公开(公告)号：US20050087434A1

公开(公告)日：2005-04-28

申请号：US10690675

申请日：2003-10-22

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: B01J19/12 ,  C07C17/395 ,  C07C19/08 ,  C07C19/10 ,  C07C23/06 ,  C07C51/58 ,  C07C6/00

CPC classification number: C07C23/06 ,  B01J19/123 ,  B01J19/127 ,  C07C17/395 ,  C07C19/08 ,  C07C19/10 ,  C07C51/58 ,  C07C2601/04 ,  C07C19/12 ,  C07C53/48

Abstract: A method of treatment of reactant fluids such as hydrochlorofluorocarbons (HCFCs), hydrofluorocarbons (HFCs), hydrochlorocarbons (HCCs), and hydrocarbons (HCs) for the production of new chemical fluids. Another method of treatment for the transformation of the reactant fluids having impurities present in the chlorofluorocarbons (CFCs) or fluorocarbons (FCs) for yielding a high quality chemical product. Reactant fluids with impurities present in used CFC or FC may form an azeotropic mixture. A photochemical reaction is used wherein the reactant fluids are molecules with hydrogen atoms in a hydrogen-carbon bond. The process is comprised of the following steps: placing the reactant fluids into a process compartment of the photochemical reactor; placing halogen fluid or oxygen fluid into the process compartment of the photochemical reactor, wherein the halogen fluid is selected from a group consisting of chlorine (Cl2), bromine (Br2) and iodine (I2); and irradiating the fluids and the halogen or oxygen fluid using radiant energy from lamps operating in the visible and ultraviolet light regions of the electromagnetic spectrum to conduct thermolysis, photolysis and photochemical treatment by halogenating or oxidizing the molecules of the reactant fluids with the halogen or oxygen fluids to form halogenated or oxidized fluids during a dwell time period.

Abstract translation: 用于生产新化学液体的反应物流体如氢氯氟烃（HCFC），氢氟碳化物（HFC），氢氯烃（HCC）和烃（HC））的处理方法。 用于转化具有存在于氯氟烃（CFC）或碳氟化合物（FC）中的杂质的反应物流体的另一种方法用于产生高质量的化学产品。 在使用的CFC或FC中存在杂质的反应物流体可形成共沸混合物。 使用光化学反应，其中反应物流体是在氢 - 碳键中具有氢原子的分子。 该方法包括以下步骤：将反应物流体置于光化学反应器的处理室中; 将卤素流体或氧气流体置于光化学反应器的处理室中，其中卤素流体选自氯（Cl 2/2），溴（Br 2 H 2） ）和碘（I 2 H 2）; 并且使用来自在电磁光谱的可见光和紫外光区域中操作的灯的辐射能来照射流体和卤素或氧气流体，以通过用卤素或氧气卤化或氧化反应物流体的分子来进行热解，光解和光化学处理 流体在停留时间段内形成卤化或氧化流体。

公开(公告)号：US5482682A

公开(公告)日：1996-01-09

申请号：US63941

申请日：1993-05-17

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: B01J10/00 ,  B01J12/00 ,  B01J19/24 ,  C07C17/10 ,  C08F2/00 ,  B01J8/04 ,  C07C17/20

CPC classification number: C07C17/10 ,  B01J12/00 ,  B01J19/2415 ,  B01J2219/0002 ,  B01J2219/00135

Abstract: The present invention relates to a method and apparatus for direct fluorination of hydrocarbons (having 1 to 4 carbons) by using molecular fluorine gas in a liquid medium. The number of reactors or reaction steps is a function of the number of hydrogen atoms in the hydrocarbon to be replaced by molecular fluorine to produce a refrigerant or other product.

Abstract translation: 本发明涉及通过在液体介质中使用分子氟气直接氟化烃（具有1至4个碳）的方法和装置。 反应器或反应步骤的数量是待分子氟代替烃的氢原子数以产生制冷剂或其它产物的函数。

公开(公告)号：US4576837A

公开(公告)日：1986-03-18

申请号：US713616

申请日：1985-03-19

Applicant: Gregorio Tarancon ,  Efrain Acevedo ,  Abel Saud

Inventor： Gregorio Tarancon ,  Efrain Acevedo ,  Abel Saud

IPC: B05D3/04 ,  C23G5/00 ,  C23C16/00

CPC classification number: B05D3/0446 ,  C23G5/00

Abstract: The method of treating a surface chemically by exposing the surface to a treating gas at high pressure for a time during which a surface reaction occurs, and then reducing the pressure of the gas for a time and removing reaction byproducts and then continuing the cycles of high pressure and low pressure until the surface reaction is completed.

Abstract translation: 通过将表面在高压下暴露于处理气体进行表面反应发生一段时间，然后将气体的压力一段时间并且除去反应副产物然后继续高的循环来化学处理表面的方法 压力和低压，直到表面反应完成。

公开(公告)号：US5628894A

公开(公告)日：1997-05-13

申请号：US544073

申请日：1995-10-17

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: C01B21/083 ,  C25B1/24 ,  C01B21/16 ,  C25B15/08

CPC classification number: C25B1/245 ,  C01B21/0835 ,  Y10S423/12

Abstract: A method for the production of nitrogen trifluoride (NF.sub.3) and hydrogen (H.sub.2) gas, starting with a molten flux including at least ammonia (NH.sub.3), a metal fluoride, and hydrogen fluoride (HF), including the steps of: circulating the molten flux from an electrolyzer, to an ammonia solubilizer, to a nitrogen trifluoride reactor, to a hydrogen fluoride solubilizer, and back to the electrolyzer; maintaining the quantity of the molten flux substantially constant by adding ammonia (NH.sub.3) and a carrier gas to the ammonia solubilizer and by adding hydrogen fluoride (HF) and a carrier gas to the hydrogen fluoride solubilizer; producing fluorine (F.sub.2) gas and hydrogen (H.sub.2) gas in the electrolyzer; transferring the carrier gas from at least one of the solubilizers to the nitrogen trifluoride reactor; mixing the fluorine gas and the carrier gas and supplying the mixed gases to the nitrogen trifluoride reactor; reacting the fluorine gas with the molten flux in the nitrogen trifluoride reactor to produce nitrogen trifluoride (NF.sub.3); and collecting the nitrogen trifluoride (NF.sub.3) produced at a nitrogen trifluoride condenser and collecting the hydrogen (H.sub.2) produced at a hydrogen condenser.

Abstract translation: 一种从至少包含氨（NH 3），金属氟化物和氟化氢（HF）的熔融助熔剂开始生产三氟化氮（NF 3）和氢气（H 2））的方法，包括以下步骤： 从电解槽，氨增溶剂，三氟化氮反应器到氟化氢增溶剂的回流到电解槽; 通过向氨增溶剂中加入氨（NH 3）和载气并通过向氟化氢增溶剂中加入氟化氢（HF）和载气，保持熔融流量的量基本恒定; 在电解槽中产生氟（F2）气和氢（H2）气; 将载气从至少一种增溶剂转移到三氟化氮反应器; 混合氟气和载气，并将混合气体供应到三氟化氮反应器; 使氟气与三氟化氮反应器中的熔融流体反应，生成三氟化氮（NF 3）; 并收集在三氟化氮冷凝器处产生的三氟化氮（NF 3）并收集在氢冷凝器处产生的氢气（H 2）。

公开(公告)号：US5407647A

公开(公告)日：1995-04-18

申请号：US250422

申请日：1994-05-27

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: B01D53/74 ,  B01J8/02 ,  B01J8/04

CPC classification number: B01J8/048 ,  B01D53/74 ,  B01J8/0285 ,  B01J8/0492 ,  B01J2208/00061 ,  B01J2208/0007 ,  B01J2208/00274 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/0084

Abstract: A gas-scrubber apparatus, including a chamber having an inlet means for receiving polluted gases to be scrubbed and having outlet means through which scrubbed gases are discharged, and heating elements for heating the chamber to maintain the polluted gases at predetermined temperature levels between the inlet means and the outlet means. The chamber includes a reaction zone for receiving a mixture of solid scrubbant materials for reacting with the polluted gases and a gas blower for directing the polluted gases to travel through the chamber to react with the scrubbant materials. At least one scrubber assembly is mounted in the reaction zone of the chamber having a baffle for collecting the polluted gases in the area adjacent the wall of the chamber. The scrubber assembly also includes thermo-convection pipes for transferring the collected polluted gases from the wall area towards the center of the chamber to maintain a substantially uniform heat distribution in a horizontal direction across the scrubber assembly. The chamber also maintains a vertical temperature gradient from the bottom to the top of the reaction zone of the chamber.

Abstract translation: 一种气体洗涤器装置，包括具有入口装置的腔室，所述入口装置用于接收待洗涤的污染气体，并且具有排出装置，排出洗涤气体的出口装置，以及用于加热室以将污染气体保持在入口之间预定温度水平的加热元件 手段和出口手段。 该室包括用于接收用于与污染气体反应的固体洗涤剂材料的混合物的反应区和用于引导污染气体穿过室以与洗涤剂材料反应的鼓风机。 至少一个洗涤器组件安装在具有挡板的室的反应区中，用于收集邻近室壁的区域中的污染气体。 洗涤器组件还包括热对流管道，用于将收集的污染气体从壁区域朝向室的中心传送，以保持穿过洗涤器组件的沿水平方向的基本均匀的热分布。 室还保持从室的反应区的底部到顶部的垂直温度梯度。

公开(公告)号：US5229072A

公开(公告)日：1993-07-20

申请号：US829417

申请日：1992-02-03

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: A01N59/10 ,  A61L2/20

CPC classification number: A61L2/20 ,  A01N59/10

Abstract: A method for sterilizing the surface of an article contaminated with bacteria and bacterial spores which comprises exposing the surface to an effective amount of a fluorine interhalogen compound sterilizing agent such as gaseous chlorine trifluoride or chloride pentafluoride, or mixtures thereof. The surface to be sterilized can be subjected to a gaseous atmosphere of controlled humidity immediately prior to or during exposure to the gaseous sterilant.

Abstract translation: 用于对被细菌和细菌孢子污染的物品的表面进行灭菌的方法，其包括将表面暴露于有效量的氟代氟化氢化合物杀菌剂如气态三氟化氯或五氟化氯或其混合物。 待暴露于气体杀菌剂之前或期间，待灭菌表面可以立即经受受控湿度的气体气氛。

公开(公告)号：US4349358A

公开(公告)日：1982-09-14

申请号：US247947

申请日：1981-03-26

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: B01F3/04 ,  B22C9/12 ,  B01D47/00

CPC classification number: B22C9/123 ,  Y10T137/0352

Abstract: A method of mixing a gas and a vaporizable liquid to provide a gaseous mixture having a constant composition, regardless of change in rate of flow, except as hereinafter provided, comprising:(a) introducing a mixture comprising a gas and a vaporizable liquid in predetermined proportions into the tube side of a tube and shell heat exchanger at a flow rate sufficient to cause turbulent flow;(b) introducing a heating fluid into the shell side of the heat exchanger at a temperature sufficient to vaporize at least part of the vaporizable liquid whereby the vaporizable liquid separates into a vapor phase and a liquid phase; and(c) delivering the mixture of gas and vapor phase to a use point and recycling the liquid phase to a point at which it will be mixed with gas for introduction into step (a).

Abstract translation: 一种混合气体和可汽化液体以提供具有恒定组成的气体混合物的方法，不管流速如何变化，除了以下提供，其包括：（a）将包含气体和可蒸发液体的混合物引入预定的 比例以足以引起湍流的流量进入管壳式换热器的管侧; （b）在足以蒸发至少部分可蒸发液体的温度下将加热流体引入热交换器的壳体侧，由此可汽化液体分离成气相和液相; 和（c）将气相和气相的混合物输送到使用点，并将液相再循环到与气体混合的点以引入步骤（a）。

公开(公告)号：US5779866A

公开(公告)日：1998-07-14

申请号：US757619

申请日：1996-11-26

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: C25B9/06 ,  C25B15/08 ,  C25B9/00

CPC classification number: C25B15/08 ,  C25B9/06

Abstract: An electrolyzer, including a lower electrolyte chamber for receiving liquid electrolyte flux and having disposed therein anode and cathode electrodes for producing anodic and cathodic gases. A first barrier is disposed in the lower electrolyte chamber between the anode and cathode electrodes having a plurality of V-shaped passageways for allowing the passage of electrons but for preventing the recombination of anodic and cathodic gases. The electrolyzer also includes an upper gas chamber having an anodic gas compartment and a cathodic gas compartment for receiving therein the anodic and cathodic gases produced in the lower electrolyte chamber. The upper gas chamber includes a second barrier disposed between the anodic and cathodic gas compartments having no passageways in order to prevent the recombination of anodic and cathodic gases. The second barrier is connected to the first barrier. In addition, the electrolyzer further includes means for transferring the anodic and cathodic gases produced in the anodic and cathodic gas compartments to holding tanks for storing of the anodic and cathodic gases.

Abstract translation: 一种电解器，包括用于接收液体电解质助焊剂的下部电解质室，并且在其中设置有用于产生阳极和阴极气体的阳极和阴极电极。 在具有多个V形通道的阳极和阴极电极之间的下部电解质室中设置第一屏障，以允许电子通过，但是用于防止阳极和阴极气体的复合。 电解槽还包括具有阳极气体室和阴极气体室的上部气室，用于在其中容纳在下部电解质室中产生的阳极和阴极气体。 上部气室包括设置在没有通道的阳极和阴极气体隔间之间的第二阻挡层，以防止阳极和阴极气体的复合。 第二屏障连接到第一屏障。 此外，电解槽还包括用于将在阳极和阴极气体隔间中产生的阳极和阴极气体转移到用于存储阳极和阴极气体的储存罐的装置。

公开(公告)号：US5260033A

公开(公告)日：1993-11-09

申请号：US775765

申请日：1991-10-15

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: B01J3/00 ,  B01J4/00 ,  B01J8/00 ,  B01J8/10 ,  B01J8/18 ,  B01J8/24 ,  B01J8/26 ,  B01J19/20 ,  C08F8/22 ,  B01F7/00

CPC classification number: C08F8/22 ,  B01J19/20 ,  B01J8/0015 ,  B01J8/10 ,  B01J8/1881 ,  B01J8/24 ,  B01J8/26 ,  B01J2219/185 ,  B01J2219/187

Abstract: An apparatus for the direct fluorination of solid particles of polymeric resins capable of being fluorinated in which the solid particles are in contact with the gaseous phase of fluorine/dense carrier fluid in a tubular reactor with an internal mechanical device comprising a rotatable shaft with screw flight, multiblade or wire brush that mechanically fluidizes the solid phase. The design of the internal mechanical device is a function of the diameter and length of the tubular reactor and the reaction time and other physical properties of the solid particles of polymeric resins. The internal mechanical device prevents agglomeration of the solid particles and promotes uniform contact with the gaseous phase by inducing mobility to the solid particles. The enhancement of solid surface contact with the gaseous phase assists the reaction between the solid polymeric resin and the elemental fluorine, as well as the heat dissipation into the dense carrier fluid.

Abstract translation: 用于直接氟化能够被氟化的聚合物树脂的固体颗粒的装置，其中固体颗粒在管式反应器中与氟/致密载体流体的气相接触，其中内部机械装置包括具有螺旋飞行的可旋转轴 ，多叶或线刷，使固相机械流化。 内部机械装置的设计是管状反应器的直径和长度以及聚合物树脂的固体颗粒的反应时间和其它物理性能的函数。 内部机械装置防止固体颗粒附聚，并通过诱导固体颗粒的迁移而促进与气相的均匀接触。 与气相的固体表面接触的增强有助于固体聚合物树脂和元素氟之间的反应，以及对致密载体流体的散热。

公开(公告)号：US5242661A

公开(公告)日：1993-09-07

申请号：US779369

申请日：1991-10-17

Applicant: Gregorio Tarancon

Inventor： Gregorio Tarancon

IPC: B01J3/00 ,  B01J4/00 ,  B01J8/00 ,  B01J8/10 ,  B01J8/18 ,  B01J8/24 ,  B01J8/26 ,  B01J19/20 ,  C08F2/00 ,  C08F8/22

CPC classification number: C08F8/22 ,  B01J19/20 ,  B01J8/0015 ,  B01J8/10 ,  B01J8/1881 ,  B01J8/24 ,  B01J8/26 ,  B01J2219/185 ,  B01J2219/187

Abstract: An apparatus for the direct fluorination of solid particles of polymeric resins capable of being fluorinated in which the solid particles are contacted by a flow of a mixture of fluorine and carrier fluid in a solid-gas reactor. In the solid-gas reactor, the fluid flow continuously agitates or fluidizes the solid particles to maintain the solid particles in motion. The degree of motion of the solid particles is a function of the linear velocity of the fluid and of the physical properties of the solid particles such as the solid bulk density, particle size, geometry of the solid particle, and adhesion or agglomeration of solid particles. The solid-gas reactor can be arranged with single or multi-reactors in batch or continous mode.

Abstract translation: 用于直接氟化能够被氟化的聚合物树脂的固体颗粒的装置，其中固体颗粒在固体 - 气体反应器中由氟和载体流体的混合物的流动接触。 在固体气体反应器中，流体流动连续搅拌或流化固体颗粒以保持固体颗粒运动。 固体颗粒的运动程度是流体的线速度和固体颗粒的物理性能的函数，例如固体堆积密度，颗粒尺寸，固体颗粒的几何形状以及固体颗粒的粘附或附聚 。 固态气体反应器可以分批或连续模式配置单个或多个反应器。