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公开(公告)号:US20240079594A1
公开(公告)日:2024-03-07
申请号:US17981128
申请日:2022-11-04
发明人: Qili SU , Zhe LI , Yong LU , Haijing LIU
IPC分类号: H01M4/62 , H01M4/139 , H01M10/0525 , H01M10/0562
CPC分类号: H01M4/623 , H01M4/139 , H01M10/0525 , H01M10/0562 , H01M2004/021
摘要: In various aspects, the present disclosure provides solvent-free methods of making a solid-state electrode active layer for a solid-state electrode in an electrochemical cell that cycles lithium ions, by using a plurality of solid polymeric binder particles capable of fibrillation with porous fibrillation particles with a first shear force to at least partially fibrillate the solid polymeric binder particles to form a polymeric binder mixture. The disclosure also contemplates a current collector and a porous active layer disposed thereon. The porous active layer includes a fibrous polymeric network having a plurality of solid particles distributed therein. The solid particles may include electroactive material particles, solid-state electrolyte particles, and porous fibrillation particles.
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公开(公告)号:US20240021866A1
公开(公告)日:2024-01-18
申请号:US17941299
申请日:2022-09-09
发明人: Zhe LI , Qili SU , Jingyuan LIU , Haijing LIU , Mark W. VERBRUGGE
IPC分类号: H01M10/0562 , H01M10/0525 , H01M50/449
CPC分类号: H01M10/0562 , H01M10/0525 , H01M50/449 , H01M2300/0068 , H01M2300/0077
摘要: The present disclosure provides an electrochemical cell that cycles lithium ions. The electrochemical cell includes a first electrode, a second electrode, a separator physically separating the first and second electrodes, a solid-state interlayer disposed between the separator and the first electrode, and a liquid electrolyte disposed in each of the first electrode, the second electrode, the separator, and the solid-state interlayer. The solid-state interlayer includes a plurality of solid-state electrolyte particles. The solid-state interlayer covers greater than or equal to about 85% of a total surface area of the surface of the first electrode.
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公开(公告)号:US20240014440A1
公开(公告)日:2024-01-11
申请号:US17900048
申请日:2022-08-31
发明人: Qili SU , Zhe LI , Haijing LIU , Lidan XING , Lijiao QUAN
IPC分类号: H01M10/0565
CPC分类号: H01M10/0565 , H01M10/0525
摘要: The present disclosure a gel polymer electrolyte for an electrochemical cell that cycles lithium ions. The gel polymer electrolyte includes a polymer host, a liquid electrolyte, and greater than or equal to about 0.1 wt. % to less than or equal to about 10 wt. % of a sulfolene additive. In certain variations, the gel polymer electrolyte also includes greater than or equal to about 0.1 wt. % to less than or equal to about 5 wt. % of an ethylene carbonate additive. The ethylene carbonate additive may be selected from the group consisting of: vinyl ethylene carbonate (VEC), fluoroethylene carbonate (FEC), vinylene carbonate, and combinations thereof. In each instance, the lithium electrolyte may include a first lithium salt, a second lithium salt that is distinct from the first lithium salt, and a third lithium salt that is distinct from the first lithium salt and the second lithium salt.
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公开(公告)号:US20220263129A1
公开(公告)日:2022-08-18
申请号:US17556175
申请日:2021-12-20
IPC分类号: H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M10/0567 , H01M10/0525
摘要: An electrolyte composition is provided. The electrolyte composition includes a solvate ionic liquid having an anion and a complex of an ether and a cation, and a diluter including a phosphorus-containing flame-retardant having a dielectric constant of less than or equal to about 20.
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公开(公告)号:US20240283057A1
公开(公告)日:2024-08-22
申请号:US18360086
申请日:2023-07-27
发明人: Yong LU , Zhe Li , Qili SU , Dave G. RICH , Haijing LIU
IPC分类号: H01M12/02
CPC分类号: H01M12/02 , H01M2300/0085
摘要: A solid-state battery cell includes an anode electrode comprising an anode current collector and an anode coating. A cathode electrode comprises a cathode current collector and a cathode coating, wherein the anode electrode and the cathode electrode exchange lithium ions. A separator layer is arranged between the anode electrode and the cathode electrode. A first capacitor electrode is arranged at least one of between the anode coating and a first side of the separator layer, between the anode coating and the anode current collector, between a second side of the separator layer and the cathode coating, and between the cathode coating and the cathode current collector.
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公开(公告)号:US20240234812A1
公开(公告)日:2024-07-11
申请号:US18232899
申请日:2023-08-11
发明人: Zhe LI , Qili SU , Haijing LIU , Shiguo ZHANG , Minghan ZHOU
IPC分类号: H01M10/0567 , H01M10/052 , H01M10/0568 , H01M10/0569
CPC分类号: H01M10/0567 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M2300/0028 , H01M2300/0091
摘要: An anode-free electrochemical cell that cycles lithium ions includes a positive electrode assembly having a positive current collector and a positive electroactive material layer, a negative current collector that includes a surface configured to receive a negative electroactive material after one or more formation cycles of the anode-free electrochemical cell, and a separating layer disposed between the positive electroactive material layer and the surface of the negative current collector. The separating layer includes an electrolyte that includes greater than or equal to about 20 wt. % to less than or equal to about 99.5 wt. % of a concentrated electrolyte having a lithium salt concentration greater than or equal to about 2 M to less than or equal to about 6 M, and greater than or equal to about 0.5 wt. % to less than or equal to about 80 wt. % of an ionic liquid.
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公开(公告)号:US20240154104A1
公开(公告)日:2024-05-09
申请号:US18363036
申请日:2023-08-01
发明人: Zhe LI , Xingcheng XIAO , Qili SU , Yong LU , Haijing LIU
IPC分类号: H01M4/38 , H01M10/0525 , H01M10/0562 , H01M10/058
CPC分类号: H01M4/386 , H01M10/0525 , H01M10/0562 , H01M10/058 , H01M2300/008
摘要: A battery cell includes an anode electrode comprising a first current collector. Anode active material is arranged on a first surface of the first current collector and is configured to exchange lithium ions. The anode active material comprises silicon. Empty spaces are formed in the anode active material in a predetermined pattern. A solid electrolyte layer is arranged adjacent to the anode electrode. A cathode electrode comprises a second current collector and cathode active material configured to exchange lithium ions and arranged adjacent to the solid electrolyte layer.
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公开(公告)号:US20230317966A1
公开(公告)日:2023-10-05
申请号:US17853690
申请日:2022-06-29
发明人: Zhe LI , Qi LU , Yong LU , Meiyuan WU , Qili SU , Haijing LIU
IPC分类号: H01M4/76 , H01M10/0525 , H01M10/0562 , H01M10/44 , H01M4/62 , H01M4/134
CPC分类号: H01M4/762 , H01M10/0525 , H01M10/0562 , H01M2004/027 , H01M4/626 , H01M4/625 , H01M4/134 , H01M10/44
摘要: An electrochemical cell that cycles lithium ions includes a positive electrode, a negative electrode current collector spaced apart from the positive electrode, and an ionically conductive electrolyte disposed between the positive electrode and the negative electrode current collector. The negative electrode current collector is of unitary one-piece construction and has a three-dimensional porous structure that defines an interconnected network of open pores. During charging of the electrochemical cell, lithium metal is deposited within the open pores of the negative electrode current collector.
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公开(公告)号:US20230253617A1
公开(公告)日:2023-08-10
申请号:US17884239
申请日:2022-08-09
发明人: Zhe LI , Qili SU , Meiyuan WU , Haijing LIU
IPC分类号: H01M10/0565 , H01M4/505 , H01M4/583
CPC分类号: H01M10/0565 , H01M4/505 , H01M4/583 , H01M2300/0085 , H01M2300/0082 , H01M2300/0028
摘要: A polymeric gel electrolyte for an electrochemical cell, such as a solid-state battery, is provided herein as well an electrochemical cell including the polymeric gel electrolyte. The polymeric gel electrolyte includes one or more lithium salts, a plasticizer component, an additive component, and a polymeric host. Examples of the plasticizer component include a carbonate, a lactone, a nitrile, a sulfone, an ether, a phosphate, and combinations thereof. The additive component includes a boron-containing additive and a carbonate-containing additive.
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公开(公告)号:US20230246172A1
公开(公告)日:2023-08-03
申请号:US17746575
申请日:2022-05-17
发明人: Zhe LI , Qili SU , Yong LU , Meiyuan WU , Haijing LIU
IPC分类号: H01M4/36 , H01M4/62 , H01M10/0565 , H01M4/58 , H01M10/0525
CPC分类号: H01M4/366 , H01M4/62 , H01M10/0565 , H01M4/5815 , H01M10/0525 , H01M2004/028
摘要: A positive electrode including an active layer is provided, where the active layer includes a plurality of positive electroactive solid-state particles, a lithium-source material coated on or dispersed with the positive electroactive solid-state particles in the active layer, and a polymeric gel electrolyte at least partially filling voids between the positive electroactive solid-state particles in the active layer. The lithium-source material having a theoretical specific capacity greater than or equal to about 100 mAh/g to less than or equal to about 3,000 mAh/g.
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