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1.发明申请SUPPORTED NOBLE METAL COMPRISING CATALYST FOR OXIDATIVE DEHYDROGENATION OR EPOXIDATION 有权用于氧化脱氢或环氧化的包含催化剂的支持金属公开(公告)号：US20120108831A1
公开(公告)日：2012-05-03
申请号：US13381807
申请日：2010-06-07
申请人： Georg Seeber , Peter Löchner , Stefan Bauer , Tobias Rosendahl , Torsten Mäurer , Günter Wegner , Martin Kamasz
发明人： Georg Seeber , Peter Löchner , Stefan Bauer , Tobias Rosendahl , Torsten Mäurer , Günter Wegner , Martin Kamasz
IPC分类号： B01J21/10 , C07D301/03 , C07C45/00 , B01J23/38 , B01J23/50
CPC分类号： B01J37/0211 , B01J23/30 , B01J23/40 , B01J23/48 , B01J23/50 , B01J23/72 , C07C45/38 , C07C47/21
摘要： Supported noble metal-comprising catalysts which can be obtained by a) application of colloidal noble metal in the form of a colloidal solution, optionally in admixture with additives acting as promoters, to a support material, b1) drying of the resulting product at from 150 to 350° C., or b2) drying of the resulting product at from 150 to 350° C. and subsequent calcination at from 350 to 550° C. for epoxidation or oxidative dehydrogenation, a process for producing it, its use and also the use of colloidal noble metal for producing supported catalysts.
摘要翻译： 负载的含贵金属的催化剂，其可以通过以下方式获得：a）以胶体溶液的形式将任选与添加剂作为助催化剂混合使用的胶态贵金属，任选地与载体材料混合，b1）将所得产物以150 或者b2）将所得产物在150-350℃下干燥，然后在350-550℃下进行煅烧，进行环氧化或氧化脱氢，其生产方法及其用途，以及 使用胶态贵金属制备负载型催化剂。
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2.发明授权Supported noble metal comprising catalyst for oxidative dehydrogenation or epoxidation 有权负载的贵金属包括用于氧化脱氢或环氧化的催化剂公开(公告)号：US08604252B2
公开(公告)日：2013-12-10
申请号：US13381807
申请日：2010-06-07
申请人： Georg Seeber , Peter Löchner , Stefan Bauer , Tobias Rosendahl , Torsten Mäurer , Günter Wegner , Martin Kamasz
发明人： Georg Seeber , Peter Löchner , Stefan Bauer , Tobias Rosendahl , Torsten Mäurer , Günter Wegner , Martin Kamasz
IPC分类号： C07C45/00 , C07D301/03 , B01J21/10 , B01J23/38
CPC分类号： B01J37/0211 , B01J23/30 , B01J23/40 , B01J23/48 , B01J23/50 , B01J23/72 , C07C45/38 , C07C47/21
摘要： Supported noble metal-comprising catalysts which can be obtained by a) application of colloidal noble metal in the form of a colloidal solution, optionally in admixture with additives acting as promoters, to a support material, b1) drying of the resulting product at from 150 to 350° C., or b2) drying of the resulting product at from 150 to 350° C. and subsequent calcination at from 350 to 550° C. for epoxidation or oxidative dehydrogenation, a process for producing it, its use and also the use of colloidal noble metal for producing supported catalysts.
摘要翻译： 负载的含贵金属的催化剂，其可以通过以下方式获得：a）以胶体溶液的形式将任选与添加剂作为助催化剂混合使用的胶态贵金属，任选地与载体材料混合，b1）将所得产物以150 或者b2）将所得产物在150-350℃下干燥，然后在350-550℃下进行煅烧，进行环氧化或氧化脱氢，其生产方法及其用途，以及 使用胶态贵金属制备负载型催化剂。
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3.发明申请USE OF A SUPPORTED CATALYST CONTAINING PRECIOUS METAL FOR OXIDATIVE DEHYDROGENATION 有权使用含有极性金属的负载型催化剂进行氧化脱氢公开(公告)号：US20110015446A1
公开(公告)日：2011-01-20
申请号：US12933441
申请日：2009-03-16
CPC分类号： B01J31/1616 , B01J21/16 , B01J23/007 , B01J23/38 , B01J23/50 , B01J23/72 , B01J23/8926 , B01J37/0219 , B01J37/086 , B01J2231/763 , B01J2531/17 , C07C45/38 , C07C47/21
摘要： The use of a supported noble metal catalyst obtainable by applying a sparingly soluble noble metal compound to a support from solution or suspension, and subsequently treating thermally, for preparing olefinically unsaturated carbonyl compounds.
摘要翻译： 使用负载的贵金属催化剂，其通过将溶于或悬浮液的微溶贵金属化合物施加到载体上，随后热处理，制备烯属不饱和羰基化合物。
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4.发明授权Use of a supported catalyst containing precious metal for oxidative dehydrogenation 有权使用含贵金属的载体催化剂进行氧化脱氢公开(公告)号：US08779212B2
公开(公告)日：2014-07-15
申请号：US12933441
申请日：2009-03-16
CPC分类号： B01J31/1616 , B01J21/16 , B01J23/007 , B01J23/38 , B01J23/50 , B01J23/72 , B01J23/8926 , B01J37/0219 , B01J37/086 , B01J2231/763 , B01J2531/17 , C07C45/38 , C07C47/21
摘要： The use of a supported noble metal catalyst obtainable by applying a sparingly soluble noble metal compound to a support from solution or suspension, and subsequently treating thermally, for preparing olefinically unsaturated carbonyl compounds.
摘要翻译： 使用负载的贵金属催化剂，其通过将溶于或悬浮液的微溶贵金属化合物施加到载体上，随后热处理，制备烯属不饱和羰基化合物。
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5.发明授权Precious metal catalysts with low metal loading for oxidative dehydrogenations 有权贵金属催化剂具有低的金属负载用于氧化脱氢公开(公告)号：US08680340B2
公开(公告)日：2014-03-25
申请号：US13457644
申请日：2012-04-27
CPC分类号： B01J37/349 , B01J23/40 , B01J23/48 , B01J23/50 , B01J35/0013 , B01J35/006 , B01J37/0219 , B01J37/0221 , B01J37/0223 , B82Y30/00 , C07C45/29 , C07C47/02
摘要： A method of production of a catalyst that has 0.05-0.25 wt. % of precious metal, preferably for the oxidative dehydrogenation of olefinically unsaturated alcohols, comprising the following steps a) producing a D.C. plasma, b) introducing the metal and support material into the plasma, c) evaporating the metal and support material or “shattering” the solid bodies of metal and support material in the plasma, and reaction of the particles, d) cooling, so that very small particles of composite material are obtained, e) applying the composite material on the catalyst support proper, the correspondingly produced catalyst and use thereof.
摘要翻译： 一种生产具有0.05-0.25wt。 ％的贵金属，优选用于烯属不饱和醇的氧化脱氢，包括以下步骤：a）制造DC等离子体，b）将金属和载体材料引入等离子体; c）蒸发金属和载体材料或“粉碎” 等离子体中的金属和支撑材料的固体物质和颗粒的反应，d）冷却，从而获得非常小的复合材料颗粒，e）将复合材料施加在催化剂载体上，相应产生的催化剂和 使用它。
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6.发明申请Precious metal catalysts with low metal loading for oxidative dehydrogenations 有权贵金属催化剂具有低的金属负载用于氧化脱氢公开(公告)号：US20120277476A1
公开(公告)日：2012-11-01
申请号：US13457644
申请日：2012-04-27
CPC分类号： B01J37/349 , B01J23/40 , B01J23/48 , B01J23/50 , B01J35/0013 , B01J35/006 , B01J37/0219 , B01J37/0221 , B01J37/0223 , B82Y30/00 , C07C45/29 , C07C47/02
摘要： A method of production of a catalyst that has 0.05-0.25 wt. % of precious metal, preferably for the oxidative dehydrogenation of olefinically unsaturated alcohols, comprising the following stepsa) producing a D.C. plasma, b) introducing the metal and support material into the plasma, c) evaporating the metal and support material or “shattering” the solid bodies of metal and support material in the plasma, and reaction of the particles, d) cooling, so that very small particles of composite material are obtained, e) applying the composite material on the catalyst support proper, the correspondingly produced catalyst and use thereof.
摘要翻译： 一种生产具有0.05-0.25wt。 ％的贵金属，优选用于烯属不饱和醇的氧化脱氢，包括以下步骤：a）制造DC等离子体，b）将金属和载体材料引入等离子体中，c）蒸发金属和载体材料或粉碎固体 等离子体中的金属和载体材料，以及颗粒的反应，d）冷却，从而获得非常小的复合材料颗粒，e）将复合材料施加在催化剂载体上，相应产生的催化剂及其用途 。
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公开(公告)号：US08580982B2
公开(公告)日：2013-11-12
申请号：US13376879
申请日：2010-06-09
申请人： Georg Seeber , Torsten Mäurer , Gerhard Theis , Dieter Köffer , Frank Rosowski
发明人： Georg Seeber , Torsten Mäurer , Gerhard Theis , Dieter Köffer , Frank Rosowski
IPC分类号： C07D301/03
CPC分类号： C07D301/10
摘要： The present invention relates to a process for preparing ethylene oxide by reaction of ethylene with oxygen in the presence of at least one silver-comprising catalyst, wherein the reaction takes place in a reactor which has a catalyst packed bed having at least two zones (i) and (ii) and the silver content of the catalyst in zone (i) is lower than the silver content of the catalyst in zone (ii). The catalyst packed bed preferably has a further zone (a) with which the reaction mixture comes into contact before the zones (i) and (ii). According to the invention, the silver content of the catalyst in the zone (a) is higher than the silver content of the catalyst in zone (i).
摘要翻译： 本发明涉及通过乙烯与氧在至少一种含银催化剂存在下反应来制备环氧乙烷的方法，其中该反应在具有至少两个区域的催化剂填充床（i ）和（ii），并且（i）区域中的催化剂的银含量低于区域（ii）中的催化剂的银含量。 催化剂填充床优选具有另外的区域（a），反应混合物在区域（i）和（ii）之前与其接触。 根据本发明，区域（a）中催化剂的银含量高于区域（i）中催化剂的银含量。
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公开(公告)号：US20120077998A1
公开(公告)日：2012-03-29
申请号：US13376879
申请日：2010-06-09
申请人： Georg Seeber , Torsten Mäurer , Gerhard Theis , Dieter Köffer , Frank Rosowski
发明人： Georg Seeber , Torsten Mäurer , Gerhard Theis , Dieter Köffer , Frank Rosowski
IPC分类号： C07D301/10
CPC分类号： C07D301/10
摘要： The present invention relates to a process for preparing ethylene oxide by reaction of ethylene with oxygen in the presence of at least one silver-comprising catalyst, wherein the reaction takes place in a reactor which has a catalyst packed bed having at least two zones (i) and (ii) and the silver content of the catalyst in zone (i) is lower than the silver content of the catalyst in zone (ii). The catalyst packed bed preferably has a further zone (a) with which the reaction mixture comes into contact before the zones (i) and (ii). According to the invention, the silver content of the catalyst in the zone (a) is higher than the silver content of the catalyst in zone (i).
摘要翻译： 本发明涉及通过乙烯与氧在至少一种含银催化剂存在下反应来制备环氧乙烷的方法，其中该反应在具有至少两个区域的催化剂填充床（i ）和（ii），并且（i）区域中的催化剂的银含量低于区域（ii）中的催化剂的银含量。 催化剂填充床优选具有另外的区域（a），反应混合物在区域（i）和（ii）之前与其接触。 根据本发明，区域（a）中催化剂的银含量高于区域（i）中催化剂的银含量。
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