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公开(公告)号：US5977254A
公开(公告)日：1999-11-02
申请号：US833462
申请日：1997-04-07
IPC分类号： C08K7/04 , C08K7/00 , C08L51/04 , C08L55/00 , C08L55/02 , C08L59/00 , C08L67/02 , C08L71/02 , C08L75/00 , C08L75/04 , C08L75/06 , C08L77/00 , C08L101/00 , C08L61/02
摘要： A molding material contains, based on the sum of the components A and B, and, if required, C, D and/or E,A: 1-99% by weight of a particulate microemulsion polymer having a glass transition temperature below 0.degree. C. and a median particle size of less than 50 nm,B: 1-99% by weight of a semicrystalline polymer B, in particular selected from at least one polymer from semicrystalline polyamides, partly aromatic copolyamides, polyolefins, ionomers, polyesters, polyetherketones, polyoxyalkylenes and polyarylene sulfides,C: 0-50% by weight of a polymer selected from a particulate graft copolymer having a median particle size of from 60 to 10,000 nm, a thermoplastic polyurethane, a thermoplastic elastomer and an acrylate, diene, EP, EPDM or silicone rubber,D: 0-50% by weight of polycarbonates andE: 0-50% by weight of fibrous or particulate fillers or of a mixture thereof.
摘要翻译： 成型材料基于组分A和B的总和，并且如果需要，包含C，D和/或E，A：1-99重量％的玻璃化转变温度低于0℃的微粒微乳液聚合物 C，中值粒径小于50nm，B：1-99重量％的半结晶聚合物B，特别是选自至少一种来自半结晶聚酰胺的聚合物，部分芳族共聚酰胺，聚烯烃，离聚物，聚酯，聚醚酮 聚氧亚烷基和聚亚芳基硫醚，C：0-50重量％的选自中值粒径为60至10,000nm的颗粒接枝共聚物的聚合物，热塑性聚氨酯，热塑性弹性体和丙烯酸酯，二烯，EP， EPDM或硅橡胶，D：0-50重量％的聚碳酸酯和E：0-50重量％的纤维或颗粒填料或其混合物。
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公开(公告)号：US06420483B1
公开(公告)日：2002-07-16
申请号：US09685742
申请日：2000-10-11
IPC分类号： C08F8100
CPC分类号： C08L55/02 , C08F279/02 , C08F279/04 , C08L2666/14 , C08L2666/02
摘要： The invention relates to a process for preparing an impact-modified plastic, where particles of a crosslinked rubber are produced from a first monomer mixture which has at least 50% by weight of conjugated diene compounds, the rubber particles are added to a second monomer mixture which has at least 85% by weight, preferably at least 90% by weight, in particular at least 98% by weight, of styrene, and the monomers of the second monomer mixture are polymerized. This process can prepare novel and improved impact-modified plastics. Novel impact-modified plastics are also described.
摘要翻译： 本发明涉及一种制备冲击改性塑料的方法，其中交联橡胶的颗粒由具有至少50重量％的共轭二烯化合物的第一单体混合物制备，将橡胶颗粒加入到第二单体混合物中， 具有至少85重量％，优选至少90重量％，特别是至少98重量％的苯乙烯，并且第二单体混合物的单体被聚合。该方法可以制备新的和改进的冲击改性塑料。 还描述了新的冲击改性塑料。
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公开(公告)号：US06566436B1
公开(公告)日：2003-05-20
申请号：US09806863
申请日：2001-04-05
申请人： Norbert Güntherberg , Heiner Görrissen , Graham Edmund Mc Kee , Norbert Niessner , Martin Weber
发明人： Norbert Güntherberg , Heiner Görrissen , Graham Edmund Mc Kee , Norbert Niessner , Martin Weber
IPC分类号： C08L500
摘要： The use of a thermoplastic molding composition which is not ABS, comprising, based on the total of the amounts of components A, B, C, and, where appropriate, D, this total being 100% by weight, a: as component A, from 1 to 48% by weight of at least one particulate emulsion polymer which has one or more phases and has a glass transition temperature below 0° C. in at least one phase, and has a median particle size from 50 to 1000 nm, b: as component B, from 1 to 48% by weight of at least one amorphous or semicrystalline polymer, c: as component C, from 51 to 90% by weight of polycarbonates, and d: as component D, from 0 to 47% by weight of conventional addictives and/or fibrous or particulate fillers, or a mixture of these, for producing moldings, or corresponding semifinished products, for the garden sector or animal-keeping sector.
摘要翻译： 使用不是ABS的热塑性模塑组合物，其包含基于组分A，B，C的总量，并且在合适的情况下，D总计为100重量％，a：作为组分A， 1至48重量％的至少一种具有一个或多个相的至少一种微粒乳液聚合物，并且在至少一个相中具有低于0℃的玻璃化转变温度，并且中值粒度为50-1000nm，b ：作为组分B，1至48重量％的至少一种无定形或半结晶聚合物，c：作为组分C，51至90重量％的聚碳酸酯，和d：作为组分D，0至47重量％ 的常规上瘾剂和/或纤维或颗粒填料，或它们的混合物，用于生产模制品或相应的半成品，用于花园部门或动物饲养部门。
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公开(公告)号：US06835775B2
公开(公告)日：2004-12-28
申请号：US10275012
申请日：2002-10-31
申请人： Michael Breulmann , Sabine Oepen , Norbert Niessner , Norbert Güntherberg , Wil Duijzings , Graham Edmund Mc Kee , Peter Rossmanith
发明人： Michael Breulmann , Sabine Oepen , Norbert Niessner , Norbert Güntherberg , Wil Duijzings , Graham Edmund Mc Kee , Peter Rossmanith
IPC分类号： C08F25500
CPC分类号： C08L25/12 , C08F265/04 , C08F279/02 , C08F279/04 , C08F291/02 , C08L51/04 , C08L55/02 , C08F2/22 , C08L2666/24 , C08L2666/02
摘要： The graft copolymer made from a1: from 10 to 90% by weight of a particulate graft base A1, made from a particulate emulsion polymer with a glass transition temperature below 0° C. made from a11: from 70 to 100% by weight of butadiene or of at least one C1-8-alkyl acrylate, or of mixtures of these, as component A11, a12: from 0 to 20% by weight of at least one polyfunctional crosslinking monomer, as component A12, a13: from 0 to 30% by weight of other copolymerizable monomers, as component A13, the total amount of these being 100% by weight, a2: from 10 to 90% by weight of a graft A2 made from the following monomers, the amounts being based on A2, a21: from 60 to 100% by weight of at least one vinylaromatic monomer, or of a (meth)acrylic ester or of mixtures of these, as component A21, and a22: from 0 to 40% by weight of at least one ethylenically unsaturated monomer, as component A22, has a median particle diameter of from 130 to 500 nm and has polymodal particle size distribution in which less than 40% by weight of the particles are present in any particle size range of width 50 nm.
摘要翻译： 由a1制得的接枝共聚物：10至90重量％的微粒接枝基质A1，其由玻璃化转变温度低于0℃的颗粒状乳液聚合物制成，由11：70至100重量％的丁二烯或 至少一种丙烯酸C 1-8 - 或它们的混合物，作为组分A11，a12：0-20重量％的至少一种多官能交联单体，作为组分A12，a13：0-30重量％ 的其它可共聚单体作为组分A13，其总量为100重量％，a2：10至90重量％的由以下单体制备的接枝A2，其量基于A2，a21：60 至100重量％的至少一种乙烯基芳族单体或（甲基）丙烯酸酯或它们的混合物作为组分A21和a22：0至40重量％的至少一种烯属不饱和单体作为组分A22 具有130-500nm的中值粒径，并且具有多模态粒度分布，其中le 超过40重量％的颗粒存在于宽度为50nm的任何粒度范围内。
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公开(公告)号：US20120220678A1
公开(公告)日：2012-08-30
申请号：US13505966
申请日：2010-11-02
申请人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
发明人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
CPC分类号： C08L55/02 , C08K5/12 , C08K5/1539 , C08K2201/014 , C08L25/12 , D01F6/56 , C08L2666/04
摘要： The present invention relates to compositions comprising (i) as component (I), at least one molding composition comprising components A and B, where A) is a graft copolymer as component A, and B) is a thermoplastic copolymer as component B; and (ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II) in which R1 is C1-C10-alkyl or C3-C8-cycloalkyl, m is 0, 1, 2, or 3, n is 2, 3, or 4, and R is hydrogen or C1-C30-alkyl; or the group —(COOR)n forms an anhydride of the formula where it is essential to the invention that component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values is 100% by weight, and also to a process for producing the composition of the invention, to the use of the composition of the invention for producing moldings, foils, foams, or fibers, and to moldings, foils, foams, or fibers comprising the composition of the invention.
摘要翻译： 本发明涉及包含（i）组分（I）的组合物，至少一种包含组分A和B的模塑组合物，其中A）是作为组分A的接枝共聚物，B）是作为组分B的热塑性共聚物; 和（ii）至少一种式（I）的环己烷多羧酸衍生物; 作为其中R 1为C 1 -C 10 - 烷基或C 3 -C 8 - 环烷基的组分（II），m为0,1,2或3，n为2,3或4，并且R为氢或C 1 -C 30 - 烷基; 或（COOR）基团形成下式的酸酐，其中组分（I）占组分A的11至19.9重量％和组分B的80.1至89重量％是本发明必需的，其中 每个重量百分比值基于组分A和B的全部，并且这些值的总和为100重量％，并且还涉及制备本发明组合物的方法，使用组合物 用于生产模制品，箔，泡沫或纤维的本发明以及包含本发明组合物的模制品，箔，泡沫或纤维。
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6.发明申请GLASS FIBER REINFORCED ABS COMPOSITIONS WITH IMPROVED STIFFNESS AND TOUGHNESS 有权玻璃纤维增强ABS组合物具有改善的韧性和韧性公开(公告)号：US20100113648A1
公开(公告)日：2010-05-06
申请号：US12593685
申请日：2008-03-20
申请人： Norbert Niessner , Kyung Ho Shon , Ravi Ponnuswamy
发明人： Norbert Niessner , Kyung Ho Shon , Ravi Ponnuswamy
CPC分类号： C08L51/04 , C08F279/02 , C08F279/04 , C08L25/12 , C08L55/02 , C08L2666/24 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： Thermoplastic moulding compositions comprising the following components: 5-95% of a copolymer A consisting of: 70-76% of vinylaromatic monomer(s) A1, 24-30% of vinyl cyanide monomer component(s) A2 and 0-50% of one or more unsaturated copolymerizable monomers A3, 0-60% of a graft rubber B and 5-50% of thin glass fibers C are advantageously used for injection moulding.
摘要翻译： 包含以下组分的热塑性模塑组合物：5-95％的共聚物A，其由以下组分组成：乙烯基芳族单体（A）为70-76％，乙烯基氰单体组分A2为24-30％，乙烯基芳族单体组分A2为0-50％ 一种或多种不饱和可共聚单体A3，0-60％的接枝橡胶B和5-50％的薄玻璃纤维C有利地用于注射成型。
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公开(公告)号：US06774167B1
公开(公告)日：2004-08-10
申请号：US10111469
申请日：2002-04-25
IPC分类号： C08K55415
CPC分类号： C08L55/02 , C08F279/04 , C08L51/04 , C08L2666/04 , C08L2666/02
摘要： Undesirable changes in shade brought about by low temperatures (Cold Stress Whitening) in impact-modified thermoplastic molding compositions F which comprise at least one elastomeric graft polymer A and at least one thermoplastic polymer B are reduced by adding from 10 to 200 ppm, based on the molding compositions F, of at least one polyorganosiloxane S to the impact-modified thermoplastic molding composition F.
摘要翻译： 在冲击改性的热塑性成型组合物F中，通过低温（冷应力增白）引起的不利影响的变化包括至少一种弹性体接枝聚合物A和至少一种热塑性聚合物B，通过加入10至200ppm，基于 至少一种聚有机硅氧烷S的成型组合物F与冲击改性热塑性模塑组合物F。
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公开(公告)号：US06649117B1
公开(公告)日：2003-11-18
申请号：US09913184
申请日：2001-08-09
IPC分类号： B29D701
CPC分类号： C08L23/08 , C08F265/04 , C08L25/14 , C08L51/003 , C08L71/02 , C08L2666/24 , C08L2666/22 , C08L2666/02
摘要： The present invention relates to thermoplastic molding compositions based on ASA (acrylonitrile-styrene-acrylate) with improved flowability and improved extrusion properties. The invention further relates to a process for preparing these thermoplastic molding compositions, their use and also, produced therefrom, reduced-gloss and antistatic films and moldings, and coatings with reduced gloss, and the use of these.
摘要翻译： 本发明涉及具有改善的流动性和改进的挤出性能的基于ASA（丙烯腈 - 苯乙烯 - 丙烯酸酯）的热塑性模塑组合物。 本发明还涉及一种制备这些热塑性模塑组合物的方法，它们的用途以及由其制备的减光泽和抗静电膜和模制品以及光泽度降低的涂料以及它们的用途。
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公开(公告)号：US06579937B1
公开(公告)日：2003-06-17
申请号：US09868516
申请日：2001-06-18
IPC分类号： C08L2508
CPC分类号： C08L51/04 , C08F265/04 , C08F265/06 , C08L53/02 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： Thermoplastic molding compositions comprising (A) 5 to 98%-wt., based on components (A) through (E), of at least one elastomeric graft copolymer, (B) 1 to 90%-wt., based on components (A) through (E), of a further copolymer, (C) 1 to 70%-wt., based on components (A) though (D), of an elastomeric block copolymer composed of at least one block CA (hard phase) having copolymerized units of a vinylaromatic monomer, and at least one elastomeric block C(B/A) (soft phase) having copolymerized units of a vinylaromatic monomer, and of a diene, (D) 0 to 300%-wt., based on components (A) through (C), of a polycarbonate, and (E) 0 to 30%-wt., based on components (A) through (E), of conventional additives and processing aids, are useful for producing films, moldings or fibers.
摘要翻译： 包含（A）基于组分（A）至（E）的至少一种弹性体接枝共聚物为5至98重量％的热塑性模制组合物，（B）基于组分（A）的1-90重量％ ）（E）中的另一种共聚物，（C）基于组分（A）至（D）的1-70重量％的由至少一个共聚的嵌段CA（硬相）组成的弹性体嵌段共聚物 乙烯基芳族单体的单元和具有乙烯基芳族单体和二烯的共聚单元的至少一种弹性嵌段C（B / A）（软相），（D）基于组分（A）为0至300重量％ ）通过（C），聚碳酸酯，和（E）0〜30重量％，基于常规添加剂和加工助剂的组分（A）至（E），可用于制备膜，模制品或纤维。
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公开(公告)号：US5972519A
公开(公告)日：1999-10-26
申请号：US983362
申请日：1998-01-13
申请人： Norbert Niessner , Konrad Knoll
发明人： Norbert Niessner , Konrad Knoll
CPC分类号： C08J5/18 , C08L53/02 , C08J2353/02 , Y10T428/31725 , Y10T428/31797 , Y10T428/31855 , Y10T428/31913 , Y10T428/31917
摘要： A film in roll form, in particular for food packaging as substitute for a film made from polyvinyl chloride, comprises from 15 to 99.6% by weight of an elastomeric styrene-butadiene block copolymer, from 15 to 99.6% of a thermoplastic polymer, from 0.1 to 10% of an antifogging agent, from 0.1 to 5% of a primary antioxidant, from 0.1 to 5% of a secondary antioxidant and from 0.1 to 50% of other auxiliaries, and shrinks perpendicularly to the direction of take-off by not more than 3% during a storage period of three months.
摘要翻译： PCT No.PCT / EP97 / 02682 Sec。 371日期1998年1月13日 102（e）日期1998年1月13日PCT提交1997年5月26日PCT公布。 公开号WO97 / 46608 日期1997年12月11日卷纸形式的薄膜，特别是用于代替由聚氯乙烯制成的薄膜的食品包装，包含15至99.6重量％的弹性体苯乙烯 - 丁二烯嵌段共聚物，15至99.6重量％ 热塑性聚合物，0.1〜10％的防雾剂，0.1〜5％的初级抗氧化剂，0.1〜5％的二级抗氧化剂和0.1〜50％的其他助剂，并垂直收缩 在三个月的储存期间，不超过3％。
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