PROCESS FOR THE REMOVAL OF SULFUR COMPOUNDS FROM GAS STREAMS
    5.
    发明申请
    PROCESS FOR THE REMOVAL OF SULFUR COMPOUNDS FROM GAS STREAMS 失效
    从气体流中去除硫化合物的方法

    公开(公告)号:US20130216460A1

    公开(公告)日:2013-08-22

    申请号:US13545920

    申请日:2012-07-10

    IPC分类号: B01D53/48 B01D53/52 B01D53/50

    摘要: A method of reducing sulfur compounds from an incoming gas stream, comprising flowing the gas stream over a hydrolysis catalyst to convert COS and CS2 to H2S and reduce SO2 to elemental sulfur to form an effluent stream; providing an acidic gas removal unit comprising an absorbent; flowing said effluent stream over said absorbent to produce a stream free of acidic gases; applying an acidic-gas desorption mode to said acidic-gas rich absorbent to produce an acidic gas stream; introducing oxygen to said acidic gas-rich stream; providing a direct oxidation vessel containing catalyst suitable for catalyzing the oxidation of the H2S to sulfur wherein the temperature of the vessel is at or above the sulfur dew point at the reaction pressure; and flowing said acidic gas-rich stream over said catalyst to produce a processed stream having a reduced level of sulfur compounds.

    摘要翻译: 一种从进入的气流中还原硫化合物的方法,包括使气流流过水解催化剂以将COS和CS2转化为H 2 S并将SO 2还原成元素硫以形成流出物流; 提供包含吸收剂的酸性气体去除单元; 使所述流出物流流过所述吸收剂以产生不含酸性气体的流; 对所述富含酸性气体的吸收剂施加酸性气体解吸模式以产生酸性气流; 向所述酸性气体富集流引入氧气; 提供含有适于催化H 2 S氧化为硫的催化剂的直接氧化容器,其中容器的温度在反应压力下等于或高于硫露点; 并将所述酸性气体富余物流流过所述催化剂以产生具有降低的硫化合物含量的加工物流。

    PROCESS FOR REFORMATION OF HYDROGEN-CONTAINING FLUIDS IN A CYCLIC FLOW REACTOR
    6.
    发明申请
    PROCESS FOR REFORMATION OF HYDROGEN-CONTAINING FLUIDS IN A CYCLIC FLOW REACTOR 有权
    在循环流动反应器中重整含氢流体的方法

    公开(公告)号:US20130105739A1

    公开(公告)日:2013-05-02

    申请号:US13663980

    申请日:2012-10-30

    IPC分类号: C01B3/36 C01B3/02

    摘要: The invention discloses an apparatus and process for the reformation of hydrogen containing fluids to hydrogen and other constituents, more particularly, the reformation of hydrocarbons or mixtures of hydrocarbons in a cyclic flow inert porous media reactor for the production of hydrogen and other constituents. In an alternate embodiment, the apparatus and process can be used for the reformation of hydrogen sulfide to produce hydrogen and sulfur.The cyclic flow reactor comprises a reaction chamber filled with a porous media matrix containing an unconstrained reaction zone located in any portion of the reactor chamber. This reactor system employs valves to canalize the reactant mixture and product mixture during flow cycling channeling the reactant mixture through the porous media matrix, and reacting the reactant mixture. In another embodiment, the reactor system may further comprise at least one aperture along the axial length of the reactor casing to enable mounting of an external energy source and/or at least one heat exchanger to provide a source of heat transfer to the inlet pipe and outlet pipe as well as the reactant mixture and product mixtures.

    摘要翻译: 本发明公开了一种用于将含氢流体改性成氢气和其它组分的装置和方法,更具体地说,在用于生产氢气和其它组分的环流惰性多孔介质反应器中烃或烃混合物的改造。 在替代实施方案中,该装置和方法可用于硫化氢的重整以产生氢和硫。 循环流动反应器包括填充有多孔介质基质的反应室,该多孔介质基质含有位于反应器室的任何部分中的无约束反应区。 该反应器系统使用阀门在流动循环期间使反应物混合物和产物混合物流通,使反应物混合物通过多孔介质基质,并使反应物混合物反应。 在另一个实施例中,反应器系统可以进一步包括沿着反应器壳体的轴向长度的至少一个孔,以使得能够安装外部能量源和/或至少一个热交换器以提供对入口管的热传递源, 出口管以及反应物混合物和产物混合物。

    PROCESS FOR PRODUCING HYDROGEN, SULFUR AND SULFUR DIOXIDE FROM HYDROGEN SULFIDE-CONTAINING GAS STREAMS
    7.
    发明申请
    PROCESS FOR PRODUCING HYDROGEN, SULFUR AND SULFUR DIOXIDE FROM HYDROGEN SULFIDE-CONTAINING GAS STREAMS 有权
    含氢硫化氢生产氢,硫和二氧化硫的方法

    公开(公告)号:US20130071314A1

    公开(公告)日:2013-03-21

    申请号:US13238837

    申请日:2011-09-21

    申请人: Puneet GUPTA

    发明人: Puneet GUPTA

    IPC分类号: C01B17/74 C01B17/50

    摘要: A process for making molecular hydrogen, elemental sulfur and sulfur dioxide from hydrogen sulfide. The process involves contacting a gas stream of hydrogen sulfide within a contacting zone with a contacting composition comprising metal sulfide in a lower sulfided state and yielding from the contacting zone a product gas stream comprising hydrogen and a recovered contacting composition comprising metal sulfide in a higher sulfided state. The higher metal sulfide is regenerated with oxygen to yield elemental sulfur and sulfur dioxide.

    摘要翻译: 从硫化氢制造分子氢,元素硫和二氧化硫的方法。 该方法包括使接触区内的硫化氢气体与包含金属硫化物在较低硫化状态的接触组合物接触,并从接触区产生包含氢气的产物气流和回收的接触组合物,其包含较高硫化物中的金属硫化物 州。 较高的金属硫化物用氧再生,产生元素硫和二氧化硫。

    Process for treating acid gas in staged furnaces with inter-stage heat recovery and inter-stage sulfur production
    9.
    发明申请
    Process for treating acid gas in staged furnaces with inter-stage heat recovery and inter-stage sulfur production 审中-公开
    在阶段热回收和阶段内硫生产的阶段炉中处理酸性气体的方法

    公开(公告)号:US20090226364A1

    公开(公告)日:2009-09-10

    申请号:US12074954

    申请日:2008-03-07

    IPC分类号: C01B17/04 B01D53/48

    摘要: A process for treating acid gases comprising hydrogen sulfide comprises introducing a first acid gas and a first oxygen-containing gas into a reducing furnace to produce a first oxidized gas stream, cooling the first oxidized gas stream in a first heat recovery system, introducing the cooled gas stream into a sulfur condenser to produce a sulfur-stripped gas, introducing the sulfur-stripped gas and a second oxygen-containing gas into an oxidizing furnace to produce a second oxidized gas stream and cooling the second oxidized gas stream in a second heat recovery system. The first acid gas can be acid gas comprising hydrogen sulfide produced in refineries. The spent acid can be spent sulfuric acid from a sulfuric acid alkylation process. The cooled second oxidized gas stream can be further treated in a spent acid recovery plant or a sulfur recovery unit.

    摘要翻译: 一种用于处理含有硫化氢的酸性气体的方法,包括将第一种酸性气体和第一种含氧气体引入还原炉中以产生第一氧化气流,在第一热回收系统中冷却第一氧化气流, 气流进入硫冷凝器以产生硫汽提气体,将硫汽提气体和第二含氧气体引入氧化炉中以产生第二氧化气流并在第二热回收中冷却第二氧化气流 系统。 第一酸性气体可以是炼油厂生产的包含硫化氢的酸性气体。 废酸可以从硫酸烷基化方法处理废硫酸。 冷却的第二氧化气流可以在废酸回收装置或硫回收装置中进一步处理。

    Configurations and Methods For Effluent Gas Treatment
    10.
    发明申请
    Configurations and Methods For Effluent Gas Treatment 有权
    流出气体处理的配置和方法

    公开(公告)号:US20080279758A1

    公开(公告)日:2008-11-13

    申请号:US11578358

    申请日:2004-11-09

    IPC分类号: C01B17/16 B01J19/00

    摘要: Sulfur oxides are removed from an oxygen-containing acid gas in configurations and methods in which oxygen is catalytically removed using hydrogen sulfide, and in which the sulfur oxides react with the hydrogen sulfide to form elemental sulfur. A first portion of the remaining sulfurous compounds is reduced to form the hydrogen sulfide for oxygen removal, while a second portion of the sulfurous compounds is further converted to elemental sulfur using a Claus reaction or catalytic direct reduction reaction.

    摘要翻译: 在使用硫化氢催化除氧的结构和方法中,从含氧酸性气体中除去硫氧化物,其中硫氧化物与硫化氢反应形成元素硫。 剩余的亚硫酸化合物的第一部分被还原以形成用于除氧的硫化氢,而使用克劳斯反应或催化直接还原反应将第二部分亚硫酸化合物进一步转化为元素硫。