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公开(公告)号：US20070006780A1
公开(公告)日：2007-01-11
申请号：US11392066
申请日：2006-03-29
IPC分类号： C04B28/26
CPC分类号： C04B28/36 , C01B17/0216 , C01B17/046 , C01B17/0469 , C04B14/06 , C04B24/00 , C04B40/0259
摘要： The invention provides a process for preparing a sulphur cement product comprising the following steps: (a) selectively oxidising hydrogen sulphide to elemental sulphur by contacting, in a reaction zone, a hydrogen sulphide containing feed gas and a molecular-oxygen containing gas with a particulate oxidation catalyst under selective oxidation conditions; (b) discharging a stream comprising liquid and/or solid elemental sulphur and particulate oxidation catalyst from the reaction zone; (c) admixing the stream comprising elemental sulphur and particulate oxidation catalyst with at least any one of elemental sulphur, a sulphur cement filler, a sulphur cement modifier, or aggregate at a temperature at which sulphur is molten; (d) solidifying the mixture obtained in step (c) by cooling it to a temperature below the melting temperature of sulphur to obtain the sulphur cement product. The invention further provides the use of a stream comprising elemental sulphur and particulate oxidation catalyst for preparing a sulphur cement product, which stream is obtained in selective oxidation step (a) of such process.
摘要翻译： 本发明提供了一种制备硫磺水泥产品的方法，包括以下步骤：（a）通过在反应区中将含硫化氢的进料气体和含分子氧气体与颗粒物接触，将硫化氢选择性氧化成元素硫 选择氧化条件下的氧化催化剂; （b）从反应区排出包含液体和/或固体元素硫和颗粒氧化催化剂的物流; （c）在硫熔融的温度下将包含元素硫和颗粒氧化催化剂的物流与元素硫，硫磺水泥填料，硫磺水泥改性剂或骨料中的至少一种混合; （d）将步骤（c）中得到的混合物冷却至低于硫的熔融温度的温度，得到硫磺水泥产品。 本发明还提供了包含元素硫和颗粒氧化催化剂的流的用途，用于制备硫磺水泥产品，该流是在这种方法的选择性氧化步骤（a）中获得的。
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公开(公告)号：US20070299148A1
公开(公告)日：2007-12-27
申请号：US11667501
申请日：2005-11-11
申请人： Guy Lode Verbist
发明人： Guy Lode Verbist
IPC分类号： C07C27/00
CPC分类号： B01J8/067 , B01J19/30 , B01J23/84 , B01J23/8913 , B01J35/023 , B01J2219/30238 , B01J2219/30242 , B01J2219/30246 , B01J2219/30269 , B01J2219/30273 , B01J2219/30408 , B01J2219/30416 , B01J2219/30475 , C10G2/331 , C10G2/341
摘要： A multitubular fixed bed reactor suitable for carrying out a catalytic process is described. There actor includes a plurality of reactor tubes, one or more of which include a fixed bed of catalyst and is/are at least partially surrounded by a heat transfer medium, preferably a cooling medium, wherein the one or more reactor tubes include at least one insert, especially a heat transfer insert and/or a pressure drop decreasing insert. Preferably the tubes are elongate, and preferably the inserts are elongate. The inserts may not extend the full length of their respective tube or tubes. The inserts may extend partly, substantially or wholly along the length of the relevant tube(s). All the tubes of the reactor may include a heat transfer and insert. Most preferably, the insert of the present invention reduces temperature differentials in a reactor tube and decrease the pressure drop over the reactor tube, so as to minimise even temperature differences, and thus optimise reaction conditions and catalytic activity within the reactor tube.
摘要翻译： 描述了适用于进行催化过程的多管式固定床反应器。 演员包括多个反应器管，其中一个或多个包括固定床催化剂，并且至少部分地被传热介质，优选冷却介质包围，其中一个或多个反应器管包括至少一个 插入，特别是传热插入件和/或降压插入件。 优选地，管是细长的，并且优选地，插入件是细长的。 插入件不能延伸其相应管或管的全长。 插入件可以沿着相关管的长度部分地，基本上或完全地延伸。 反应器的所有管子可以包括热传递和插入物。 最优选地，本发明的插入物减少了反应器管中的温度差并且降低了反应器管上的压力降，使得均匀温度差异最小化，从而优化反应器管内的反应条件和催化活性。
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公开(公告)号：US20090143493A1
公开(公告)日：2009-06-04
申请号：US12244415
申请日：2008-10-02
申请人： Jacobus Johannes Cornelis Geerlings , Marinus Johannes Reynhout , Wilhelmus Johannes Scholten , Guy Lode Verbist
发明人： Jacobus Johannes Cornelis Geerlings , Marinus Johannes Reynhout , Wilhelmus Johannes Scholten , Guy Lode Verbist
CPC分类号： B01J21/063 , B01J23/8892 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J37/0009 , C10G2/33 , C10G2/332 , Y10T428/2982
摘要： A titania catalyst support having a particle size distribution with a first peak at a first particle size and a second peak at a second particle size, wherein the second particle size is at least 50% larger than the first particle size. A method of manufacture is also disclosed. The support and resulting catalyst can be used for catalysing a Fischer-Tropsch reaction.
摘要翻译： 一种二氧化钛催化剂载体，其具有第一粒径的第一峰和第二粒径的第二峰的粒度分布，其中第二粒径比第一粒径大至少50％。 还公开了一种制造方法。 载体和所得催化剂可用于催化费 - 托反应。
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公开(公告)号：US20050228059A1
公开(公告)日：2005-10-13
申请号：US10519341
申请日：2003-06-18
CPC分类号： C10G2/32
摘要： The invention concerns a process for the preparation of hydrocarbons and the generation of heat involving i) introducing a gas comprising carbon monoxide and hydrogen into a first reactor section having catalyst and introducing cooling fluid into this first reactor section; ii) allowing a part of the carbon monoxide to react catalytically in the first reactor section to hydrocarbons and water, at least part of the reaction heat being absorbed directly by the cooling-fluid; iii) withdrawing from the reactor section a stream consisting of the reaction product containing the hydrocarbons, water, unconverted feed and cooling fluid; iv) cooling down at least a part of the withdrawn stream containing cooling fluid to generate heat; v) optionally removing water from the withdrawn stream, and, vi) repeating at least once steps I-v with the stream obtained in step v in further reactor section(s). The invention further relates to a reactor suitable for carrying out the above process.
摘要翻译： 本发明涉及一种制备烃类和产生热量的方法，包括：i）将含有一氧化碳和氢气的气体引入具有催化剂的第一反应器部分并将冷却流体引入该第一反应器部分; ii）允许一部分一氧化碳在第一反应器部分中催化反应成烃和水，至少部分反应热被冷却液直接吸收; iii）从反应器部分抽出由含有烃，水，未转化的进料和冷却流体的反应产物组成的料流; iv）冷却包含冷却流体的至少一部分排出的流以产生热量; v）任选地从排出的流中除去水，以及vi）用另外的反应器段中的步骤v中获得的物流重复至少一次步骤I-v。 本发明还涉及一种适于实施上述方法的反应器。
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