公开(公告)号：US11879080B2

公开(公告)日：2024-01-23

申请号：US16720129

申请日：2019-12-19

申请人： HENKEL AG & CO. KGAA

发明人： Atsushi Kakuda ,  Naohiro Maeda

IPC分类号： C09J7/35 ,  C09J7/38 ,  C08L23/20 ,  C08L91/00 ,  C09J11/08 ,  C09J123/08 ,  C09J123/12

CPC分类号： C09J7/35 ,  C08L23/20 ,  C08L91/00 ,  C09J7/381 ,  C09J11/08 ,  C09J123/0815 ,  C09J123/12 ,  C08L2205/035 ,  C08L2314/06

摘要： Disclosed is a hot melt adhesive comprising: (A) a metallocene based propylene homopolymer, (B) a metallocene based ethylene/α-olefin copolymer, (C) a tackifier resin, and (D) a plasticizer, wherein the plasticizer (D) comprises (D1) an oil and (D2) at least one polymer selected from polybutene, polybutadiene, polyisobutylene, and polyisoprene. This hot melt adhesive has an initial adhesive strength enough to enable a pressure sensitive adhesion body to stick easily on a member, thus making it possible to firmly hold the pressure sensitive adhesion body on the member. The hot melt adhesive is also excellent in releasability, thus causing no adhesive residue on the member when the pressure sensitive adhesion body is peeled from the member.

公开(公告)号：US10513642B2

公开(公告)日：2019-12-24

申请号：US16167812

申请日：2018-10-23

申请人： HENKEL AG & CO. KGAA

发明人： Kentarou Inoue ,  Masahiro Moriguchi ,  Naohiro Maeda

IPC分类号： C09J153/02 ,  C08K5/01 ,  C09J145/00 ,  A61F13/15

摘要： Problem to be solved of the present invention is to provide a hot-melt adhesive agent which is capable of applying at low temperature, has an excellent adhesiveness at low temperature, and a disposable product obtained by employing the hot-melt adhesive agent. Means for solving the problem is a hot-melt adhesive agent comprised of a thermoplastic block copolymer (A) which is a copolymer of vinyl class aromatic hydrocarbons and conjugated diene compounds, wherein the thermoplastic block copolymer (A) comprises a radial type styrene block copolymer having a styrene content of 35 to 45% by weight and a diblock content of 50 to 90% by weight, and having a viscosity at 25° C. as a 25% (by weight) toluene solution of not more than 250 mPa·s (A1).

公开(公告)号：US10138400B2

公开(公告)日：2018-11-27

申请号：US15598426

申请日：2017-05-18

申请人： HENKEL AG & CO. KGAA

发明人： Kentarou Inoue ,  Masahiro Moriguchi ,  Naohiro Maeda

IPC分类号： C09J153/02 ,  C08K5/01 ,  C09J145/00 ,  A61F13/15

摘要： Problem to be solved of the present invention is to provide a hot-melt adhesive agent which is capable of applying at low temperature, has an excellent adhesiveness at low temperature, and a disposable product obtained by employing the hot-melt adhesive agent. Means for solving the problem is a hot-melt adhesive agent comprised of a thermoplastic block copolymer (A) which is a copolymer of vinyl class aromatic hydrocarbons and conjugated diene compounds, wherein the thermoplastic block copolymer (A) comprises a radial type styrene block copolymer having a styrene content of 35 to 45% by weight and a diblock content of 50 to 90% by weight, and having a viscosity at 25° C. as a 25% (by weight) toluene solution of not more than 250 mPa·s (A1).

公开(公告)号：US10017672B2

公开(公告)日：2018-07-10

申请号：US14944526

申请日：2015-11-18

申请人： HENKEL AG & CO. KGAA

发明人： Masahiro Moriguchi ,  Naohiro Maeda

IPC分类号： C09J153/02 ,  B32B37/12 ,  A61L15/58 ,  C08L53/02

CPC分类号： C09J153/02 ,  A61L15/585 ,  B32B37/1207 ,  B32B2037/1215 ,  C08L53/02 ,  C08L2205/02

摘要： Problem to be solved of the present invention is to provide a hot-melt adhesive agent which is capable of applying at low temperature, excellent in adhesiveness at the wide temperature ranges (10 to 40° C.), and excellent in balance between tackiness and retention force, and a disposable product obtained by employing the hot-melt adhesive agent. Means for Solving the problem is a hot-melt adhesive agent comprising a thermoplastic block copolymer (A) which is a copolymer of vinyl class aromatic hydrocarbons and conjugated diene compounds, wherein the thermoplastic block copolymer (A) comprises the following component (A1) and component (A2): (A1) a radial type styrene block copolymer having a styrene content of 35 to 45% by weight, a diblock content of 50 to 90% by weight, and has a viscosity at 25° C. as 25% toluene solution of not more than 250 mPa·s; and (A2) a triblock type styrene block copolymer.

公开(公告)号：US09816014B2

公开(公告)日：2017-11-14

申请号：US14211178

申请日：2014-03-14

申请人： HENKEL AG & CO. KGAA

发明人： Masahiro Moriguchi ,  Shigekazu Saito ,  Kentarou Inoue ,  Takanori Okuda ,  Naohiro Maeda

IPC分类号： C09J123/12 ,  C08L23/12 ,  C09J151/06 ,  C08L51/06

CPC分类号： C09J123/12 ,  C08L23/12 ,  C08L51/06 ,  C09J151/00 ,  C09J151/06 ,  Y10T428/2891 ,  Y10T442/2738 ,  C08L51/00

摘要： The present invention provides a hot melt adhesive suitable for use in disposable products, which can be applied at a high speed and provides excellent in adhesion in a wet state and low-temperature coating, with little odor. The hot melt adhesive for disposable products comprises: (A) a propylene homopolymer having a melting point of 100° C. or lower obtained by polymerizing propylene using a metallocene catalyst; and (B) a wax modified with carboxylic acid and/or carboxylic acid anhydride. The wet adhesion of the hot melt adhesive is improved when the wax is modified with maleic acid and/or maleic anhydride.

公开(公告)号：US10808151B2

公开(公告)日：2020-10-20

申请号：US16006109

申请日：2018-06-12

申请人： HENKEL AG & CO. KGAA

发明人： Masahiro Moriguchi ,  Naohiro Maeda

IPC分类号： C09J153/02 ,  C08L53/02 ,  B32B37/12 ,  A61L15/58

摘要： Problem to be solved of the present invention is to provide a hot-melt adhesive agent which is capable of applying at low temperature, excellent in adhesiveness at the wide temperature ranges (10 to 40° C.), and excellent in balance between tackiness and retention force, and a disposable product obtained by employing the hot-melt adhesive agent. Means for Solving the problem is a hot-melt adhesive agent comprising a thermoplastic block copolymer (A) which is a copolymer of vinyl class aromatic hydrocarbons and conjugated diene compounds, wherein the thermoplastic block copolymer (A) comprises the following component (A1) and component (A2): (A1) a radial type styrene block copolymer having a styrene content of 35 to 45% by weight, a diblock content of 50 to 90% by weight, and has a viscosity at 25° C. as 25% toluene solution of not more than 250 mPa·s; and (A2) a triblock type styrene block copolymer.

公开(公告)号：US09765245B2

公开(公告)日：2017-09-19

申请号：US14865004

申请日：2015-09-25

申请人： HENKEL AG & CO. KGAA

发明人： Kentarou Inoue ,  Masahiro Moriguchi ,  Naohiro Maeda

IPC分类号： C09J153/02 ,  C09J145/00 ,  C08K5/01 ,  A61F13/15

CPC分类号： C09J153/02 ,  A61F13/15 ,  C08K5/01 ,  C09J145/00

摘要： Problem to be solved of the present invention is to provide a hot-melt adhesive agent which is capable of applying at low temperature, has an excellent adhesiveness at low temperature, and a disposable product obtained by employing the hot-melt adhesive agent. Means for solving the problem is a hot-melt adhesive agent comprised of a thermoplastic block copolymer (A) which is a copolymer of vinyl class aromatic hydrocarbons and conjugated diene compounds, wherein the thermoplastic block copolymer (A) comprises a radial type styrene block copolymer having a styrene content of 35 to 45% by weight and a diblock content of 50 to 90% by weight, and having a viscosity at 25° C. as a 25% (by weight) toluene solution of not more than 250 mPa·s (A1).