Abstract:
Provided is a battery including: a positive electrode; a negative electrode; and an electrolyte layer, in which a laminate in which the negative electrode, the electrolyte layer, the positive electrode, the electrolyte layer, and the negative electrode are laminated in this order is regarded as a minimum unit, the positive electrode is composed of a first composite body consisting of a metal body and a positive electrode mixture containing a positive electrode active material, the negative electrode is composed of a second composite body consisting of a metal body and a negative electrode mixture containing a negative electrode active material, and the metal bodies are metallic porous bodies or metal meshes.
Abstract:
Provided is an electrode mixture layer capable of reducing internal resistance by use of a carbon nanotube molding. The electrode mixture layer includes an active material and a conductor of carbon nanotubes in close contact with the surface of the active material, and the number density of the carbon nanotubes is 4 tubes/μm or more. The number density is defined as a value obtained by providing measurement lines on a scanning electron microscope image of a surface of the electrode mixture layer at 0.3 μm intervals both longitudinally and laterally, measuring the total number of the carbon nanotubes being in close contact with the surface of the active material and intersecting the measurement lines, and dividing the total number of the carbon nanotubes by the total length of the measurement lines on the active material surface.
Abstract:
Provided is a metal oxygen battery 1 including a positive electrode 2 having oxygen as an active material, a negative electrode 3 having metallic lithium as an active material, and an electrolyte layer 4 interposed between the positive electrode 2 and negative electrode 3. The positive electrode 2 contains oxygen storage material including mixed crystal of hexagonal composite metal oxide expressed by the general formula AxByOz (in which, A is one type of metal selected from a group of Y, Sc, La, Sr, Ba, Zr, Au, Ag, Pt, Pd, B is one type of metal selected from a group of Mn, Ti, Ru, Zr, Ni, Cr, and x=1, 1≦y≦2, 1≦z≦7, provided that a case where both A and B are Zr is excluded) and one or more non-hexagonal composite metal oxide expressed by the general formula AxByOz.
Abstract:
To provide a negative electrode for nonaqueous electrolyte secondary batteries, by which the structural deterioration of the electrode is suppressed and cycle characteristics can be improved by absorbing the expansion and contraction of a silicon-based active material placed in the inside of a current collector made of porous metal, and a nonaqueous electrolyte secondary battery including the same. A negative electrode for nonaqueous electrolyte secondary batteries, having a current collector made of porous metal, and a negative electrode material placed in pores of the porous metal, the negative electrode material including a negative electrode active material including a silicon-based material; a skeleton forming agent including a silicate having a siloxane bond; a conductive additive; a binder; and a fibrous material.
Abstract:
In a lithium ion secondary battery (1), a positive electrode (2) and a negative electrode (3) are alternately adjacent to each other via separators (4) and (5). The positive electrode (2) includes a positive electrode current collector composed of a metal porous body, a first positive electrode active material (21) held on one side of the positive electrode current collector, and a second positive electrode active material (22) held on the other side. The negative electrode (3) includes a negative electrode current collector composed of a metal porous body, a first negative electrode active material (31) held on one side of the negative electrode current collector, and a second negative electrode active material (32) held on the other side. The first positive electrode active material (21) faces the first negative electrode active material (31), and the positive electrode active material (22) faces the second negative electrode active material (32).
Abstract:
Provided is a metal oxygen battery 1 including a positive electrode 2 having oxygen as an active material, a negative electrode 3 having metallic lithium as an active material, and an electrolyte layer 4 interposed between the positive electrode 2 and negative electrode 3. The positive electrode 2 contains oxygen storage material including mixed crystal of hexagonal composite metal oxide expressed by the general formula AxByOz (in which, A is one type of metal selected from a group of Y, Sc, La, Sr, Ba, Zr, Au, Ag, Pt, Pd, B is one type of metal selected from a group of Mn, Ti, Ru, Zr, Ni, Cr, and x=1, 1≦y≦2, 1≦z≦7, provided that a case where both A and B are Zr is excluded) and one or more non-hexagonal composite metal oxide expressed by the general formula AxByOz.
Abstract:
A positive electrode includes a metal porous body, a positive electrode mixture containing a positive electrode active material loaded into the metal porous body and a current collection part connected to the metal porous body, and the metal porous body has a region with a porosity of less than 60%.
Abstract:
Provided are a negative electrode that is for use in a non-aqueous electrolyte secondary battery, includes a porous metal body as a current collector, contains a skeleton-forming agent highly infiltrated in the current collector so that it is less likely to suffer from structural degradation and provides improved cycle durability; and a non-aqueous electrolyte secondary battery including such a negative electrode. The negative electrode for use in a non-aqueous electrolyte secondary battery includes a current collector including a porous metal body; a first negative electrode material disposed in pores of the porous metal body and including a conductive aid, a binder, and a negative electrode active material including a silicon-based material; and a second negative electrode material disposed in pores of the porous metal body and including a skeleton-forming agent including a silicate having a siloxane bond.
Abstract:
Provided are a negative electrode that is for use in a non-aqueous electrolyte secondary battery, includes a porous metal body as a current collector, contains a skeleton-forming agent highly infiltrated in the current collector so that It is less likely to suffer from structural degradation and provides improved cycle durability; and a non-aqueous electrolyte secondary battery including such a negative electrode. The negative electrode for use in a non-aqueous electrolyte secondary battery includes a current collector including a porous metal body; a first negative electrode material disposed in pores of the porous metal body and including a conductive aid, a binder, and a negative electrode active material including a silicon-based material; and a second negative electrode material disposed in pores of the porous metal body and including a skeleton-forming agent including a silicate having a siloxane bond.
Abstract:
In a lithium ion secondary battery (1), a positive electrode (2) and a negative electrode (3) are alternately adjacent to each other via separators (4) and (5). The positive electrode (2) includes a positive electrode current collector composed of a metal porous body, a first positive electrode active material (21) held on one side of the positive electrode current collector, and a second positive electrode active material (22) held on the other side. The negative electrode (3) includes a negative electrode current collector composed of a metal porous body, a first negative electrode active material (31) held on one side of the negative electrode current collector, and a second negative electrode active material (32) held on the other side. The first positive electrode active material (21) faces the first negative electrode active material (31), and the positive electrode active material (22) faces the second negative electrode active material (32).