whitening agent may be added to the polymerization system. In another process, a chemical retarder that inhibits free radical rubber crosslinking may be added to the polymerization system.

公开(公告)号：US20150307644A1

公开(公告)日：2015-10-29

申请号：US14794209

申请日：2015-07-08

Applicant: FINA TECHNOLOGY, INC.

Inventor： Carlos DeAnda ,  Graciela Morales ,  Jose M. Sosa ,  David Knoeppel

IPC: C08F279/02 ,  C08F299/02

CPC classification number: C08F279/02 ,  C08F285/00 ,  C08F297/044 ,  C08F299/02 ,  C08F212/08

Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.

Abstract translation: 一种制备具有增加的橡胶相体积的橡胶改性聚合物的方法，包括将乙烯基芳族单体和弹性体加入到聚合反应器中以形成反应混合物，使反应混合物聚合，将共聚物与聚合的反应混合物结合形成 混合物，使组合的混合物进一步聚合，并从进一步的聚合中获得橡胶改性的聚合物产物。

公开(公告)号：US20140323654A1

公开(公告)日：2014-10-30

申请号：US14328342

申请日：2014-07-10

Applicant: FINA TECHNOLOGY, INC.

Inventor： Carlos DeAnda ,  Graciela Morales ,  Jose M. Sosa ,  David Knoeppel

IPC: C08F279/02

CPC classification number: C08F279/02 ,  C08F285/00 ,  C08F297/044 ,  C08F299/02 ,  C08F212/08

Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.

Abstract translation: 一种制备具有增加的橡胶相体积的橡胶改性聚合物的方法，包括将乙烯基芳族单体和弹性体进料到聚合反应器中以形成反应混合物，使反应混合物聚合，将共聚物与聚合的反应混合物结合形成 混合物，使组合的混合物进一步聚合，并从进一步的聚合中获得橡胶改性的聚合物产物。