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    Mixture of a thermoplastic polymer of an alkyl methacrylate and a graft polymer of methyl methacrylate onto crosslinked alkyl acrylate rubber
    4.
    发明授权
    Mixture of a thermoplastic polymer of an alkyl methacrylate and a graft polymer of methyl methacrylate onto crosslinked alkyl acrylate rubber 失效
    甲基丙烯酸烷基酯的热塑性聚合物和甲基丙烯酸甲酯的接枝聚合物与交联的丙烯酸烷基酯橡胶的混合物

    公开(公告)号：US4461868A

    公开(公告)日：1984-07-24

    申请号：US473756

    申请日：1983-03-09

    申请人： Christian Lindner ,  Karl-Heinz Ott ,  Horst Peters ,  Josef Buekers ,  Dieter Neuray

    发明人： Christian Lindner ,  Karl-Heinz Ott ,  Horst Peters ,  Josef Buekers ,  Dieter Neuray

    IPC分类号： C08L33/00 ,  C08L7/00 ,  C08L21/00 ,  C08L25/00 ,  C08L25/12 ,  C08L33/02 ,  C08L33/04 ,  C08L33/10 ,  C08L51/00 ,  C08L51/02 ,  C08L51/06 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00 ,  C08L51/04

    CPC分类号： C08L69/00 ,  Y10S525/902

    摘要： The present invention relates to mixtures comprising(a) thermoplastic aromatic polycarbonates having Mw (weight average molecular weight) of 10,000 to 200,000, preferably 20,000 to 80,000 (determined by measuring the relative viscosity .eta.rel in CH.sub.2 Cl.sub.2 at 25.degree. C. and a concentration of 0,5 g per 100 ml CH.sub.2 Cl.sub.2(b) thermoplastic polymers of C.sub.1 -C.sub.4 --alkyl methacrylates having Mw (weight average moleculr weight) of 10,000 to 1,000,000 (measured in dimethylformamide at 25.degree. C.) and(c) particulate graft polymers of methyl methacrylate onto a particulate, highly crosslinked alkyl acrylate-rubber which can optionally also contain a crosslinked diene rubber as an inner core, as well as to thermoplastic moulding compositions based on thermoplastic ABS resins or thermoplastic SAN resins which contain the three-component mixture (a)+(b)+(c).

    摘要翻译： 本发明涉及包含（a）热塑性芳族聚碳酸酯的混合物，所述热塑性芳族聚碳酸酯具有10,000至200,000，优选20,000至80,000（通过在25℃下测量CH 2 Cl 2中的相对粘度和相对浓度，并且浓度 （b）甲基丙烯酸C 1 -C 4烷基酯的热塑性聚合物具有10,000至1,000,000（在二甲基甲酰胺中在25℃下测量），并且（c）颗粒移植物（重量平均分子量）为10,000至1,000,000 甲基丙烯酸甲酯的聚合物可以任选地还含有作为内芯的交联二烯橡胶的颗粒状，高度交联的丙烯酸烷基酯橡胶，以及基于热塑性ABS树脂或含有三组分的热塑性SAN树脂的热塑性模塑组合物 混合物（a）+（b）+（c）。

    Polycarbonate-polyolefin moulding compositions
    5.
    发明授权
    Polycarbonate-polyolefin moulding compositions 失效
    聚碳酸酯 - 聚烯烃模塑组合物

    公开(公告)号：US4499237A

    公开(公告)日：1985-02-12

    申请号：US180334

    申请日：1980-08-22

    申请人： Peter Tacke ,  Helmut Korber ,  Josef Merten ,  Dieter Neuray

    发明人： Peter Tacke ,  Helmut Korber ,  Josef Merten ,  Dieter Neuray

    IPC分类号： C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L69/00 ,  C08L101/00

    CPC分类号： C08L69/00

    摘要： A mixture comprising 1. from 70 to 99% by weight of a predominantly aromatic polycarbonate; and 2. from 30 to 1% by weight of a polyolefin graft polymer of (a) 70 to 95% by weight of a graft base consisting of a homopolymer of aliphatic and/or aromatic monoolefins or of a copolymer of these olefins, and up to 50% by weight of other monoolefinically unsaturated, radially polymerizable compounds and/or up to 5% by weight of diolefins, and (b) 5 to 30% by weight of at least one graft-polymerizable vinyl compound, the olefin graft polymers having been obtained by contacting a melt of the graft base (a) with oxygen or an oxygen-containing gas for at most 10 min. with intensive mixing under a pressure of from 1 to 150 bars and at a temperature of from 80.degree. C. to 300.degree. C., adding the vinyl compounds (b) to be grafted on immediately afterwards with intensive mixing in the absence of oxygen or oxygen-containing gas and removing the residual monomers after the graft polymerization reaction.

    摘要翻译： 包含1.70至99重量％的主要是芳族聚碳酸酯的混合物; 和2.30至1重量％的（a）70至95重量％的由脂族和/或芳族单烯烃的均聚物或这些烯烃的共聚物组成的接枝基质的聚烯烃接枝聚合物和上述 至50重量％的其它单烯属不饱和的可径向聚合的化合物和/或至多5重量％的二烯烃，和（b）5至30重量％的至少一种可接枝聚合的乙烯基化合物，所述烯烃接枝聚合物具有 通过将接枝基质（a）的熔体与氧或含氧气体接触至多10分钟而获得。 在1至150巴的压力和80℃至300℃的温度下进行强烈混合，然后在不存在氧气的情况下立即将密封混合的乙烯基化合物（b）立即加入， 含氧气体，并在接枝聚合反应后除去残留的单体。