摘要:
A battery includes S battery cells of a first type. Each of the S battery cells includes a plurality of first cathode electrodes and a plurality of first anode electrodes. The battery includes T battery cells of a second type, wherein each of the T battery cells includes a plurality of second cathode electrodes and a plurality of second anode electrodes, where S and T are integers greater than one. The T battery cells are arranged between the S battery cells. At least one of the plurality of first cathode electrodes includes a first cathode active material that is different than a second cathode active material of the plurality of second cathode electrodes. The plurality of first anode electrodes includes a first anode active material that is different than a second anode active material of the plurality of second anode electrodes.
摘要:
A method for fabricating a dual-layer capacitive cabode electrode includes fabricating a first film including capacitive active material; fabricating a second film including cathode active material; hot jointing the first film and the second film to create a cabode film; and laminating the cabode film onto opposite sides of a current collector using conductive adhesive.
摘要:
A rechargeable lithium-ion battery is provided that includes a positive electrode with a positive electroactive material that in a charged state includes lithium iron (II) orthosilicate (Li2FeSiO4) and in a discharged state includes FeSiO4 or LiFeSiO4. A negative electrode includes phosphorene. A separator is disposed between the positive and negative electrodes. An electrolyte has an organic solvent especially containing ether-based organic solvents and a lithium salt that provides a conductive medium for lithium ions to transfer between the positive electrode and the negative electrode. Such a rechargeable lithium-ion battery provides advantageous power delivery, long driving ranges, and fast charge to enhance widespread use of batteries, especially in vehicles. Furthermore, lithium plating can be minimized or avoided, even at low temperature charging. Methods of recharging a rechargeable lithium-ion battery at low temperatures are also provided.
摘要:
A battery and supercapacitor system of a vehicle includes a lithium ion battery (LIB) disposed within a housing. The LIB includes: an electrolyte including lithium; and first and second electrodes disposed in the electrolyte. A supercapacitor is disposed within the housing and includes: the electrolyte; and third and fourth electrodes disposed in the electrolyte.
摘要:
An electrochemical device according to various aspects of the present disclosure includes an electrochemical cell and an inductor coil. The electrochemical cell includes a current collector. the current collector includes an electrically-conductive material. The inductor coil is configured to generate a magnetic field. The magnetic field is configured to induce an eddy current in the current collector to generate heat in the current collector. In various aspects, the present disclosure also provides a method of internally heating an electrochemical cell. In various aspects, the present disclosure also provides a method of controlling heating of an electrochemical cell.
摘要:
A method of making a negative electrode material for an electrochemical cell that cycles lithium ions is provided that includes centrifugally distributing a molten precursor comprising silicon and lithium by contacting the molten precursor with a rotating surface in a centrifugal atomizing reactor. The molten precursor is solidified to form a plurality of substantially round solid electroactive particles comprising an alloy of lithium and silicon and having a D50 diameter of less than or equal to about 20 micrometers. In certain variations, the negative electroactive material particles may further have one or more coatings disposed thereon, such as a carbonaceous coating and/or an oxide-based coating.
摘要:
A capacitor-assisted electrode for an electrochemical cell that cycles lithium ions is provided. The capacitor-assisted electrode may include at least two electroactive materials disposed on one or more surfaces of a current collector. A first electroactive material of the at least two electroactive materials may have a first reversible specific capacity and forms a first electroactive material having a first press density. A second electroactive material of the at least two electroactive materials has a second reversible specific capacity and forms a second electroactive material having a second press density. The second reversible specific capacity may be different from the first reversible specific capacity. The second press density may be different from the first press density. One or more capacitor materials may be disposed on or intermingled with one or more of the at least two electroactive materials.
摘要:
The present disclosure provides methods of compensation for capacity loss resulting from cycle-induced lithium consumption in an electrochemical cell including at least one electrode. Such methods may include adding a lithiation additive to the at least one electrode so as to create a lithium source. The lithium source compensates for cycle-induced lithiation loss such that the electrochemical cell having the lithiation additive experiences total capacity losses of less than or equal to about 5% of an initial capacity prior to cycling of lithium. The lithiation additive includes a lithium silicate represented by the formula LiuHr, where Hr=Liy-uSiOz and where 0≤y≤3.75 and 0≤z≤2 and u is a useable portion of y, 0≤u≤y. The lithium source may include z/4 Li4SiO4 and LimSi, where 0≤m≤4.4.
摘要:
An electroactive material for use in an electrochemical cell, like a lithium ion battery, is provided. The electroactive material comprises a multifunctional hybrid protective coating system formed over an electroactive material. The coating system includes a first oxide-based coating disposed on one or more surfaces of the electroactive material, followed by a second coating deposited via a non-aqueous process. The second coating may be a fluoride-based, nitride-based, or carbide-based coating. The first and second coatings may be applied by atomic layer deposition (ALD) to form conformal ultrathin layers over the electroactive materials. Such a multifunctional hybrid protective coating system can suppress formation of gases within the electrochemical cell and also minimize formation of solid electrolyte interface (SEI) layers on the electrode to improve battery performance. Methods for making such materials and using such materials in electrochemical cells are likewise provided.
摘要:
A battery system includes: a battery cell; and a temperature sensing array disposed on a surface of the battery cell, the temperature sensing array including: a conducting strip; and a plurality of temperature sensors connected in series with the conducting strip such that current flowing through the conducting strip flows through each of the temperature sensors, where each of the plurality of temperature sensors has at least one characteristic that varies in accordance with temperature, where the plurality of temperature sensors is distributed in different locations across the surface of the battery cell, and where an output current of the temperature sensing array varies in accordance with a change in temperature in any of the different locations.