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公开(公告)号:US20240250301A1
公开(公告)日:2024-07-25
申请号:US18127524
申请日:2023-03-28
发明人: Dewen KONG , Haijing LIU , Si CHEN , Mengyan HOU , Mark W. VERBRUGGE
IPC分类号: H01M10/0567 , H01M4/36 , H01M4/58 , H01M4/583 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M50/46
CPC分类号: H01M10/0567 , H01M4/364 , H01M4/5825 , H01M4/583 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M50/46 , H01M2004/027 , H01M2300/0037 , H01M2300/0051
摘要: An electrochemical cell that cycles lithium ions includes a positive electrode that includes a positive electroactive material, a negative electrode that includes a silicon-containing negative electroactive material, a separating layer disposed between the positive electrode and the negative electrode, and an electrolyte that is in contact with at least one of the positive electroactive material, the negative electroactive material, and the separating layer. The electrolyte includes greater than or equal to about 0.1 wt. % to less than or equal to about 10 wt. % of a phosphite-type additive.
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公开(公告)号:US20230046608A1
公开(公告)日:2023-02-16
申请号:US17710900
申请日:2022-03-31
发明人: Qili SU , Zhe LI , Mengyan HOU , Yong LU , Haijing LIU
IPC分类号: H01M10/0565 , H01M10/0525 , H01M4/62
摘要: An electrochemical cell that cycles lithium ions is provided. The electrochemical cell includes a first electrode, a second electrode, and an electrolyte layer disposed between the first electrode and the second electrode. The first electrode includes a first plurality of solid-state electroactive material particles and a first polymeric gel electrolyte, where the first polymeric gel electrolyte includes a first additive. The second electrode includes a second plurality of solid-state electroactive material particles and a second polymeric gel electrolyte that is different from the first polymeric gel electrolyte, where the second polymeric gel electrolyte includes a second additive. The electrolyte layers include a third polymeric gel electrolyte that is different from both the first polymeric gel electrolyte and the second polymeric gel electrolyte.
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公开(公告)号:US20210020929A1
公开(公告)日:2021-01-21
申请号:US16514193
申请日:2019-07-17
发明人: Dewen KONG , Yong LU , Mengyan HOU , Zhe LI , Haijing LIU
摘要: Solid-state electrodes and methods of forming solid-state electrodes and batteries are provided. The method includes contacting an electrode precursor with a liquid. The liquid includes one or more precursors of an ionically conductive polymer. The electrode precursor includes a plurality of electroactive particles and a plurality of electrolyte particles disposed on a current collector. A plurality of interparticle pores exists between the electroactive and electrolyte particles. When the electrode precursor is contacted with the liquid, the liquid flows into the interparticle pores. The one or more precursors of the ionically conductive polymer are electropolymerized so as to cause the formation of a polymeric matrix (including the ionically conductive polymer) that surrounds and embeds the plurality of electroactive particles and the plurality of electrolyte particles so as to form the solid-state electrode.
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公开(公告)号:US20230246310A1
公开(公告)日:2023-08-03
申请号:US17696567
申请日:2022-03-16
发明人: Yong LU , Zhe LI , Mengyan HOU , Qili SU , Meiyuan WU , Xiaochao QUE , Haijing LIU , Si CHEN
IPC分类号: H01M50/543 , H01M10/0525 , H01M50/411 , H01M50/46 , H01M50/449 , H01M4/131 , H01M4/583
CPC分类号: H01M50/543 , H01M10/0525 , H01M50/411 , H01M50/46 , H01M50/449 , H01M4/131 , H01M4/583 , H01M2300/0082 , H01M2004/029
摘要: A high-power gel-assisted battery stack that cycles lithium ions is provided with two terminal electrodes having opposite polarities and at least one bipolar electrode assembly disposed therebetween. A first electrode is disposed on a first side of a bipolar current collector and a second electrode with an opposite polarity to the first electrode is disposed on a second side of the bipolar current collector. Each electrode includes a porous layer having an electroactive material and a solid-state electrolyte disposed in a polymeric binder. A polymer gel electrolyte is distributed in pores of the porous. The stack also includes at least two free-standing gel separator layers each being disposed between the at least one bipolar electrode assembly and terminal electrodes. Each respective free-standing gel separator layer comprises polyacrylonitrile (PAN) and an electrolyte distributed therein. The high-power gel-assisted battery stack has a maximum voltage rating of ≥about 12V.
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公开(公告)号:US20230231110A1
公开(公告)日:2023-07-20
申请号:US17882876
申请日:2022-08-08
发明人: Mengyan HOU , Haijing LIU , Xiaochao QUE , Meiyuan WU
IPC分类号: H01M4/36 , H01M4/38 , H01M10/0525 , H01M4/62 , H01M4/04
CPC分类号: H01M4/366 , H01M4/386 , H01M10/0525 , H01M4/625 , H01M4/0471 , H01M4/0416 , H01M2004/027
摘要: Negative electrodes for electrochemical cells that cycle lithium ions are provided. The negative electrodes comprise electroactive material particles that exhibit a core-shell structure defining a core made of a lithiated silicon-based material and a shell surrounding the core that is a bi-layer structure including first and second carbon coating layers. An electrical conductivity of the first carbon coating layer is greater than that of the second carbon coating layer. A method of manufacturing a negative electrode material is provided in which a first carbon coating layer is formed on an outer surface of a silicon-based precursor particle. The silicon-based precursor particle is exposed to a lithium source to form a lithiated silicon-based particle having the first carbon coating layer. A second carbon coating layer is formed on the first carbon coating layer over the lithiated silicon-based particle to form an electroactive material particle.
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公开(公告)号:US20230025830A1
公开(公告)日:2023-01-26
申请号:US17697135
申请日:2022-03-17
发明人: Qili SU , Mengyan HOU , Zhe LI , Haijing LIU
IPC分类号: H01M10/0585 , H01M4/04 , H01M4/36 , H01M4/62 , H01M10/0565
摘要: The present disclosure provides a method for forming a solid-state battery. The method includes stacking two or more cell units, where each cell unit is formed by substantially aligning a first electrode and a second electrode, where the first electrode includes one or more first electroactive material layers disposed on or adjacent to one or more surfaces of a releasable substrate and the second electrode includes one or more second electroactive material layers disposed on or adjacent to one or more surfaces of a current collector; disposing an electrolyte layer between exposed surfaces of the first electrode and the second electrode; and removing the releasable substrate to form the cell unit.
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公开(公告)号:US20230015143A1
公开(公告)日:2023-01-19
申请号:US17688445
申请日:2022-03-07
发明人: Qili SU , Mengyan HOU , Meiyuan WU , Haijing LIU
IPC分类号: H01M10/0562 , H01M10/0525 , H01M10/0583 , H01M10/04 , H01M4/04
摘要: A method for forming a solid-state battery is provided. The method includes disposing one or more cell units along a continuous current collector to form a stack precursor. In some examples, disposing of the one or more cell units along the continuous current collector includes concurrently disposing the one or more cell units along the continuous current collector and winding the continuous current collector to form a stack. In other examples, the continuous current collector is a z-folded current collector and the disposing the one or more cell units along the continuous current collector includes inserting the one or more cell units into one or more pockets formed by folds of the continuous current collector. The method may further include applying heat, pressure, or a combination of heat and pressure to the stack precursor to form a compressed stack, and cutting the continuous current collector to form the solid-state battery.
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公开(公告)号:US20230072660A1
公开(公告)日:2023-03-09
申请号:US17560673
申请日:2021-12-23
发明人: Qili SU , Zhe LI , Meiyuan WU , Mengyan HOU , Haijing LIU
IPC分类号: H01M4/78
摘要: A battery includes positive and negative current collectors and a plurality of bipolar electrodes arranged in a stack between the positive and negative current collectors. The positive and negative current collectors and the stack of the plurality of bipolar electrodes are folded in an S-shape.
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公开(公告)号:US20220263055A1
公开(公告)日:2022-08-18
申请号:US17550507
申请日:2021-12-14
发明人: Mengyan HOU , Qili SU , Meiyuan WU , Haijing LIU
IPC分类号: H01M4/04 , H01M10/0585 , H01M10/0565
摘要: A method for forming a bipolar solid-state battery may include preparing a plurality of freestanding gels each comprising a polymer, a solvent, and a lithium salt and, also, positioning a first freestanding gel between a first electrode and a second electrode and a second freestanding gel between the second electrode and a third electrode. Each of the first electrode, the second electrode, and the third electrode may include a plurality of electroactive particles. The method may also include infiltrating at least a portion of the first free-standing gel into a space between particles of the first electrode and the second electrode and at least a portion of the second free-standing gel into a space between the particles of second electrode and the third electrode.
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公开(公告)号:US20210135224A1
公开(公告)日:2021-05-06
申请号:US17084782
申请日:2020-10-30
发明人: Mengyan HOU , Haijing LIU , Qili SU , Xiaochao QUE
摘要: A hybrid electrochemical device including at least two electrically connected solid-state electrochemical cells is provided. Each electrochemical cell includes a first outer electrode having a first current collector and a first electroactive layer, a second outer electrode having a second current collector and a second electroactive layer, and one or more intervening electrodes disposed between the electroactive layers. At least one of the intervening electrodes includes one or more capacitor additives. The first outer electrode is electrically connected to at least one of the intervening electrodes in a first electrical configuration. The second outer electrode is electrically connected to at least one of the intervening electrodes in a second electrical configuration. The at least two electrochemical cells are electrically connected in a third electrical configuration. The first and second electrical configurations are the same and the third electrical configuration is distinct from the first and second electrical configurations.
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