公开(公告)号：US09809699B2

公开(公告)日：2017-11-07

申请号：US14927528

申请日：2015-10-30

申请人： FINA TECHNOLOGY, INC.

发明人： Giovanni Trimino ,  Carlos DeAnda ,  David W. Knoeppel

IPC分类号： C08L25/06 ,  C08K5/524 ,  C08L51/00 ,  C08L51/04 ,  C08K5/105 ,  C08K5/17 ,  C08K5/20 ,  C08K5/3492 ,  C08K5/353

CPC分类号： C08K5/524 ,  C08K5/105 ,  C08K5/17 ,  C08K5/20 ,  C08K5/3492 ,  C08K5/353 ,  C08L25/06 ,  C08L51/003 ,  C08L51/04

摘要： High impact polystyrene may be formed with increased swell index and reduced or eliminated discoloration. A process of forming high impact polystyrene may include providing a polymerization system including a polymerization reactor and a devolatilizer. High impact polystyrene may be formed in the polymerization reactor, and sent to the devolatilizer. A polar antioxidant having a hindered phenol structure and an aliphatic amine group, and with a phosphite antioxidant may be added to the polymerization system. In another process, a chemical retarder and a fluorescent whitening agent may be added to the polymerization system. In another process, a chemical retarder that inhibits free radical rubber crosslinking may be added to the polymerization system.

公开(公告)号：US20150218358A1

公开(公告)日：2015-08-06

申请号：US14688591

申请日：2015-04-16

申请人： FINA TECHNOLOGY, INC.

发明人： Wei Wang ,  David W. Knoeppel ,  Fengkui Li ,  Jose M. Sosa

IPC分类号： C08L25/14

CPC分类号： C08L25/14 ,  C08L25/06 ,  C08L29/04 ,  C08L35/06 ,  C08L67/00 ,  C08L101/00 ,  C08L2201/06

摘要： Polystyrene blends and methods of making polystyrene blends including combining a styrene monomer and an epoxy-functional comonomer to form a combined mixture, subjecting the combined mixture to polymerization to obtain a polystyrene copolymer and combining the polystyrene copolymer with a biodegradable polymer to obtain a polystyrene blend.

摘要翻译： 聚苯乙烯共混物和制备聚苯乙烯共混物的方法，包括组合苯乙烯单体和环氧官能的共聚单体以形成组合的混合物，使合并的混合物进行聚合以获得聚苯乙烯共聚物并将聚苯乙烯共聚物与可生物降解的聚合物组合以获得聚苯乙烯共混物 。

公开(公告)号：US20150094404A1

公开(公告)日：2015-04-02

申请号：US14565857

申请日：2014-12-10

申请人： FINA TECHNOLOGY, INC.

发明人： Wei Wang ,  David W. Knoeppel ,  Jose M. Sosa

IPC分类号： C08L25/14 ,  C08L3/00 ,  C08L1/00 ,  C08L5/00 ,  C08L25/08

CPC分类号： C08L25/14 ,  C08K5/0016 ,  C08L1/00 ,  C08L3/00 ,  C08L5/00 ,  C08L25/08 ,  C08L29/04 ,  C08L35/06 ,  C08L67/04 ,  C08L2201/06

摘要： A styrenic composition including a polar modified styrenic co-polymer resulting from the polymerization of a combined mixture of at least one styrenic monomer and at least one comonomer and a biodegradable component is disclosed. The at least one comonomer includes a polar functional group and the polar modified styrenic co-polymer and the biodegradable component are combined to obtain a styrenic composition having a biodegradable component. Also disclosed is a method of enhancing bio-polymer miscibility in a styrenic based polymer. The polarity of a blend is manipulated by combining a styrenic monomer and a polar co-monomer to form a combined mixture and subjecting the combined mixture to polymerization to obtain a styrenic polymer blend to which a bio-polymer is added.

摘要翻译： 公开了一种苯乙烯组合物，其包含由至少一种苯乙烯类单体和至少一种共聚单体和可生物降解的组分的组合混合物的聚合产生的极性改性苯乙烯共聚物。 所述至少一种共聚单体包括极性官能团和极性改性的苯乙烯类共聚物，并且所述可生物降解的组分被组合以获得具有可生物降解的组分的苯乙烯组合物。 还公开了一种提高苯乙烯类聚合物中生物聚合物混溶性的方法。 通过组合苯乙烯类单体和极性共聚单体来混合共混物的极性，以形成组合的混合物，并将合并的混合物进行聚合，得到加入生物聚合物的苯乙烯聚合物共混物。

公开(公告)号：US08809459B2

公开(公告)日：2014-08-19

申请号：US13754036

申请日：2013-01-30

申请人： Fina Technology, Inc.

发明人： Camille Grossetete ,  David W. Knoeppel ,  Jose M. Sosa ,  Shane Steagall ,  Carlos Corletto

IPC分类号： C08F8/00 ,  C08L25/02

CPC分类号： C08L25/06 ,  C08L2205/02 ,  C08L2207/20

摘要： A method of preparing a polystyrene blend that includes combining a first polystyrene composition having a first melt flow index with a second polystyrene composition having a second melt flow index and forming a polystyrene blend, the second melt flow index being at least 2 dg/min higher that the first melt flow index. The polystyrene blend has an observed tensile strength value greater than 3% above the expected tensile strength value. The second polystyrene composition can include a recycled polystyrene material, which can include expanded polystyrene. An alternate method of preparing the polystyrene blend includes combining a polystyrene composition with a styrene monomer to form a reaction mixture, polymerizing the reaction mixture and obtaining a polystyrene blend, where the polystyrene containing composition has a melt flow index at least 2 dg/min higher than the melt flow index of the styrene monomer after it has been polymerized.

摘要翻译： 一种制备聚苯乙烯共混物的方法，其包括将具有第一熔体流动指数的第一聚苯乙烯组合物与具有第二熔体流动指数的第二聚苯乙烯组合物组合并形成聚苯乙烯共混物，所述第二熔体流动指数至少为2dg / min 第一个熔体流动指数。 聚苯乙烯共混物的观测拉伸强度值大于预期拉伸强度值的3％以上。 第二聚苯乙烯组合物可以包括再循环的聚苯乙烯材料，其可以包括发泡聚苯乙烯。 制备聚苯乙烯共混物的替代方法包括将聚苯乙烯组合物与苯乙烯单体组合以形成反应混合物，使反应混合物聚合并获得聚苯乙烯共混物，其中含聚苯乙烯的组合物的熔体流动指数至少为2dg / min 比苯乙烯单体聚合后的熔体流动指数高。

公开(公告)号：US11639429B2

公开(公告)日：2023-05-02

申请号：US16985097

申请日：2020-08-04

申请人： FINA TECHNOLOGY, INC.

发明人： Fengkui Li ,  Jayna Brown ,  Jon David Tippet ,  Kenneth P. Blackmon ,  David W. Knoeppel ,  John R. Gaustad ,  Wyman T. Stephens ,  Ying Wang

IPC分类号： C08J9/28 ,  C08K3/22 ,  C08K5/02

摘要： A polystyrene (PS) composition for making an extruded foam, the PS composition comprising: a dried PS/alumina compound comprising a PS and an alumina additive, wherein the dried PS/alumina compound has a moisture content, measured by Coulometer, that is less than or equal to about 0.05 weight percent (wt %); and a blowing agent.

公开(公告)号：US08981004B2

公开(公告)日：2015-03-17

申请号：US14136921

申请日：2013-12-20

申请人： Fina Technology, Inc.

发明人： James R. Butler ,  David W. Knoeppel

IPC分类号： C08L25/04 ,  C08K9/06 ,  C08F2/44 ,  C08F12/08 ,  B82Y30/00 ,  C08K3/22 ,  C08K3/36

CPC分类号： C08K3/36 ,  B82Y30/00 ,  C08F2/44 ,  C08F12/08 ,  C08K3/22 ,  C08K9/06 ,  C08K2003/2227 ,  C08K2201/011 ,  Y10S977/778 ,  Y10S977/779 ,  Y10S977/783

摘要： Disclosed is a method of making a polystyrene based nanocomposite by combining a monomer with a nanoparticle to form a mixture and subjecting the mixture to polymerization conditions to produce a polymeric composite. In an embodiment the nanoparticle has been treated with an additive prior to combining with the monomer and the additive contains a silane moiety.

摘要翻译： 公开了通过将单体与纳米颗粒结合以形成混合物并使混合物经受聚合条件以制备聚合物复合材料制备聚苯乙烯基纳米复合材料的方法。 在一个实施方案中，纳米颗粒在与单体组合之前已经用添加剂处理，并且添加剂含有硅烷部分。

公开(公告)号：US09815957B2

公开(公告)日：2017-11-14

申请号：US14495340

申请日：2014-09-24

申请人： FINA TECHNOLOGY, INC.

发明人： Jose M. Sosa ,  David W. Knoeppel

IPC分类号： C08J9/28 ,  B29C44/08 ,  C08J9/00 ,  C08J9/12

CPC分类号： C08J9/28 ,  B29C44/08 ,  C08J9/0066 ,  C08J9/122 ,  C08J9/125 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/10 ,  C08J2203/182 ,  C08J2205/042 ,  C08J2205/044 ,  C08J2205/048 ,  C08J2325/04 ,  C08J2325/06

摘要： Cellular and multi-cellular polystyrene and polystyrenic foams and methods of forming such foams are disclosed. The foams include an expanded polystyrene formed from expansion of an expandable polystyrene including an adsorbent comprising alumina, wherein the multi-cellular polystyrene exhibits a multi-cellular size distribution. The process for forming a foamed article includes providing a formed styrenic polymer and contacting the formed styrenic polymer with a first blowing agent and an adsorbent comprising alumina to form extrusion polystyrene. The process further includes forming the extrusion styrenic polymer into an expanded styrenic polymer and forming the expanded styrenic polymer into a foamed article.

公开(公告)号：US09212278B2

公开(公告)日：2015-12-15

申请号：US14180540

申请日：2014-02-14

申请人： FINA TECHNOLOGY, INC.

发明人： David W. Knoeppel ,  Likuo Sun ,  Jon Tippet

IPC分类号： C08L25/06 ,  C08L51/04 ,  C08L25/08 ,  C08L25/10

CPC分类号： C08L25/06 ,  C08F279/02 ,  C08F285/00 ,  C08L25/08 ,  C08L25/10 ,  C08L51/04 ,  C08F212/08

摘要： A high impact polystyrene (HIPS) is made from styrene monomer and 3 to 20 wt % of an elastomeric component phase including polybutadiene rubber and styrene butadiene copolymer. The HIPS has a 60 degree gloss of 90 or more, a Gardner drop of at least 10 in-lb, and an Izod impact strength of 1.8 ft-lb/in or more. The HIPS can have salami morphology with rubber particle size between 1 and 1.3 microns.

摘要翻译： 高抗冲聚苯乙烯（HIPS）由苯乙烯单体和3至20wt％的弹性体组分相制成，包括聚丁二烯橡胶和苯乙烯丁二烯共聚物。 HIPS具有90度或更大的60度光泽度，至少10英寸磅的加德纳滴度和1.8英尺磅/英寸或更大的艾佐德冲击强度。 HIPS可以具有1到1.3微米之间的橡胶粒度的萨拉米香肠形态。

公开(公告)号：US20150057383A1

公开(公告)日：2015-02-26

申请号：US14533730

申请日：2014-11-05

申请人： FINA TECHNOLOGY, INC.

发明人： Wei Wang ,  David W. Knoeppel ,  Melissa Greenberg

IPC分类号： C08J9/12

CPC分类号： C08J9/122 ,  C08F212/08 ,  C08J9/0023 ,  C08J9/12 ,  C08J9/142 ,  C08J2203/06 ,  C08J2203/10 ,  C08J2203/12 ,  C08J2325/08 ,  C08J2351/00 ,  C08F2220/281 ,  C08F222/08 ,  C08F2220/1825 ,  C08F2220/325

摘要： A method of making a foamable polystyrene composition includes combining a styrenic monomer and a co-monomer containing a polar functional group to obtain a mixture, subjecting the mixture to polymerization to obtain a styrenic co-polymer, and combining the styrenic co-polymer with a blowing agent in a foaming process to obtain foamed articles.

摘要翻译： 制备可发泡聚苯乙烯组合物的方法包括将苯乙烯单体和含有极性官能团的共聚单体混合以获得混合物，使混合物聚合以获得苯乙烯共聚物，并将苯乙烯共聚物与 发泡剂中发泡剂得到泡沫制品。

公开(公告)号：US20150011665A1

公开(公告)日：2015-01-08

申请号：US14495340

申请日：2014-09-24

申请人： FINA TECHNOLOGY, INC.

发明人： Jose M. Sosa ,  David W. Knoeppel

IPC分类号： C08J9/28 ,  C08J9/12 ,  C08J9/00

CPC分类号： C08J9/28 ,  B29C44/08 ,  C08J9/0066 ,  C08J9/122 ,  C08J9/125 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/10 ,  C08J2203/182 ,  C08J2205/042 ,  C08J2205/044 ,  C08J2205/048 ,  C08J2325/04 ,  C08J2325/06

摘要： Cellular and multi-cellular polystyrene and polystyrenic foams and methods of forming such foams are disclosed. The foams include an expanded polystyrene formed from expansion of an expandable polystyrene including an adsorbent comprising alumina, wherein the multi-cellular polystyrene exhibits a multi-cellular size distribution. The process for forming a foamed article includes providing a formed styrenic polymer and contacting the formed styrenic polymer with a first blowing agent and an adsorbent comprising alumina to form extrusion polystyrene. The process further includes forming the extrusion styrenic polymer into an expanded styrenic polymer and forming the expanded styrenic polymer into a foamed article.

摘要翻译： 公开了细胞和多细胞聚苯乙烯和聚苯乙烯泡沫以及形成这种泡沫的方法。 泡沫包括由可膨胀聚苯乙烯膨胀形成的发泡聚苯乙烯，其包括包含氧化铝的吸附剂，其中多孔聚苯乙烯表现出多孔尺寸分布。 形成发泡制品的方法包括提供形成的苯乙烯类聚合物并使所形成的苯乙烯类聚合物与第一发泡剂和包含氧化铝的吸附剂接触以形成挤出聚苯乙烯。 该方法还包括将挤出苯乙烯聚合物形成膨胀的苯乙烯聚合物，并将膨胀的苯乙烯聚合物形成发泡制品。