公开(公告)号：US20140100300A1

公开(公告)日：2014-04-10

申请号：US14103192

申请日：2013-12-11

Applicant: FINA TECHNOLOGY, INC.

Inventor： John Gaustad ,  Juan Aguirre ,  Joe Shuler

IPC: C08F30/04

CPC classification number: C08F30/04 ,  C08F212/08 ,  C08F220/06 ,  C08F230/04 ,  C08J5/18 ,  C08J9/00 ,  C08J9/04 ,  C08J2325/14 ,  C08K5/0091 ,  C08L35/06 ,  C08L35/00 ,  C08F220/14 ,  C08F222/10

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

Abstract translation: 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / 10min。 至1.9g / 10分钟。

公开(公告)号：US08889755B2

公开(公告)日：2014-11-18

申请号：US14103192

申请日：2013-12-11

Applicant: Fina Technology, Inc.

Inventor： John Gaustad ,  Juan Aguirre ,  Joe Shuler

IPC: C08F30/04 ,  C08J5/18 ,  C08K5/00 ,  C08J9/04 ,  C08J9/00 ,  C08L35/06 ,  C08F230/04 ,  C08F212/08 ,  C08F220/06

CPC classification number: C08F30/04 ,  C08F212/08 ,  C08F220/06 ,  C08F230/04 ,  C08J5/18 ,  C08J9/00 ,  C08J9/04 ,  C08J2325/14 ,  C08K5/0091 ,  C08L35/06 ,  C08L35/00 ,  C08F220/14 ,  C08F222/10

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

Abstract translation: 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / 10min。 至1.9g / 10分钟。

公开(公告)号：US08653212B2

公开(公告)日：2014-02-18

申请号：US13964781

申请日：2013-08-12

Applicant: Fina Technology, Inc.

Inventor： John Gaustad ,  Juan Aguirre ,  Joe Shuler

IPC: C08F30/04 ,  C08F20/00 ,  C08L33/06

CPC classification number: C08F30/04 ,  C08F212/08 ,  C08F220/06 ,  C08F230/04 ,  C08J5/18 ,  C08J9/00 ,  C08J9/04 ,  C08J2325/14 ,  C08K5/0091 ,  C08L35/06 ,  C08L35/00 ,  C08F220/14 ,  C08F222/10

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

Abstract translation: 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / 10min。 至1.9g / 10分钟。

公开(公告)号：US20130331471A1

公开(公告)日：2013-12-12

申请号：US13964781

申请日：2013-08-12

Applicant: Fina Technology, Inc.

Inventor： John Gaustad ,  Juan Aguirre ,  Joe Shuler

IPC: C08F230/04 ,  C08L35/06

CPC classification number: C08F30/04 ,  C08F212/08 ,  C08F220/06 ,  C08F230/04 ,  C08J5/18 ,  C08J9/00 ,  C08J9/04 ,  C08J2325/14 ,  C08K5/0091 ,  C08L35/06 ,  C08L35/00 ,  C08F220/14 ,  C08F222/10

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/min. to 1.9 g/10 min.

Abstract translation: 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / min。 至1.9g / 10分钟。

公开(公告)号：US20140200293A1

公开(公告)日：2014-07-17

申请号：US14167719

申请日：2014-01-29

Applicant: FINA TECHNOLOGY, INC.

Inventor： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Ted Harris

IPC: C08K9/04 ,  B29D22/00

CPC classification number: C08K9/04 ,  B29C49/0005 ,  B29C49/06 ,  B29D22/003 ,  B29K2025/00 ,  B29K2105/162 ,  Y10T428/1352 ,  Y10T428/1397

Abstract: Disclosed is a polystyrene based polymer/layered compound nanocomposite for injection blow molding or injection stretch blow molding of articles. The nanocomposite can reduce shrinkage and warpage to the preform during the reheating process compared to neat polystyrene. The incorporation of layered compounds can increase the processability of PS preforms, help improve heating efficiency, and improve bottle mechanical properties. The layered compound can be treated with chemicals or compounds having an affinity with the styrene monomer or polystyrene, thus producing a treated layered compound having an affinity with the styrene monomer or polystyrene. The monomer and the layered compound can be combined prior to polymerization. The polymer and layered compound can be combined by solution mixing in a solvent. The layered compound can also be incorporated into the mixture by compounding a polymer product with the layered compound, or the combination of any of the above three approaches

Abstract translation: 公开了用于注射吹塑或注射拉伸吹塑成型的聚苯乙烯基聚合物/层状复合纳米复合材料。 与纯聚苯乙烯相比，纳米复合材料可以在再加热过程中减少预成型件的收缩和翘曲。 结合层状化合物可以增加PS预制件的加工性能，有助于提高加热效率，并提高瓶子的机械性能。 层状化合物可以用与苯乙烯单体或聚苯乙烯具有亲和性的化学物质或化合物进行处理，从而产生与苯乙烯单体或聚苯乙烯具有亲和性的经处理的层状化合物。 单体和层状化合物可以在聚合之前进行组合。 聚合物和层状化合物可以通过在溶剂中的溶液混合来组合。 也可以通过将聚合物与层状化合物混合，或者将上述三种方法中的任一种