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公开(公告)号：US07981993B2
公开(公告)日：2011-07-19
申请号：US12452201
申请日：2008-06-09
IPC分类号： C08F210/08 , C08F210/16
CPC分类号： C08F210/08 , C08F4/65912 , C08F210/16 , C08F4/65927 , C08F2500/03 , C08F2500/11 , C08F2500/20
摘要： A 1-butene ethylene copolymer having an ethylene derived units content ranging from 15.10% by molto 18.00% by mol having the following properties: a) distribution of molecular weight lower than 3; preferably b) hardness shore A (measured according to ISO 868) lower than 65; c) tension set lower than 30% at 100% of deformation (ISO 2285) d) no melting pointdetectable at the DSC; e) Melting enthalpy measured after 10 days of aging at room temperature comprised between 4 and 15 J/g.
摘要翻译： 乙烯衍生单元含量范围为15.10摩尔％至18.00摩尔％的1-丁烯乙烯共聚物具有以下特性：a）低于3的分子量分布; 优选b）硬度岸A（根据ISO 868测量）低于65; c）100％变形时张力设定低于30％（ISO 2285）d）在DSC下无法检测到熔点; e）在室温下老化10天后测量的熔融焓在4至15J / g之间。
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公开(公告)号：US20100137543A1
公开(公告)日：2010-06-03
申请号：US12452201
申请日：2008-06-09
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F210/16 , C08F4/65927 , C08F2500/03 , C08F2500/11 , C08F2500/20
摘要： A 1-butene ethylene copolymer having an ethylene derived units content ranging from 15.10% by molto 18.00% by mol having the following properties: a) distribution of molecular weight lower than 3; preferably b) hardness shore A (measured according to ISO 868) lower than 65; c) tension set lower than 30% at 100% of deformation (ISO 2285) d) no melting pointdetectable at the DSC; e) Melting enthalpy measured after 10 days of aging at room temperature comprised between 4 and 15 J/g.
摘要翻译： 乙烯衍生单元含量范围为15.10摩尔％至18.00摩尔％的1-丁烯乙烯共聚物具有以下特性：a）低于3的分子量分布; 优选b）硬度岸A（根据ISO 868测量）低于65; c）100％变形时张力设定低于30％（ISO 2285）d）在DSC下无法检测到熔点; e）在室温下老化10天后测量的熔融焓在4至15J / g之间。
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公开(公告)号：US09593171B2
公开(公告)日：2017-03-14
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。
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公开(公告)号：US20140046010A1
公开(公告)日：2014-02-13
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
IPC分类号： C08F4/16
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。
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公开(公告)号：US20100324238A1
公开(公告)日：2010-12-23
申请号：US12735956
申请日：2009-02-27
申请人： Luigi Resconi , Davide Balboni , Simona Esposito
发明人： Luigi Resconi , Davide Balboni , Simona Esposito
CPC分类号： C08F210/16 , C08F4/65912 , C08F210/08 , C08F210/14 , C08F2420/05 , C08F4/65927 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A terpolymer of 1-butene, ethylene and a at least a C8-C12 alpha-olefin derived units, containing from 0.1% to 5% by mole of ethylene derived units and from 1 from 20% by mol of C8-C12 alpha-olefin derived units, endowed with the following properties: i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by 13C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135° C. comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C8-C12 alpha-olefin content fulfil the following relationship: TmI
摘要翻译： 1-丁烯，乙烯和至少一种C 8 -C 12α-烯烃衍生单元的三元共聚物，其含有0.1％至5％（摩尔）的乙烯衍生单元，和1％为20％（摩尔）的C 8 -C 12α-烯烃 具有以下性质：i）等于或等于90％的全同立构五单元mmmm; 低于4的五元组（mmrr + mrrm）和13C NMR不能检测到的五元组。 ii）在135℃下在四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; iii）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI <130×C-0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量，TmI是 通过DSC测量的第一熔融转变中的最高熔融峰不能检测到熔点Tm1。
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公开(公告)号：US20110003951A1
公开(公告)日：2011-01-06
申请号：US12735951
申请日：2009-02-25
申请人： Luigi Resconi , Davide Balboni , Simona Esposito
发明人： Luigi Resconi , Davide Balboni , Simona Esposito
CPC分类号： C08F210/08 , C08F4/65912 , C08F2420/05 , C08F4/65927 , C08F210/14 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F2500/20
摘要： A copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, having a content of C8-C12 alpha-olefin derived units equal to or higher than 7.2% and lower than 20.0% by mole; endowed with the following features: a) no detectable melting point TmII as the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetraline at 135° C. comprised between 0.8 and 5.0 dL/g; c) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable at 13C NMR; d) the tensile modulus (TM) measured with DMTA in MPa and the comonomer content fulfill the following relationship: TM
摘要翻译： 具有等于或高于7.2％且低于20.0摩尔％的C 8 -C 12α-烯烃衍生单元的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元的共聚物; 具有以下特征：a）没有可检测的熔点TmII作为第二熔融转变中最高的熔融峰; b）在135℃下在四氢化萘中测量的特性粘度（IV）为0.8至5.0dL / g; c）全同立构五价mmmm高于或等于90％; 低于4的五元组（mmrr + mrrm）和在13 C NMR下不能检测到的五元组; d）用DMTA测量的拉伸弹性模量（MPa）和共聚单体含量满足以下关系：TM <-14×C + 200其中C是C8-C12α-烯烃衍生单元的摩尔含量; e）100％变形时的张力设定值低于55％; 和f）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI <-0.20×C + 70其中C是C 8 -C 12α-烯烃衍生单元的摩尔含量， TmI是第一次熔融转变中最高的熔融峰; 否则熔点Tm1不能通过DSC检测。
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公开(公告)号：US20100324244A1
公开(公告)日：2010-12-23
申请号：US12735948
申请日：2009-02-23
申请人： Luigi Resconi , Davide Balboni , Simona Esposito
发明人： Luigi Resconi , Davide Balboni , Simona Esposito
IPC分类号： C08F210/08 , C08F4/52
CPC分类号： C08F210/08 , C08F210/14 , C08F210/06 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, preferably at least 1-octene derived units, containing from 0% to 2% by mole of propylene or pentene, having a content of C8-C12 alpha-olefin derived units higher than 0.2% and lower than 7.2% by mole; endowed with the following features: a) the melting point measured by DSC (TmII) and the C8-C12 alpha-olefin molar content fulfil the following relationship: 0
摘要翻译： 含有C-C 12α-烯烃含量为0〜2摩尔％的丙烯或戊烯的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元，优选至少1-辛烯衍生单元的共聚物 高于0.2％且低于7.2摩尔％的α-烯烃衍生单元; 具有以下特征：a）通过DSC（TmII）和C8-C12α-烯烃摩尔含量测量的熔点满足以下关系：0
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