Process for producing C.sub.3 -C.sub.4 monoalkylchlorides
    4.
    发明授权
    Process for producing C.sub.3 -C.sub.4 monoalkylchlorides 失效
    生产C3-C4单烷基氯化物的方法

    公开(公告)号:US5132476A

    公开(公告)日:1992-07-21

    申请号:US719660

    申请日:1991-06-24

    CPC分类号: C07C17/16 C07C17/38

    摘要: The vaporous reaction product from the continuous reaction of C.sub.3 -C.sub.4 monoalkanols with hydrogen chloride is removed, condensed, and split into a light organic phase and a heavy aqueous phase. The heavy aqueous phase is immediately distilled yielding HCl-containing reaction water at the bottom of the column and an alcohol stream at the head of the column from where it is returned to the synthesis. The light organic phase is washed with water, dried and, optionally, distilled. The water from this washing operation is neutralized, stripped off in order to remove dissolved organic constituents, and removed as waste water from the system.

    摘要翻译: 将C3-C4单链烷醇与氯化氢的连续反应的气相反应产物除去,冷凝,分为轻质有机相和重质水相。 立即蒸馏出重质水相,在塔的底部产生含HCl的反应水,并在塔头从其返回到合成中的醇流。 轻质有机相用水洗涤,干燥,任选地蒸馏。 洗涤操作中的水被中和,剥离以除去溶解的有机成分,并从系统中作为废水除去。

    Process for the production of isopropyl alcohol
    6.
    发明授权
    Process for the production of isopropyl alcohol 失效
    异丙醇生产工艺

    公开(公告)号:US4760203A

    公开(公告)日:1988-07-26

    申请号:US86431

    申请日:1987-08-18

    IPC分类号: C07C29/04 C07C29/06

    CPC分类号: C07C29/04

    摘要: A direct hydration process for the production of isopropyl alcohol by reacting a propene-containing hydrocarbon stream with an aqueous stream in an interconnected series of reactors in the presence of an acidic cation exchange resin catalyst wherein the improvement comprises charging a propene-containing hydrocarbon stream to one end of a series of interconnected reactors and charging an aqueous stream to the opposite end of a series of interconnected reactors and directing the streams through the series of reactors so that the hydrocarbon stream and the aqueous stream flow in opposite directions with respect to the series of interconnected reactors and flow in parallel streams through each individual reactor is provided.

    摘要翻译: 在酸性阳离子交换树脂催化剂存在下,通过在相互连接的反应器系列中使含丙烯的烃物流与含水物流反应,生产异丙醇的直接水合方法,其中改进之处在于将含丙烯的烃物流 一系列相互连接的反应器的一端,并将水流装入一系列相互连通的反应器的相对端,并引导物流通过该系列反应器,使得烃流和水流相对于该系列的相反方向流动 的互连反应器并且通过每个单独的反应器以平行流流动。

    Process for the purifying distillation of crude sec-butyl alcohol
    8.
    发明授权
    Process for the purifying distillation of crude sec-butyl alcohol 失效
    粗制仲丁醇纯化蒸馏的方法

    公开(公告)号:US4902385A

    公开(公告)日:1990-02-20

    申请号:US233775

    申请日:1988-08-19

    申请人: Gunther Osterburg

    发明人: Gunther Osterburg

    CPC分类号: C07C29/82

    摘要: Practically anhydrous crude sec-butyl alcohol produced by catalytic direct hydration of n-butenes is freed by means of water from the azeotropically boiling and low-boiling by-products by continuous azeotropic distillation in a separation column, the prepurified anhydrous sec-butyl alcohol obtained is withdrawn and the high-boiling by-products are subsequently separated in a separate column.

    摘要翻译: 通过在分离塔中连续共沸蒸馏,通过来自共沸沸点和低沸点副产物的水来释放通过正丁烯的催化直接水合生产的实际无水粗制仲丁醇,得到预纯化的无水仲丁醇 并且高沸点副产物随后在单独的塔中分离。

    Process for the production of tertiary alcohols
    9.
    发明授权
    Process for the production of tertiary alcohols 失效
    生产叔醇的方法

    公开(公告)号:US4760202A

    公开(公告)日:1988-07-26

    申请号:US86429

    申请日:1987-08-18

    CPC分类号: C07C29/04

    摘要: Tertiary alcohols with 4 or 5 carbon atoms are produced by reacting an isoolefin-containing hydrocarbon stream with water in the presence of a strongly acidic, solid hydration catalyst in such a way that each of the two process streams, the hydrocarbon stream and the process water, is cascaded through several reactors connected in series such that one process stream is fed to one end of the line of reactors and the other process stream to the other end of the line of reactors, and the two process streams pass through the line of reactors in opposite directions, while they pass through the individual reactors as parallel currents.

    摘要翻译: 具有4或5个碳原子的叔醇通过在强酸性固体水合催化剂存在下使含异烯烃的烃流与水反应,使得两种工艺流,烃流和工艺水中的每一种 ,通过串联连接的几个反应器级联,使得一个工艺流被供给到反应器管线的一端,另一个工艺流进入反应器管线的另一端,并且两个工艺流通过反应器管线 在相反的方向,当它们作为并联电流通过各个反应器时。