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公开(公告)号：US20090281365A1
公开(公告)日：2009-11-12
申请号：US12305450
申请日：2007-06-15
申请人： Stephan Hatscher , Michael Hesse
发明人： Stephan Hatscher , Michael Hesse
CPC分类号： B01D53/864 , B01D53/02 , B01D2253/112 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J21/066 , B01J23/72 , B01J37/0009 , B01J37/03 , B01J2220/42 , B01J2220/56 , C07C7/12 , C10K1/32 , C10K3/04 , Y02P20/52 , C07C11/06
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper and zirconium oxides but no zinc oxide, which comprises from 70 to 99.8% by weight of copper oxide and from 0.2 to 30% by weight of zirconium oxide, based on the total amount of the adsorption composition.
摘要翻译： 通过在包含铜和锆氧化物但不含氧化锌的吸附组合物上吸附一氧化碳，其包含70至99.8重量％的氧化铜和0.2至30重量％的氧化锆，基于 吸附组合物的总量。
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2.发明申请METHOD FOR THE PRODUCTION OF POLYTETRAHYDROFURANE OR TETRAHYDROFURANE COPOLYMERS 有权聚四氢呋喃或四氢呋喃共聚物的制备方法公开(公告)号：US20090215971A1
公开(公告)日：2009-08-27
申请号：US12303491
申请日：2007-05-25
CPC分类号： C08G65/20
摘要： The present invention relates to a process for preparing polytetrahydrofuran or tetrahydrofuran copolymers by polymerization of tetrahydrofuran in the presence of a telogen and/or a comonomer over a fixed bed of an acid catalyst, in which the temperature of the polymerization mixture increases in the direction of flow through the catalyst bed.
摘要翻译： 本发明涉及在四氢呋喃的存在下，在酸催化剂的固定床上，在四氢呋喃和/或共聚单体存在下聚合制备聚四氢呋喃或四氢呋喃共聚物的方法，其中聚合混合物的温度在 流过催化剂床。
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公开(公告)号：US20080281116A1
公开(公告)日：2008-11-13
申请号：US12096619
申请日：2006-12-12
IPC分类号： C07F5/06
CPC分类号： B01J31/1691 , B01J20/226 , B01J39/26 , B01J45/00 , B01J2231/49 , C07C51/418 , C07F5/069 , C07C63/28
摘要： The present invention relates to porous metal organic frameworks comprising at least one at least bidentate organic compound L coordinated to at least one metal ion M, wherein L has at least one functional group G which bonds noncoordinatively to M and is selected from the group consisting of —SO3H and —PO3H2 and their analogues. The invention further provides processes for their preparation and also their use.
摘要翻译： 本发明涉及包含至少一种与至少一种金属离子M配位的至少二齿有机化合物L的多孔金属有机骨架，其中L具有至少一个官能团G，其与M非键合键合并选自 -SO 3 H和-PO 3 H 2 H 2和它们的类似物。 本发明进一步提供了它们的制备方法及其应用。
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公开(公告)号：US08858691B2
公开(公告)日：2014-10-14
申请号：US14061807
申请日：2013-10-24
申请人： Stephan Hatscher
发明人： Stephan Hatscher
IPC分类号： B01D53/02
CPC分类号： B01J20/28083 , B01D53/04 , B01D53/82 , B01D53/8603 , B01D2253/112 , B01D2253/311 , B01D2255/20761 , B01D2255/9205 , B01D2257/20 , B01D2257/30 , B01D2257/304 , B01D2257/306 , B01D2257/308 , C10L3/10 , C10L3/102 , H01M8/0675
摘要： The invention relates to adsorbents for removing impurities from water-comprising gas streams, in particular for use in fuel cell systems, wherein the adsorbents comprise oxides of elements selected from the group consisting of Cu, Fe, Zn, Ni, Co, Mn, Mg, Ba, Zr, Ce, La or combinations of these elements, have a copper oxide content of at least 30% by weight and have pore volumes of less than 0.175 ml·g−1 for pores having a radius of less than 20 nm.
摘要翻译： 本发明涉及用于从含水气流中除去杂质的吸附剂，特别是用于燃料电池系统中的吸附剂，其中吸附剂包括选自Cu，Fe，Zn，Ni，Co，Mn，Mg ，Ba，Zr，Ce，La或这些元素的组合，对于半径小于20nm的孔，其氧化铜含量为至少30重量％，孔体积小于0.175ml·g-1。
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5.发明授权公开(公告)号：US08637724B2
公开(公告)日：2014-01-28
申请号：US13228296
申请日：2011-09-08
申请人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
发明人： Guido Henze , Lothar Karrer , Heiko Urtel , Stephan Hatscher
IPC分类号： C07C7/12
CPC分类号： B01J20/3458 , B01J20/06 , B01J20/3078 , B01J20/3085 , B01J20/3483 , B01J2220/42 , C07C7/12 , C10G25/003 , C10G25/12 , C10G2400/20 , C07C11/06
摘要： The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composition is heated to a temperature in the range from 160 to 400° C. and a regeneration gas is passed through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas.
摘要翻译： 本发明涉及一种用于在其使用之后再生含铜，锌和氧化锆的吸附组合物用于从包含一氧化碳和至少一种烯烃的物质流吸附除去一氧化碳的方法，其中吸附组合物 加热至160〜400℃的温度，再生气体通过吸附组合物，再生气体在惰性载气中含有1000〜3000ppm的氧气。
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6.发明授权Process for the activation of a copper-, zinc- and zirconium oxide-comprising adsorption composition 有权用于活化含铜，锌和氧化锆的吸附组合物的方法公开(公告)号：US08637723B2
公开(公告)日：2014-01-28
申请号：US13228309
申请日：2011-09-08
申请人： Guido Henze , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
发明人： Guido Henze , Lothar Karrer , David J. Artrip , Heiko Urtel , Stephan Hatscher
IPC分类号： C07C7/12
CPC分类号： B01J20/3078 , B01D2251/602 , B01D2257/502 , B01J20/0211 , B01J20/0237 , B01J20/0244 , B01J20/06 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/42 , C07C7/12 , C07C11/02
摘要： The invention relates to a process for the activation of a copper, zinc and zirconium oxide-comprising adsorption composition for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin wherein (i) in a first activation step an activation gas mixture comprising the olefin and an inert gas is passed through the adsorption composition, and (ii) in a second activation step the adsorption composition is heated to a temperature in the range from 180 to 300° C. and an inert gas is passed through it, wherein the steps (i) and (ii) can each be performed several times.
摘要翻译： 本发明涉及用于活化含铜，锌和氧化锆的吸附组合物的方法，用于从包含一氧化碳和至少一种烯烃的物流中吸附除去一氧化碳，其中（i）在第一活化步骤中，活化 包含烯烃和惰性气体的气体混合物通过吸附组合物，和（ii）在第二活化步骤中，将吸附组合物加热到180-300℃的温度，并使惰性气体通过 其中，步骤（i）和（ii）可以分别进行几次。
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公开(公告)号：US08597407B2
公开(公告)日：2013-12-03
申请号：US13140072
申请日：2009-12-10
申请人： Stephan Hatscher
发明人： Stephan Hatscher
IPC分类号： B01D53/02
CPC分类号： B01J20/28083 , B01D53/04 , B01D53/82 , B01D53/8603 , B01D2253/112 , B01D2253/311 , B01D2255/20761 , B01D2255/9205 , B01D2257/20 , B01D2257/30 , B01D2257/304 , B01D2257/306 , B01D2257/308 , C10L3/10 , C10L3/102 , H01M8/0675
摘要： The invention relates to adsorbents for removing impurities from water-comprising gas streams, in particular for use in fuel cell systems, wherein the adsorbents comprise oxides of elements selected from the group consisting of Cu, Fe, Zn, Ni, Co, Mn, Mg, Ba, Zr, Ce, La or combinations of these elements, have a copper oxide content of at least 30% by weight and have pore volumes of less than 0.175 ml·g−1 for pores having a radius of less than 20 nm.
摘要翻译： 本发明涉及用于从含水气流中除去杂质的吸附剂，特别是用于燃料电池系统中的吸附剂，其中吸附剂包括选自Cu，Fe，Zn，Ni，Co，Mn，Mg ，Ba，Zr，Ce，La或这些元素的组合，对于半径小于20nm的孔，其氧化铜含量为至少30重量％，孔体积小于0.175ml·g-1。
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8.发明授权Method for the production of polytetrahydrofurane or tetrahydrofurane copolymers 有权生产聚四氢呋喃或四氢呋喃共聚物的方法公开(公告)号：US08030439B2
公开(公告)日：2011-10-04
申请号：US12303491
申请日：2007-05-25
IPC分类号： C08G59/00
CPC分类号： C08G65/20
摘要： The present invention relates to a process for preparing polytetrahydrofuran or tetrahydrofuran copolymers by polymerization of tetrahydrofuran in the presence of a telogen and/or a comonomer over a fixed bed of an acid catalyst, in which the temperature of the polymerization mixture increases in the direction of flow through the catalyst bed.
摘要翻译： 本发明涉及在四氢呋喃的存在下，在酸催化剂的固定床上，在四氢呋喃和/或共聚单体存在下聚合制备聚四氢呋喃或四氢呋喃共聚物的方法，其中聚合混合物的温度在 流过催化剂床。
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公开(公告)号：US07781368B2
公开(公告)日：2010-08-24
申请号：US12279368
申请日：2007-02-07
CPC分类号： B01J23/80 , B01D53/02 , B01D53/865 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/56
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper, zinc and zirconium oxides and whose copper-comprising component has a degree of reduction, expressed as weight ratio of metallic copper to the sum of metallic copper and copper oxides, calculated as CuO, of at least 45% and not more than 75%.
摘要翻译： 通过在包含铜，锌和锆的氧化物的吸附组合物上吸附除去一氧化碳，并且其含铜组分具有减少程度，以金属铜与金属铜和铜氧化物之和的重量比表示，计算 作为CuO，为至少45％且不大于75％。
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10.发明申请公开(公告)号：US20090312588A1
公开(公告)日：2009-12-17
申请号：US12374191
申请日：2007-07-05
申请人： Stephan Hatscher , Michael Hesse
发明人： Stephan Hatscher , Michael Hesse
IPC分类号： C07C5/03
CPC分类号： B01J23/80 , B01J37/0009 , B01J37/03 , B01J37/06 , C07C5/09 , C07C2523/80 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： Unsaturated hydrocarbons are hydrogenated over catalysts which comprise copper and zinc and whose active composition, in unreduced form, consists essentially of from 10 to 95% by weight of copper oxide, calculated as copper(II) oxide (CuO), from 5 to 90% by weight of zinc oxide (ZnO), optionally from 0.1 to 50% by weight of zirconium dioxide (ZrO2) and optionally from 0.1% by weight to 50% by weight of Al2O3, the proportions by weight adding up to 100% by weight.
摘要翻译： 不饱和烃在包含铜和锌的催化剂上氢化，并且其未还原形式的活性组合物基本上由10至95重量％的氧化铜计算，氧化铜（II）（CuO）为5-90重量％ 的氧化锌（ZnO），任选的0.1至50重量％的二氧化锆（ZrO 2）和任选的0.1重量％至50重量％的Al 2 O 3，其重量比加至100重量％。
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