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1.发明申请公开(公告)号：US20120065452A1
公开(公告)日：2012-03-15
申请号：US13228309
申请日：2011-09-08
申请人： GUIDO HENZE , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
发明人： GUIDO HENZE , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
CPC分类号： B01J20/3078 , B01D2251/602 , B01D2257/502 , B01J20/0211 , B01J20/0237 , B01J20/0244 , B01J20/06 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/42 , C07C7/12 , C07C11/02
摘要： The invention relates to a process for the activation of a copper, zinc and zirconium oxide-comprising adsorption composition for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin wherein (i) in a first activation step an activation gas mixture comprising the olefin and an inert gas is passed through the adsorption composition, and (ii) in a second activation step the adsorption composition is heated to a temperature in the range from 180 to 300° C. and an inert gas is passed through it, wherein the steps (i) and (ii) can each be performed several times.
摘要翻译： 本发明涉及用于活化含铜，锌和氧化锆的吸附组合物的方法，用于从包含一氧化碳和至少一种烯烃的物流中吸附除去一氧化碳，其中（i）在第一活化步骤中，活化 包含烯烃和惰性气体的气体混合物通过吸附组合物，和（ii）在第二活化步骤中，将吸附组合物加热到180-300℃的温度，并使惰性气体通过 其中，步骤（i）和（ii）可以分别进行几次。
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2.发明授权公开(公告)号：US08637724B2
公开(公告)日：2014-01-28
申请号：US13228296
申请日：2011-09-08
申请人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
发明人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
IPC分类号： C07C7/12
CPC分类号： B01J20/3458 , B01J20/06 , B01J20/3078 , B01J20/3085 , B01J20/3483 , B01J2220/42 , C07C7/12 , C10G25/003 , C10G25/12 , C10G2400/20 , C07C11/06
摘要： The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composition is heated to a temperature in the range from 160 to 400° C. and a regeneration gas is passed through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas.
摘要翻译： 本发明涉及一种用于在其使用之后再生含铜，锌和氧化锆的吸附组合物用于从包含一氧化碳和至少一种烯烃的物质流吸附除去一氧化碳的方法，其中吸附组合物 加热至160〜400℃的温度，再生气体通过吸附组合物，再生气体在惰性载气中含有1000〜3000ppm的氧气。
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3.发明授权Process for the activation of a copper-, zinc- and zirconium oxide-comprising adsorption composition 有权用于活化含铜，锌和氧化锆的吸附组合物的方法公开(公告)号：US08637723B2
公开(公告)日：2014-01-28
申请号：US13228309
申请日：2011-09-08
申请人： Guido Henze , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
发明人： Guido Henze , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
IPC分类号： C07C7/12
CPC分类号： B01J20/3078 , B01D2251/602 , B01D2257/502 , B01J20/0211 , B01J20/0237 , B01J20/0244 , B01J20/06 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/42 , C07C7/12 , C07C11/02
摘要： The invention relates to a process for the activation of a copper, zinc and zirconium oxide-comprising adsorption composition for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin wherein (i) in a first activation step an activation gas mixture comprising the olefin and an inert gas is passed through the adsorption composition, and (ii) in a second activation step the adsorption composition is heated to a temperature in the range from 180 to 300° C. and an inert gas is passed through it, wherein the steps (i) and (ii) can each be performed several times.
摘要翻译： 本发明涉及用于活化含铜，锌和氧化锆的吸附组合物的方法，用于从包含一氧化碳和至少一种烯烃的物流中吸附除去一氧化碳，其中（i）在第一活化步骤中，活化 包含烯烃和惰性气体的气体混合物通过吸附组合物，和（ii）在第二活化步骤中，将吸附组合物加热到180-300℃的温度，并使惰性气体通过 其中，步骤（i）和（ii）可以分别进行几次。
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4.发明申请公开(公告)号：US20140155255A1
公开(公告)日：2014-06-05
申请号：US14134660
申请日：2013-12-19
申请人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
发明人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
IPC分类号： B01J20/34
CPC分类号： B01J20/3458 , B01J20/06 , B01J20/3078 , B01J20/3085 , B01J20/3483 , B01J2220/42 , C07C7/12 , C10G25/003 , C10G25/12 , C10G2400/20 , C07C11/06
摘要： The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composition is heated to a temperature in the range from 160 to 400° C. and a regeneration gas is passed through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas.
摘要翻译： 本发明涉及一种用于在其使用之后再生含铜，锌和氧化锆的吸附组合物用于从包含一氧化碳和至少一种烯烃的物质流吸附除去一氧化碳的方法，其中吸附组合物 加热至160〜400℃的温度，再生气体通过吸附组合物，再生气体在惰性载气中含有1000〜3000ppm的氧气。
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5.发明申请公开(公告)号：US20120065451A1
公开(公告)日：2012-03-15
申请号：US13228296
申请日：2011-09-08
申请人： GUIDO HENZE , Lothar Karrer , Heiko Urtel , Stephan Hatscher
发明人： GUIDO HENZE , Lothar Karrer , Heiko Urtel , Stephan Hatscher
CPC分类号： B01J20/3458 , B01J20/06 , B01J20/3078 , B01J20/3085 , B01J20/3483 , B01J2220/42 , C07C7/12 , C10G25/003 , C10G25/12 , C10G2400/20 , C07C11/06
摘要： The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composition is heated to a temperature in the range from 160 to 400° C. and a regeneration gas is passed through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas.
摘要翻译： 本发明涉及一种用于在其使用之后再生含铜，锌和氧化锆的吸附组合物用于从包含一氧化碳和至少一种烯烃的物质流吸附除去一氧化碳的方法，其中吸附组合物 加热至160〜400℃的温度，再生气体通过吸附组合物，再生气体在惰性载气中含有1000〜3000ppm的氧气。
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6.发明申请公开(公告)号：US20140117281A1
公开(公告)日：2014-05-01
申请号：US14134385
申请日：2013-12-19
申请人： Guido Henze , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
发明人： Guido Henze , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
IPC分类号： B01J20/30
CPC分类号： B01J20/3078 , B01D2251/602 , B01D2257/502 , B01J20/0211 , B01J20/0237 , B01J20/0244 , B01J20/06 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/42 , C07C7/12 , C07C11/02
摘要： A process for the activation of a copper, zinc and zirconium oxide-comprising adsorption composition for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin wherein: (i) in a first activation step an activation gas mixture comprising the olefin and an inert gas is passed through the adsorption composition; and (ii) in a second activation step the adsorption composition is heated to a temperature in the range from 180 to 300° C. and an inert gas is passed through it, wherein the steps (i) and (ii) can each be performed several times.
摘要翻译： 一种用于从包含一氧化碳和至少一种烯烃的物流中吸附除去一氧化碳的含铜，锌和氧化锆的吸附组合物的方法，其中：（i）在第一活化步骤中，将活化气体混合物包括 使烯烃和惰性气体通过吸附组合物; 和（ii）在第二活化步骤中，将吸附组合物加热到180-300℃的温度，并使惰性气体通过，其中步骤（i）和（ii）可以各自进行 几次。
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公开(公告)号：US20090098037A1
公开(公告)日：2009-04-16
申请号：US12279368
申请日：2007-02-07
CPC分类号： B01J23/80 , B01D53/02 , B01D53/865 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/56
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper, zinc and zirconium oxides and whose copper-comprising component has a degree of reduction, expressed as weight ratio of metallic copper to the sum of metallic copper and copper oxides, calculated as CuO, of at least 45% and not more than 75%.
摘要翻译： 通过在包含铜，锌和锆的氧化物的吸附组合物上吸附除去一氧化碳，并且其含铜组分具有减少程度，以金属铜与金属铜和铜氧化物之和的重量比表示，计算 作为CuO，为至少45％且不大于75％。
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公开(公告)号：US07781368B2
公开(公告)日：2010-08-24
申请号：US12279368
申请日：2007-02-07
CPC分类号： B01J23/80 , B01D53/02 , B01D53/865 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/56
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper, zinc and zirconium oxides and whose copper-comprising component has a degree of reduction, expressed as weight ratio of metallic copper to the sum of metallic copper and copper oxides, calculated as CuO, of at least 45% and not more than 75%.
摘要翻译： 通过在包含铜，锌和锆的氧化物的吸附组合物上吸附除去一氧化碳，并且其含铜组分具有减少程度，以金属铜与金属铜和铜氧化物之和的重量比表示，计算 作为CuO，为至少45％且不大于75％。
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9.发明授权公开(公告)号：US07884048B2
公开(公告)日：2011-02-08
申请号：US12833431
申请日：2010-07-09
CPC分类号： B01J23/80 , B01D53/02 , B01D53/865 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/56
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper, zinc and zirconium oxides and whose copper-comprising component has a degree of reduction, expressed as weight ratio of metallic copper to the sum of metallic copper and copper oxides, calculated as CuO, of at least 45% and not more than 75%.
摘要翻译： 通过在包含铜，锌和锆的氧化物的吸附组合物上吸附除去一氧化碳，并且其含铜组分具有减少程度，以金属铜与金属铜和铜氧化物之和的重量比表示，计算 作为CuO，为至少45％且不大于75％。
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10.发明申请公开(公告)号：US20100273640A1
公开(公告)日：2010-10-28
申请号：US12833431
申请日：2010-07-09
CPC分类号： B01J23/80 , B01D53/02 , B01D53/865 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/56
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper, zinc and zirconium oxides and whose copper-comprising component has a degree of reduction, expressed as weight ratio of metallic copper to the sum of metallic copper and copper oxides, calculated as CuO, of at least 45% and not more than 75%.
摘要翻译： 通过在包含铜，锌和锆的氧化物的吸附组合物上吸附除去一氧化碳，并且其含铜组分具有减少程度，以金属铜与金属铜和铜氧化物之和的重量比表示，计算 作为CuO，为至少45％且不大于75％。
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