公开(公告)号：US20170007975A1

公开(公告)日：2017-01-12

申请号：US15120723

申请日：2014-03-04

Applicant: HUTCHINSON

Inventor： Bruno DUFOUR ,  Hugo DORIE ,  Philippe SONNTAG

IPC: B01J13/00 ,  H01G11/32 ,  C08G8/22 ,  E04B1/78 ,  C01B31/02 ,  C08J3/075

CPC classification number: B01J13/0091 ,  B01J13/0065 ,  C01B32/05 ,  C08G8/22 ,  C08J3/075 ,  C08J2361/12 ,  E04B1/78 ,  H01G11/32

Abstract: The invention relates to a gelled carbon-based composition forming an organic polymeric monolithic gel which is suitable for forming an aerogel by drying, to uses and to a process for preparing this carbon-based composition. The invention applies especially to the production of such gels having a very low density and a very low heat conductivity, a very high specific surface area and a satisfactory compression strength, for their use as thermal superinsulators or as carbon-based electrode precursors of supercondensers.A composition according to the invention comprises a resin at least partly derived from polyhydroxybenzenes H and from formaldehyde(s) F, said polyhydroxybenzenes comprising at least one unsubstituted poly-hydroxybenzene R′ and at least one polyhydroxybenzene substituted with one or two alkyl groups.This composition is such that said polyhydroxybenzenes comprise several said unsubstituted polyhydroxybenzenes R and R′ and in that the composition comprises a water-soluble cationic polyelectrolyte P.

Abstract translation: 该组合物使得所述多羟基苯包含数个所述未取代的多羟基苯R和R'，并且组合物包含水溶性阳离子聚电解质P.

公开(公告)号：US20170197839A1

公开(公告)日：2017-07-13

申请号：US15316775

申请日：2015-06-10

Applicant: HUTCHINSON

Inventor： Hugo DORIE ,  David AYME-PERROT ,  Philippe SONNTAG ,  Bruno DUFOUR

IPC: C01B31/02 ,  C08G73/06 ,  H01G11/34

CPC classification number: H01G11/34 ,  C01B32/05 ,  C01B32/342 ,  C01B32/382 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/40 ,  C08G8/22 ,  C08G73/0683 ,  C08G2210/00 ,  H01G11/24 ,  H01G11/32 ,  H01G11/44 ,  Y02E60/13 ,  Y02T10/7022

Abstract: The invention relates to a gelled aqueous polymer composition for forming, by means of drying then pyrolysis, a monolithic porous carbon, to a pyrolysed carbonated composition produced by the drying, followed by the pyrolysis, of said gelled composition, to a porous carbon electrode for a supercapacitor comprising said pyrolysed composition, and to methods for producing said respectively gelled and pyrolysed compositions. A gelled composition according to the invention, produced from the polycondensation of polyhydroxybenzene(s) and hexymethylenetetramine, is such that the hexymethylenetetramine comprised therein represents a mass fraction of between 7% and 15% inclusive. Said gelled composition is produced by a) polycondensation in an aqueous solvent of the polyhydroxybenzene(s) and hexymethylenetetramine, followed by b) gelling by heating of said polycondensate.

公开(公告)号：US20170029574A1

公开(公告)日：2017-02-02

申请号：US15302412

申请日：2014-04-07

Applicant: HUTCHINSON

Inventor： Yannick BUREAU ,  Hugo DORIE ,  Philippe SONNTAG ,  Bruno DUFOUR ,  Jeremie JACQUEMOND

IPC: C08J3/075 ,  H01G11/28 ,  H01G11/32 ,  H01G11/26 ,  C01B31/08 ,  C08J9/28

CPC classification number: C08J3/075 ,  C01B32/00 ,  C01B32/05 ,  C01B32/382 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/40 ,  C08J9/0061 ,  C08J9/28 ,  C08J2201/026 ,  C08J2201/0504 ,  C08J2205/026 ,  C08J2361/10 ,  C08J2361/12 ,  C08J2433/14 ,  C08J2439/00 ,  C08J2479/00 ,  H01G11/26 ,  H01G11/28 ,  H01G11/32 ,  Y02E60/13

Abstract: The invention relates to a gelled, crosslinked and non-dried aqueous polymeric composition capable of forming a non-monolithic organic aerogel by drying, to this aerogel, to a non-monolithic porous carbon resulting from a pyrolysis of this aerogel, to an electrode based on this porous carbon, and to a process for preparing this composition and this aerogel. The invention applies in particular to supercapacitors. A gelled, crosslinked and non-dried composition according to the invention, which is based on a resin resulting at least partly from a polycondensation of polyhydroxybenzene(s) R and formaldehyde(s) F and which comprises at least one water-soluble cationic polyelectrolyte P, is such that the composition is formed from an aqueous dispersion of microparticles of a shear-thinning physical gel that is crosslinked in an aqueous medium. The composition not yet crosslinked is in particular prepared by dilution of a prepolymer that forms this gel in an aqueous solvent in order to form the aqueous dispersion of microparticles of said gel.

Abstract translation: 本发明涉及胶凝的，交联的和非干燥的水性聚合物组合物，其能够通过将由该气凝胶的热解产生的非整体多孔碳干燥至该气凝胶形成非整体有机气凝胶 在该多孔碳上，以及制备该组合物和该气凝胶的方法。 本发明特别适用于超级电容器。 根据本发明的胶凝的，交联的和未干燥的组合物，其基于至少部分地由多羟基苯R和甲醛F缩聚得到的树脂，并且其包含至少一种水溶性阳离子聚电解质 P是使得组合物由在水性介质中交联的剪切稀化物理凝胶的微粒的水分散体形成。 还未交联的组合物特别是通过在水性溶剂中稀释形成该凝胶的预聚物以形成所述凝胶微粒的水分散体来制备。