公开(公告)号：US4985317A

公开(公告)日：1991-01-15

申请号：US372075

申请日：1989-06-28

申请人： Ginya Adachi ,  Nobuhito Imanaka ,  Hiromichi Aono ,  Eisuke Sugimoto ,  Yoshihiko Sadaoka ,  Naoshi Yasuda ,  Takeo Hara ,  Masaki Nagata

发明人： Ginya Adachi ,  Nobuhito Imanaka ,  Hiromichi Aono ,  Eisuke Sugimoto ,  Yoshihiko Sadaoka ,  Naoshi Yasuda ,  Takeo Hara ,  Masaki Nagata

IPC分类号： C01B25/45 ,  C01B33/20 ,  H01M6/18

CPC分类号： H01M6/185 ,  C01B25/45 ,  C01B33/20 ,  C04B35/16 ,  C04B35/447 ,  H01M6/18 ,  C04B2235/3203 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3232 ,  C04B2235/3272 ,  C04B2235/3418 ,  C04B2235/447 ,  C04B2235/77 ,  C04B2235/80

摘要： A lithium ion-conductive solid electrolyte consisting of a compound represented by the chemical formula, Li.sub.1+x M.sub.x Ti.sub.2-x (PO.sub.4).sub.3 (M is at least one element selected from the group consisting of Fe, Al and rare earth elements and x is a number of 0.1 to 1.9), a compound represented by the chemical formula, Li.sub.1+y Ti.sub.2 Si.sub.y P.sub.3-y O.sub.12 (Y is a number of 0.1 to 2.9), or a compound obtained by mixing a compound represented by the chemical formula, LiTi.sub.2 (PO.sub.4).sub.3 with a lithium compound other than LiTi.sub.2 (PO.sub.4).sub.3 and sintering the resulting mixture. Said lithium ion-conductive solid electrolyte can be produced by subjecting to solid phase reaction a mixture of a titanium oxide, a lithium salt, a phosphoric salt and M.sub.2 O.sub.3 (M is at least one element selected from the group consisting of Fe, Al and rare earth elements) or a silicon oxide or a mixture of LiTi.sub.2 (PO.sub.4).sub.3 and other lithium compound. Said lithium ion-conductive electrolyte can be used in the form of a lithium ion-conductive electrolyte sheet to prepare a structure suitable for solid electrochemical elements.

摘要翻译： 由化学式Li1 + xMxTi2-x（PO4）3表示的化合物组成的锂离子传导性固体电解质（M为选自Fe，Al和稀土元素中的至少一种元素，x为 数为0.1〜1.9），由化学式Li1 + yTi2SiyP3-yO12表示的化合物（Y为0.1〜2.9的数），或将化学式表示的化合物LiTi2（PO4）3 与LiTi 2（PO 4）3之外的锂化合物并烧结所得混合物。 所述锂离子传导性固体电解质可以通过将氧化钛，锂盐，磷酸盐和M 2 O 3的混合物进行固相反应来制造（M为选自Fe，Al和稀土元素中的至少一种元素 地球元素）或氧化硅或LiTi 2（PO 4）3与其它锂化合物的混合物。 所述锂离子传导性电解质可以以锂离子传导电解质片的形式使用，以制备适用于固体电化学元件的结构。

公开(公告)号：US20080260620A1

公开(公告)日：2008-10-23

申请号：US11575467

申请日：2005-09-02

申请人： Hiromichi Aono ,  Tsunehiro Maehara ,  Yasumasa Hattori ,  Kensaku Mori

发明人： Hiromichi Aono ,  Tsunehiro Maehara ,  Yasumasa Hattori ,  Kensaku Mori

IPC分类号： C01G49/02

CPC分类号： C01G49/009 ,  A61N1/406 ,  A61N2/02 ,  C01G49/0018 ,  C01G49/0036 ,  C01P2002/72 ,  C01P2006/42

摘要： This invention provides a powder material, which is capable of obtaining a heating value flat is greater than that of MgFe2O4, and the manufacturing method thereof.The powder material is expressed by the general formula Mg1-xAxFe2O4 (where A in the formula is at least one element selected from the group of Ca, Sr and Ba, and the range of x in the formula is 0.05≦x≦0.95). It is preferred that the range of x in the general formula be 0.2≦x≦0.8. Also, it is preferred that the size of crystallites on the (440) surface be 80 to 200 Å.

摘要翻译： 本发明提供一种粉末材料及其制造方法，该粉末材料能够获得平坦的发热值大于MgFe 2 O 4 O 4。 粉末材料由通式Mg 1-x A x 2 Fe 2 O 4（其中A 在该式中是选自Ca，Sr和Ba中的至少一种元素，式中x的范围为0.05 <= x <= 0.95）。 优选通式中的x的范围为0.2≤x≤0.8。 此外，优选的是（440）表面上的微晶尺寸为80至200。