摘要:
The invention relates to a metallocene compound of the formula I ##STR1## where the two indenyl ligands have substitution patterns different from one another. The metallocene compound can be used as catalyst component for olefin polymerization.
摘要:
The present invention relates to a polynuclear metallocene compound of the formula I ##STR1## a process for their preparation and their use as a catalyst for olefin polymerization.
摘要:
The invention relates to a metallocene compound of the formula I ##STR1## where the two indenyl ligands have substitution patterns different from one another. The metallocene compound can be used as catalyst component for olefin polymerization.
摘要:
The present invention relates to a metallocene compound of the formula I ##STR1## which can advantageously be used as catalyst component for olefin polymerization.
摘要:
The present invention relates to a metallocene compound of the formula I ##STR1## which can advantageously be used as catalyst component for olefin polymerization.
摘要:
The present invention relates to a polynuclear metallocene compound of the formula I ##STR1## a process for their preparation and their use as a catalyst for olefin polymerization.
摘要:
The present invention relates to a polynuclear metallocene compound of the formula I ##STR1## a process for their preparation and their use as a catalyst for olefin polymerization.
摘要:
The invention relates to a metallocene compound of the formula I ##STR1## where the two indenyl ligands have substitution patterns different from one another. The metallocene compound can be used as catalyst component for olefin polymerization.
摘要:
A very effective catalyst system for the polymerization or copolymerization of olefins comprises a cocatalyst, preferably an aluminoxane or a supported aluminoxane, and a metallocene of the formula I ##STR1## in which, in the preferred form, M.sup.1 in Zr or Hf, R.sup.1 and R.sup.2 are halogen or alkyl, R.sup.3 is alkyl, R.sup.4 to R.sup.12 are alkyl or hydrogen and R.sup.13 is a (substituted) alkylene or heteroatom bridge. The metallocenes, in particular the zirconocenes, produce polymers of very high molecular weight, in the case of prochiral monomers polymers of very high molecular weight, very high stereotacticity and very high melting point, at high catalyst activities in the industrially particularly interesting temperature range between 50 and 80.degree. C. In addition, reactor deposits are avoided by means of supported catalyst systems.
摘要:
Disclosed is a catalyst system and method of polymerizing olefins, wherein the catalyst comprises a bridged metallocene of the following structure: ##STR1## wherein M.sup.1 is a transition metal of groups 4-6, R.sup.1 -R.sup.9 is hydrogen or other groups with the proviso that substituents R.sup.3 and R.sup.6 are not hydrogen, and wherein the metallocene is present in the meso form or in a mixture including both the meso and racemic forms.
摘要翻译:公开了一种聚合烯烃的催化剂体系和方法,其中催化剂包含具有以下结构的桥连茂金属:其中M1是基团4-6的过渡金属,R 1 -R 9是氢或其它基团,条件是取代基R 3和 R 6不是氢,并且其中茂金属以内消旋形式存在或以包括内消旋形式和外消旋形式的混合物存在。