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    Materials comprising a matrix and process for preparing them
    2.
    发明授权
    Materials comprising a matrix and process for preparing them 有权

    公开(公告)号：US09926479B2

    公开(公告)日：2018-03-27

    申请号：US13375956

    申请日：2010-05-10

    申请人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    发明人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    IPC分类号： C08L75/04 ,  C09K5/06 ,  C08L71/02

    CPC分类号： C09K5/063 ,  C08L71/02 ,  C08L75/04 ,  C08L2666/22

    摘要： The present invention is concerned with a material comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) exhibits a phase change as measured by differential scanning calorimetry (DSC) in the temperature range −10° C. to +60° C. with an enthalpy ΔHm of at least 87 kJ/kg, 3) is interpenetrating said matrix A, and 4) has an average molecular weight of more than 700 and comprises at least 50% by weight of oxyalkylene groups, based on the weight of this material, wherein at least 85% of the oxyalkylene groups are oxyethylene groups (hereinafter called polymeric material B); and wherein the relative amount of said matrix A and of said polymeric material B, on a weight basis, ranges from 15:85 to 75:25. Process for preparing such material.

    Process for preparing a polyisocyanurate polyurethane material
    3.
    发明授权
    Process for preparing a polyisocyanurate polyurethane material 有权
    聚异氰脲酸酯聚氨酯材料的制备方法

    公开(公告)号：US08785570B2

    公开(公告)日：2014-07-22

    申请号：US12089831

    申请日：2006-09-29

    申请人： Gerhard Jozef Bleys ,  Eric Huygens ,  Stijn Roekaerts ,  Marc Vandervesse ,  Hans Godelieve Guido Verbeke

    发明人： Gerhard Jozef Bleys ,  Eric Huygens ,  Stijn Roekaerts ,  Marc Vandervesse ,  Hans Godelieve Guido Verbeke

    IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/09 ,  C08G18/76 ,  C08G18/48

    CPC分类号： C08G18/092 ,  C08G18/4837 ,  C08G18/7671

    摘要： A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerization catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4′-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25° C. and has an NCO value of at least 20% by weight (polyisocyanate a), and b) 25-0% by weight of another polyisocyanate (polyisocyanate b), the amount of polyisocyanate a) and polyisocyanate b) being calculated on the total amount of this polyisocyanate a) and polyisocyanate b), and wherein the isocyanate-reactive composition comprises a) 80-100% by weight of a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 1100-5000 and an oxyethylene (EO) content of 65-100% by weight and b) 20-0% by weight of one or more other isocyanate-reactive compounds, the amount of polyol a) and isocyanate-reactive compound b) being calculated on the total amount of this polyol a) and compound b).

    摘要翻译： 一种制备聚异氰脲酸酯聚氨酯材料的方法，该方法包括使多异氰酸酯和异氰酸酯反应性组合物反应，其中反应在异氰酸酯指数为1600至100,000的条件下进行，并且在三聚催化剂存在下进行，其中多异氰酸酯包含a） 75-100重量％的二苯基甲烷二异氰酸酯，其包含至少40重量％，优选至少60重量％，最优选至少85重量％的4,4'-二苯基甲烷二异氰酸酯和/或所述二苯基甲烷二异氰酸酯的变体，其变体是液体 并且具有至少20重量％的NCO值（多异氰酸酯a），和b）25-0重量％的另一多异氰酸酯（多异氰酸酯b），多异氰酸酯a）和多异氰酸酯的量b）为 基于该多异氰酸酯a）和多异氰酸酯b）的总量计算，并且其中异氰酸酯反应性组合物包含a）80-100重量％的具有平均标称功能的聚醚多元醇 2-6，平均当量为1100-5000，氧化乙烯（EO）含量为65-100重量％，b）20-0重量％的一种或多种其它异氰酸酯反应性化合物，其量为 多元醇a）和异氰酸酯反应性化合物b）根据该多元醇a）和化合物b）的总量计算。

    FOAMED MATERIALS COMPRISING A MATRIX HAVING A HIGH HIGHBLOCK CONTENT AND PROCESS FOR PREPARING THEM
    5.
    发明申请
    FOAMED MATERIALS COMPRISING A MATRIX HAVING A HIGH HIGHBLOCK CONTENT AND PROCESS FOR PREPARING THEM 有权
    包含具有高高压含量的基质的泡沫材料及其制备方法

    公开(公告)号：US20110015287A1

    公开(公告)日：2011-01-20

    申请号：US12920286

    申请日：2009-03-04

    申请人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    发明人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    IPC分类号： C08J9/00

    CPC分类号： C08G18/10 ,  C08G18/283 ,  C08G18/2865 ,  C08G18/7664 ,  C08G18/7671 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083 ,  C08G2270/00 ,  C08G2290/00 ,  C08G2350/00 ,  C08L75/02 ,  C08L75/04

    摘要： Foamed material having a density of less than 100 kg/m3 and comprising a matrix material comprising a plurality of urea groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is a polymer having an average molecular weight of more than 500 which polymer comprises at least 50% by weight of oxyethylene groups based on the weight of this polymer (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 70:30 and process for making such materials.

    摘要翻译： 具有小于100kg / m 3的密度的发泡材料，并且包含包含多个脲基并且具有大于50％的硬嵌段含量的基质材料（以下称为基质A）; 和1）不具有能够与异氰酸酯基形成氨基甲酸酯，脲或异氰脲酸酯基的基团的聚合物材料，2）互穿所述基质A，和3）是平均分子量大于500的聚合物 该聚合物包含至少50重量％的基于该​​聚合物重量的氧化乙烯基团（以下称为聚合物材料B）; 并且其中用于制备所述基质A和所述聚合物材料B的所有成分的相对量以重量为基准在10:90至70:30的范围内以及制备这种材料的方法。

    Elastomeric materials having a high hardblock content and process for preparing them
    6.
    发明授权
    Elastomeric materials having a high hardblock content and process for preparing them 有权
    具有高硬嵌段含量的弹性材料及其制备方法

    公开(公告)号：US08519062B2

    公开(公告)日：2013-08-27

    申请号：US12866803

    申请日：2009-02-05

    申请人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    发明人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    IPC分类号： C08G18/42 ,  C08G18/48 ,  C08G18/62

    CPC分类号： C08G18/2865 ,  C08G18/4837 ,  C08G18/6674 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08G2105/02 ,  C08G2270/00 ,  C08G2350/00 ,  C08G2410/00 ,  C08L75/04 ,  C08L2666/20

    摘要： Elastomeric material having a density of more than 100 kg/m3 and comprising a matrix material comprising a plurality of urethane, urea and/or isocyanurate groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is the reaction product of a polyisocyanate and a polymer having an average molecular weight of more than 500 and one isocyanate-reactive group at an isocyanate index of 100-250 (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 90:10 and process for making such materials.

    摘要翻译： 密度大于100kg / m 3的弹性体材料，其包含多个氨基甲酸酯，脲和/或异氰脲酸酯基，并且具有大于50％的硬嵌段含量的基体材料（以下称为基体A）; 和1）不具有能够与异氰酸酯基形成氨基甲酸酯，脲或异氰脲酸酯基的基团的聚合物材料，2）互穿所述基质A，和3）是多异氰酸酯和具有 平均分子量大于500，异氰酸酯指数为100-250的异氰酸酯反应性基团（以下称为聚合材料B）; 并且其中用于制备所述基质A和所述聚合物材料B的所有成分的重量的相对量为10:90至90:10，并且用于制备这种材料的方法。

    Foamed materials comprising a matrix having a high highblock content and process for preparing them
    7.
    发明授权
    Foamed materials comprising a matrix having a high highblock content and process for preparing them 有权
    发泡材料包括具有高的高嵌段含量的基质和用于制备它们的方法

    公开(公告)号：US08349908B2

    公开(公告)日：2013-01-08

    申请号：US12920286

    申请日：2009-03-04

    申请人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    发明人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    IPC分类号： C08L75/02

    CPC分类号： C08G18/10 ,  C08G18/283 ,  C08G18/2865 ,  C08G18/7664 ,  C08G18/7671 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083 ,  C08G2270/00 ,  C08G2290/00 ,  C08G2350/00 ,  C08L75/02 ,  C08L75/04

    摘要： Foamed material having a density of less than 100 kg/m3 and comprising a matrix material comprising a plurality of urea groups and having a hardblock content of more than 50% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) is interpenetrating said matrix A, and 3) is a polymer having an average molecular weight of more than 500 which polymer comprises at least 50% by weight of oxyethylene groups based on the weight of this polymer (hereinafter called polymeric material B); and wherein the relative amount of all ingredients used to make said matrix A and of said polymeric material B, on a weight basis, ranges from 10:90 to 70:30 and process for making such materials.

    摘要翻译： 具有小于100kg / m 3的密度的发泡材料，并且包含包含多个脲基并且具有大于50％的硬嵌段含量的基质材料（以下称为基质A）; 和1）不具有能够与异氰酸酯基形成氨基甲酸酯，脲或异氰脲酸酯基的基团的聚合物材料，2）互穿所述基质A，和3）是平均分子量大于500的聚合物 该聚合物包含至少50重量％的基于该​​聚合物重量的氧化乙烯基团（以下称为聚合物材料B）; 并且其中用于制备所述基质A和所述聚合物材料B的所有成分的相对量以重量为基准在10:90至70:30的范围内以及制备这种材料的方法。

    Materials Comprising a Matrix and Process for Preparing Them
    9.
    发明申请
    Materials Comprising a Matrix and Process for Preparing Them 有权
    包括矩阵的材料及其制备方法

    公开(公告)号：US20120077942A1

    公开(公告)日：2012-03-29

    申请号：US13375956

    申请日：2010-05-10

    申请人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    发明人： Gerhard Jozef Bleys ,  Hans Godelieve Guido Verbeke

    IPC分类号： C08L75/04

    CPC分类号： C09K5/063 ,  C08L71/02 ,  C08L75/04 ,  C08L2666/22

    摘要： The present invention is concerned with a material comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) exhibits a phase change as measured by differential scanning calorimetry (DSC) in the temperature range −10° C. to +60° C. with an enthalpy ΔHm of at least 87 kJ/kg, 3) is interpenetrating said matrix A, and 4) has an average molecular weight of more than 700 and comprises at least 50% by weight of oxyalkylene groups, based on the weight of this material, wherein at least 85% of the oxyalkylene groups are oxyethylene groups (hereinafter called polymeric material B); and wherein the relative amount of said matrix A and of said polymeric material B, on a weight basis, ranges from 15:85 to 75:25. Process for preparing such material.

    摘要翻译： 本发明涉及一种材料，其包括：基质材料，其包含多个氨基甲酸酯和/或脲和/或异氰脲酸酯基团，并且具有大于75％的硬嵌段含量（以下称为基质A）; 和1）不具有能够形成具有异氰酸酯基的氨基甲酸酯，脲或异氰脲酸酯基的基团的聚合物材料，2）在-10℃的温度范围内显示出通过差示扫描量热法（DSC）测量的相变 至+ 60℃，焓＆Dgr; Hm为至少87kJ / kg，3）互穿所述基质A，和4）具有大于700的平均分子量，并且包含至少50重量％ 氧化烯基团，基于该材料的重量，其中至少85％的氧化烯基团是氧化乙烯基团（以下称为聚合物材料B）; 并且其中所述基质A和所述聚合物材料B的重量的相对量为15:85至75:25。 制备这种材料的方法。