公开(公告)号：US10829645B2

公开(公告)日：2020-11-10

申请号：US16150768

申请日：2018-10-03

Applicant: FUJIFILM Corporation

Inventor： Miho Asahi ,  Naoya Shibata

IPC: G02B1/10 ,  C09D5/00 ,  B32B7/02 ,  G02B1/118 ,  B05D5/06 ,  G02B1/115 ,  G02B1/14 ,  G02B5/30

Abstract: A method of manufacturing an antireflection film including, in the following order, a substrate, a hard coat layer and an antireflection layer as defined herein includes: applying a hard coat layer forming composition including a crosslinking compound having a weight-average molecular weight equal to or greater than 600, a compound having a molecular weight smaller than 600 and having a photopolymerizable group and a photopolymerization initiator, onto the substrate as defined herein; semi-curing the hard coat layer forming film; applying an antireflection layer forming composition including particles, a binder resin forming compound and a solvent, onto the semi-cured hard coat layer forming film as defined herein; causing a part of the binder resin forming compound to permeate the hard coat layer forming film as defined herein; and completely curing the hard coat layer forming film and the antireflection layer forming film as defined herein.

公开(公告)号：US11078314B2

公开(公告)日：2021-08-03

申请号：US16564549

申请日：2019-09-09

Applicant: FUJIFILM Corporation

Inventor： Reiko Fukagawa ,  Miho Asahi

IPC: C08F214/18 ,  G02B1/14 ,  C08J5/18 ,  G02B5/30

Abstract: A copolymer includes a repeating unit of Formula (I) and a repeating unit of Formula (II), a composition includes the copolymer, and an optical film has a layer formed of the composition, in the Formulae (I) and (II), R1 and R2 represent a hydrogen atom or an alkyl group, L3 and L1 represent a divalent linking group, L2 represents a single bond or a divalent linking group, and L4 represents a single bond or a divalent linking group, L4 does not represent a linking group including —O(C═O)—NH—, X represents a perfluoropolyether group, an alkyl group having a branched structure in which hydrogen is all substituted into fluorine, an alkenyl group, or an alkynyl group, and Y represents a crosslinking group.

公开(公告)号：US09874659B2

公开(公告)日：2018-01-23

申请号：US15059899

申请日：2016-03-03

Applicant: FUJIFILM Corporation

Inventor： Naoya Shibata ,  Miho Asahi ,  Hajime Nakayama ,  Ayako Matsumoto

IPC: G02B27/00 ,  G02B1/118 ,  G02B1/111 ,  G02B1/14 ,  G02B5/30 ,  C03C17/00

Abstract: An antireflection article includes a substrate; and an antireflection layer containing a binder resin and inorganic particles, wherein the inorganic particles are particles having an average primary particle diameter of 150 nm to 250 nm and a CV value of 4% or less, 99.9% or more of the inorganic particles are perfectly spherical particles, the antireflection layer includes a moth eye structure composed of an unevenness shape formed by the inorganic particles on a surface of the antireflection layer, and an area occupancy ratio of the inorganic particles on the surface of the antireflection layer is 25% to 64%.

公开(公告)号：US11914248B2

公开(公告)日：2024-02-27

申请号：US17092316

申请日：2020-11-08

Applicant: FUJIFILM Corporation

Inventor： Yutaka Nozoe ,  Takashi Iizumi ,  Kazushige Nakagawa ,  Takahiro Kato ,  Miho Asahi ,  Hirofumi Omura ,  Yuki Hirai

IPC: G02F1/1337 ,  C08F220/60 ,  C08F220/32 ,  C08F220/36 ,  G02F1/01 ,  C08F220/30 ,  C08F220/58 ,  C08F220/28

CPC classification number: G02F1/133711 ,  C08F220/30 ,  C08F220/32 ,  C08F220/325 ,  C08F220/36 ,  C08F220/365 ,  C08F220/58 ,  C08F220/603 ,  G02F1/0136 ,  G02F1/13378 ,  C08F220/281 ,  C09K2323/02 ,  G02F2202/022 ,  C08F220/603 ,  C08F220/40 ,  C08F220/603 ,  C08F220/281 ,  C08F220/58 ,  C08F220/32 ,  C08F220/32 ,  C08F220/58 ,  C08F220/281 ,  C08F220/603 ,  C08F220/40 ,  C08F220/603

Abstract: An object of the invention is to provide a photo-alignment copolymer which makes it possible to produce a photo-alignment film having excellent solvent resistance and liquid crystal aligning properties, and a photo-alignment film and an optical laminate produced using the photo-alignment copolymer. A photo-alignment copolymer of the invention is a photo-alignment copolymer having a repeating unit A including a photo-alignment group represented by Formula (A) and a repeating unit B including a crosslinkable group represented by Formula (B).

公开(公告)号：US10436948B2

公开(公告)日：2019-10-08

申请号：US14883312

申请日：2015-10-14

Applicant: FUJIFILM Corporation

Inventor： Daiki Wakizaka ,  Miho Asahi

IPC: G02B1/14 ,  G02B1/12 ,  G02B5/30 ,  G02F1/1335 ,  G02B1/04

Abstract: There is provided an optical film which includes a light transmissive support body containing a thermoplastic resin, a layer containing the thermoplastic resin and a resin cured with light and/or heat, and a layer containing a resin same as the resin cured with light and/or heat and a cyclic polyolefin-based resin in this order.

公开(公告)号：US10338276B2

公开(公告)日：2019-07-02

申请号：US14851722

申请日：2015-09-11

Applicant: FUJIFILM Corporation

Inventor： Miho Asahi ,  Kazuo Kamohara ,  Shuntaro Ibuki ,  Ayako Matsumoto ,  Daiki Wakizaka

IPC: G02B1/14 ,  G02B5/30 ,  G02B1/111 ,  G02B1/118

Abstract: There is provided an antireflective film, including: a plastic substrate; a infiltration layer; and an antireflective layer containing metallic oxide fine particles with an average primary particle diameter of 50 nm to 250 nm and a viscosity increasing compound, in this order, wherein the infiltration layer contains a polymer of a (meth)acrylate compound having a molecular weight of 400 or less, and the antireflective layer has a moth-eye structure including an uneven shape formed by the metallic oxide fine particles.

公开(公告)号：US10399309B2

公开(公告)日：2019-09-03

申请号：US15280052

申请日：2016-09-29

Applicant: FUJIFILM Corporation

Inventor： Miho Asahi ,  Ayako Matsumoto ,  Shuntaro Ibuki ,  Makoto Uchimura

IPC: B32B27/20 ,  B29D11/00 ,  B32B27/30 ,  G02B1/118 ,  G02B5/30 ,  G02B5/02

Abstract: An antireflection film includes: a substrate; and an antireflection layer formed with a composition containing metal oxide particles having surface hydroxyl groups as particles for forming a moth eye structure, and two compounds having (meth)acryloyl groups, where the antireflection layer contains a binder resin including at least one of a structure derived from the two (meth)acryloyl groups, and the moth eye structure has an irregular shape formed with the metal oxide particles on a surface on a side opposite to an interface on the substrate side, and in the irregular shape of the antireflection layer, B/A is a ratio between a distance A between peaks of adjacent convex portions and a distance B between a center between peaks of the adjacent convex portions and a concave portion is 0.5 or greater.

公开(公告)号：US10082605B2

公开(公告)日：2018-09-25

申请号：US15096781

申请日：2016-04-12

Applicant: FUJIFILM Corporation

Inventor： Shuntaro Ibuki ,  Makoto Uchimura ,  Miho Asahi

IPC: G02B1/118 ,  C03C17/00 ,  G02B1/113 ,  H01J29/89 ,  G02B1/11

CPC classification number: G02B1/118 ,  C03C17/007 ,  G02B1/11 ,  G02B1/113 ,  H01J29/896 ,  H01J2229/8913 ,  Y10T428/10

Abstract: There is provided a method of manufacturing a specific antireflection article, the method including: applying, on the substrate, an antireflection layer-forming composition containing: specific binders, specific metal oxide particles, a metal chelate catalyst, and a solvent to dispose a first particle group composed of metal oxide particles which form a convex portion having an unevenness shape, and a second particle group composed of metal oxide particles between the first particle group and the substrate; volatilizing and drying the solvent; and heating and curing the binder (a) and the binder (b) after the volatilizing and drying of the solvent.

公开(公告)号：US10585225B2

公开(公告)日：2020-03-10

申请号：US15726881

申请日：2017-10-06

Applicant: FUJIFILM Corporation

Inventor： Miho Asahi ,  Ayako Matsumoto ,  Shuntaro Ibuki ,  Shinya Watanabe ,  Hajime Nakayama ,  Naoya Shibata

IPC: G02B5/30 ,  G02B27/28 ,  B32B27/18 ,  G09F9/00 ,  B32B27/00 ,  G02B1/14 ,  B32B27/22 ,  G02F1/1335 ,  C08J7/04

Abstract: A transparent film includes: a base material; and at least one scratch resistant layer of which indentation hardness is 300 MPa or greater and of which a thickness is 50 to 1,000 nm on an outermost surface of the transparent film at one side or both sides of the base material, and a number of times of folding endurance of the transparent film measured by an MIT testing machine according to JIS P8115 (2001) is 1,000 times or greater.

公开(公告)号：US10012770B2

公开(公告)日：2018-07-03

申请号：US14812477

申请日：2015-07-29

Applicant: FUJIFILM Corporation

Inventor： Kenichi Fukuda ,  Miho Asahi ,  Yutaka Nozoe

IPC: G02F1/1335 ,  G02B1/14 ,  G02B1/10 ,  G02B5/30 ,  C08J5/18 ,  B32B27/00 ,  G02B1/04 ,  C08J7/04

CPC classification number: G02B1/10 ,  B32B27/00 ,  C08J5/18 ,  C08J7/047 ,  C08J2333/12 ,  C08J2335/02 ,  C08J2435/02 ,  G02B1/04 ,  G02B1/14 ,  G02B5/30 ,  G02B5/3033 ,  G02F1/133528 ,  Y10T428/10 ,  Y10T428/31844 ,  Y10T428/31848 ,  C08L23/18

Abstract: There is provided an optical film comprising a layer formed on a base film by curing a curable composition containing the specific component (A) in an amount of 50 to 99% by mass and the specific component (B) in an amount of 1 to 50% by mass, based on the total solid content of the curable composition when the total solid content of the curable composition is set to 100% by mass.