公开(公告)号：US5990349A

公开(公告)日：1999-11-23

申请号：US37020

申请日：1998-03-09

申请人： Friedhelm Geiger ,  Baudouin Halsberghe ,  Hans-Joachim Hasselbach ,  Klaus Hentschel ,  Klaus Huthmacher ,  Martin Korfer ,  Sven-Peter Mannsfeld ,  Herbert Tanner ,  Ferdinand Theissen ,  Jose Vanrobaeys ,  Klaus Willigerodt

发明人： Friedhelm Geiger ,  Baudouin Halsberghe ,  Hans-Joachim Hasselbach ,  Klaus Hentschel ,  Klaus Huthmacher ,  Martin Korfer ,  Sven-Peter Mannsfeld ,  Herbert Tanner ,  Ferdinand Theissen ,  Jose Vanrobaeys ,  Klaus Willigerodt

IPC分类号： C07C319/20 ,  C07C319/28 ,  C07C323/58 ,  C07D233/76 ,  C07C321/00 ,  C07C315/00

CPC分类号： C07C319/20 ,  C07C319/28 ,  C07D233/76

摘要： A process for the preparation of methionine or a salt of methionine by reaction of the components 3-methylmercaptopropionaldhyde, hydrogen cyanide, ammonia and carbon dioxide or components from which the above-mentioned components can be prepared, optionally in the presence of water, to 5-(2-methylmercaptoethyl)-hydantoin and further reaction thereof to methionine or the salt thereof, characterised in that the reaction of the components is initiated by means of at least one premixture in such a way that a first mixture is formed containing at least the predominant proportion (at least 5/10) of the 3-methylmercaptopropionaldeyde and at least 1/10 of the hydrogen cyanide component or corresponding quantities of components from which these components can be prepared, and less than 5/10 of one of the components ammonia, carbon dioxide or of the components from which ammonia or carbon dioxide can be prepared, and in that this first mixture is combined with the other component(s) for the reactive conversion to 5-(2-methylmercaptoethyl)-hydantoin, wherein this (these) latter component(s) may be premixed in one or more other mixtures.

摘要翻译： 通过将3-甲基巯基丙酸，氰化氢，氨和二氧化碳或可由其制备上述组分的组分，任选地在水存在下，将组分3-甲基巯基丙酸，氰化氢，氨和二氧化碳或组分反应制备甲硫氨酸或甲硫氨酸的方法， - （2-甲基巯基乙基） - 乙内酰脲及其与甲硫氨酸或其盐的反应，其特征在于，组分的反应通过至少一种预混物引发，使得形成第一混合物至少含有 3-甲基巯基丙酸的主要比例（至少+ E，fra 5/10 + EE）和氰化氢组分的至少+ E，fra 1/10 + EE或可以制备这些组分的相应量的组分， 并且可以制备氨，二氧化碳或其中可以制备氨或二氧化碳的组分之一的小于+ E，fra 5/10 + EE，并且因为该第一混合物与 反应转化成5-（2-甲基巯基乙基） - 乙内酰脲的其它组分，其中这些（这些）后一种组分可以在一种或多种其它混合物中预混合。

公开(公告)号：US5770769A

公开(公告)日：1998-06-23

申请号：US768624

申请日：1996-12-18

申请人： Friedhelm Geiger ,  Baudouin Halsberghe ,  Hans-Joachim Hasselbach ,  Klaus Hentschel ,  Klaus Huthmacher ,  Martin Korfer ,  Sven-Peter Mannsfeld ,  Herbert Tanner ,  Ferdinand Theissen ,  Jose Vanrobaeys ,  Klaus Willigerodt

发明人： Friedhelm Geiger ,  Baudouin Halsberghe ,  Hans-Joachim Hasselbach ,  Klaus Hentschel ,  Klaus Huthmacher ,  Martin Korfer ,  Sven-Peter Mannsfeld ,  Herbert Tanner ,  Ferdinand Theissen ,  Jose Vanrobaeys ,  Klaus Willigerodt

IPC分类号： C07C319/20 ,  C07C319/28 ,  C07C323/58 ,  C07D233/76 ,  C07C321/00

CPC分类号： C07C319/20 ,  C07C319/28 ,  C07D233/76

摘要： A process for the preparation of methionine or a salt of methionine by reaction of the components 3-methylmercaptopropionaldhyde, hydrogen cyanide, ammonia and carbon dioxide or components from which the above-mentioned components can be prepared, optionally in the presence of water, to 5-(2-methylmercaptoethyl)-hydantoin and further reaction thereof to methionine or the salt thereof, characterised in that the reaction of the components is initiated by means of at least one premixture in such a way that a first mixture is formed containing at least the predominant proportion (at least 5/10) of the 3-methylmercaptopropionaldeyde and at least 1/10 of the hydrogen cyanide component or corresponding quantities of components from which these components can be prepared, and less than 5/10 of one of the components ammonia, carbon dioxide or of the components from which ammonia or carbon dioxide can be prepared, and in that this first mixture is combined with the other component(s) for the reactive conversion to 5-(2-methylmercaptoethyl)-hydantoin, wherein this (these) latter component(s) may be premixed in one or more other mixtures.

公开(公告)号：US4303621A

公开(公告)日：1981-12-01

申请号：US930012

申请日：1978-08-01

申请人： Theodor Lussling ,  Klaus-Peter Muller ,  Gerd Schreyer ,  Ferdinand Theissen

发明人： Theodor Lussling ,  Klaus-Peter Muller ,  Gerd Schreyer ,  Ferdinand Theissen

IPC分类号： C07C319/28 ,  B01D9/02 ,  C01D7/00 ,  C01D7/10 ,  C07C20060101 ,  C07C67/00 ,  C07C227/04 ,  C07C255/04 ,  C07C313/00 ,  C07C319/20 ,  C07C323/58

CPC分类号： C01D7/00

摘要： Methionine and potassium are recovered from the recycling solution of the potassium carbonate-methionine process by concentrating the mother liquor after the methionine precipitation and with cooling carbonating the mother liquor.

摘要翻译： 通过在甲硫氨酸沉淀后浓缩母液并冷却碳酸化母液，从碳酸钾 - 甲硫氨酸方法的循环溶液中回收甲硫氨酸和钾。

公开(公告)号：US4136108A

公开(公告)日：1979-01-23

申请号：US294925

申请日：1972-10-04

申请人： Theodor Lussling ,  Ferdinand Theissen ,  Wolfgang Weigert

发明人： Theodor Lussling ,  Ferdinand Theissen ,  Wolfgang Weigert

IPC分类号： C07C121/22 ,  C07C120/00

CPC分类号： C07C255/00

摘要： Malononitrile is prepared by the short time high temperature reaction of gaseous acetonitrile and cyanogen chloride in the molar ratio of acetonitrile to cyanogen halide of above 1 characterized in that the well mixed reaction components are reacted at an average temperature below 800.degree. C. and the reaction is quenched to condense acetonitrile and malononitrile by introducing a cooling medium into the reaction system.

公开(公告)号：US4048232A

公开(公告)日：1977-09-13

申请号：US399127

申请日：1973-09-20

申请人： Edgar Koberstein ,  Klaus Muller ,  Ferdinand Theissen

发明人： Edgar Koberstein ,  Klaus Muller ,  Ferdinand Theissen

IPC分类号： C07B61/00 ,  B01J31/00 ,  C07C20060101 ,  C07C47/02 ,  C07C67/00 ,  C07C313/00 ,  C07C319/18 ,  C07C323/22 ,  C07C325/00

CPC分类号： C07C323/00

摘要： 3-Methylmercaptopropionaldehyde is made from acrolein and methyl mercaptan using hexamethylene tetramine as the catalyst.

摘要翻译： 使用六亚甲基四胺作为催化剂，由丙烯醛和甲基硫醇制备3-甲基巯基丙醛。