摘要:
There is disclosed an alkaline battery including a positive electrode material mixture, a negative electrode, a separator interposed between the positive electrode material mixture and the negative electrode, and an alkaline electrolyte, wherein the positive electrode material mixture includes a first active material comprising nickel oxyhydroxide and a second active material comprising manganese dioxide, the nickel oxyhydroxide includes a γ-type crystal structure, the content of nickel in the nickel oxyhydroxide is not less than 45 wt %, and the average particle diameter on a volume basis of the nickel oxyhydroxide measured with a laser diffraction particle size distribution analyzer is 3 to 20 μm.
摘要:
An alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, the positive electrode including a positive electrode material mixture containing a nickel oxyhydroxide, electrolytic manganese dioxide and a graphite conductive material, wherein the nickel oxyhydroxide includes a crystal having manganese dissolved therein and having a β type structure, and the amount of the manganese contained in the nickel oxyhydroxide is 0.5 to 10 mol % relative to the total amount of nickel and the manganese in the nickel oxyhydroxide.
摘要:
An alkaline battery of the present invention includes a positive electrode material mixture including nickel oxyhydroxide. The nickel oxyhydroxide includes a secondary particle with a crystal structure mainly composed of γ-type at least a portion of the surface layer of the secondary particle, and with a crystal structure mainly composed of β-type in the inner portion of the secondary particle. Based on the present invention, the advantage of the alkaline battery, i.e., excellence in discharge performance under high-load, can be kept and the conventional problem of storage characteristics can be improved.
摘要:
An alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, wherein the positive electrode includes a positive electrode material mixture including nickel oxyhydroxide, electrolytic manganese dioxide and expanded graphite, the expanded graphite has an average particle diameter on a volume basis of 5 to 25 μm, a BET specific surface area of 4 to 10 m2/g, and a bulk specific gravity (apparent density) measured by a static method of 0.03 to 0.10 g/cm3, the nickel oxyhydroxide has an average nickel valence of not less than 3.05, and a content of the expanded graphite in a total amount of the nickel oxyhydroxide, the electrolytic manganese dioxide and the expanded graphite that are included in the positive electrode material mixture of 3 to 15 wt %.
摘要翻译:一种包括正极,负极和碱性电解质的碱性电池,其中所述正极包括包含羟基氧化镍,电解二氧化锰和膨胀石墨的正极材料混合物,所述膨胀石墨的平均粒径基于 5〜25μm,BET比表面积为4〜10m 2 / g,静态法测定的体积比重(表观密度)为0.03〜0.10g / cm 2, 3,氢氧化正镍的平均镍价不小于3.05,膨胀石墨的含量在正极中包含的氢氧化正镍,电解二氧化锰和膨胀石墨的总量 电极材料混合物为3〜15重量%。
摘要:
Disclosed is an alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, (1) the positive electrode having a positive electrode material mixture containing electrolytic manganese doxide and nickel oxyhydroxide, (2) the nickel oxyhydroxide having a crystal in which at least Mg is dissolved, and (3) the nickel oxyhydroxide having a tap density determined after 500 taps of not less than 2 g/cm3, an average particle size based on volume of 8 to 20 μm, and an average nickel valence of 2.95 to 3.05.
摘要翻译:公开了一种包括正极,负极和碱性电解质的碱性电池,(1)正极具有含有电解锰氧化锰和氢氧化正镍的正极材料混合物,(2)具有晶体的氢氧化正镍, 溶解最少量的Mg,(3)在500次抽头后测定的振实密度不小于2g / cm 3的氢氧化正镍,基于体积为8〜20μm的平均粒径, 平均镍价为2.95〜3.05。
摘要:
An alkaline battery includes a positive electrode mixture, a negative electrode, and a separator interposed between the positive electrode mixture and the negative electrode. The positive electrode mixture contains a nickel oxyhydroxide, manganese dioxide and a conductive agent. (1) The nickel oxyhydroxide includes at least manganese dissolved therein, and the manganese accounts for 0.5 to 10% by mole of the total amount of metal elements contained in the nickel oxyhydroxide. (2) The nickel oxyhydroxide mainly has a β-type crystal structure. (3) The nickel oxyhydroxide has a volume-basis mean particle size of 8 to 15 μm. The use of this positive electrode mixture makes it possible to heighten the capacity of the alkaline battery and improve its storage characteristics. Also, the above-mentioned properties of the nickel oxyhydroxide including manganese enable a significant improvement in the productivity of the nickel oxyhydroxide.
摘要:
An alkaline battery of the present invention includes a positive electrode material mixture including nickel oxyhydroxide. The nickel oxyhydroxide includes a secondary particle with a crystal structure mainly composed of γ-type at at least a portion of the surface layer of the secondary particle, and with a crystal structure mainly composed of β-type in the inner portion of the secondary particle. Based on the present invention, the advantage of the alkaline battery, i.e., excellence in discharge performance under high-load, can be kept and the conventional problem of storage characteristics can be improved.
摘要:
This invention relates to an alkaline battery including: an electrode assembly composed of a positive electrode, a negative electrode, and a separator; a negative electrode current collector inserted in the negative electrode; an electrolyte of an alkaline aqueous solution contained in the electrode assembly; a battery can for accommodating the electrode assembly, the negative electrode current collector, and the electrolyte; and a sealing member for sealing an opening of the battery can. The ratio of the electrical capacity of the negative electrode to the electrical capacity of the positive electrode is 1.00 to 1.15. The volume obtained by subtracting the volume of the electrode assembly containing the electrolyte and the volume of the negative electrode current collector from the internal volume of the battery that is formed by the battery can and the sealing member constitutes 5 to 15% of the internal volume.
摘要:
An alkaline battery of this invention includes a positive electrode containing manganese dioxide powder and nickel oxyhydroxide powder with a mean particle size of 8 to 18 μm as positive electrode active materials and graphite powder with a mean particle size of 8 to 25 μm as a conductive material. The positive electrode contains 5 to 9 parts by weight of the graphite powder per 100 parts by weight of the positive electrode active materials.
摘要:
An alkaline battery comprising: a positive electrode mixture comprising manganese dioxide and nickel oxyhydroxide as active materials; a negative electrode comprising zinc as an active material; and an alkaline electrolyte, characterized in that the potential of the manganese dioxide relative to a mercury/mercury oxide electrode in a potassium hydroxide aqueous solution having a KOH concentration of 40 wt % is 270 mV or higher.