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    A PROCESS FOR PRODUCING CO FROM CO2 IN A SOLID OXIDE ELECTROLYSIS CELL
    2.
    发明申请
    A PROCESS FOR PRODUCING CO FROM CO2 IN A SOLID OXIDE ELECTROLYSIS CELL 审中-公开
    在固体氧化物电解池中从CO 2生产CO的方法

    公开(公告)号：US20160040311A1

    公开(公告)日：2016-02-11

    申请号：US14780462

    申请日：2013-03-26

    申请人： HALDOR TOPSØE A/S

    发明人： Niklas Bengt Jakobsson ,  Claus Friis Pedersen ,  John Bøgild Hansen

    IPC分类号： C25B15/08 ,  B01D53/047 ,  C25B15/02 ,  C25B1/00 ,  C25B9/18

    CPC分类号： C25B15/08 ,  B01D53/047 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/1122 ,  B01D2253/1124 ,  B01D2256/20 ,  B01D2257/504 ,  B01D2259/402 ,  C25B1/00 ,  C25B9/00 ,  C25B9/18 ,  C25B15/00 ,  C25B15/02 ,  Y02E60/366

    摘要： The invention concerns a process for producing carbon monoxide (CO) from carbon dioxide (CO2) in a solid oxide electrolysis cell (SOEC) or SOEC stack, wherein CO2 is led to the fuel side of the stack with an applied current and excess oxygen is transported to the oxygen side of the stack, optionally using air or nitrogen to flush the oxygen side, and wherein the product stream from the SOEC, containing CO mixed with CO2, is subjected to a separation process. The process further comprises heating the inlet gas on both the fuel side and the oxygen side by means of separate heating units, so as to supply heat to the SOEC, where the operation temperature of said heating units is at least equal to the operation temperature of the cell stack minus 50° C., preferably at least equal to the operation temperature of the cell stack.

    摘要翻译： 本发明涉及一种在固体氧化物电解池（SOEC）或SOEC堆中从二氧化碳（CO 2）生产一氧化碳（CO）的方法，其中CO 2以施加的电流被引导到堆的燃料侧，过量的氧是 运送到堆的氧气侧，任选地使用空气或氮气冲洗氧气侧，并且其中来自含有与CO混合的CO的SOEC的产物流经受分离过程。 该方法还包括通过单独的加热单元加热燃料侧和氧气侧的入口气体，以便向SOEC供应热量，其中所述加热单元的操作温度至少等于 电池堆减去50℃，优选至少等于电池堆的工作温度。

    Method for removing hydrogen sulfide from an acid gas
    6.
    发明授权
    Method for removing hydrogen sulfide from an acid gas 有权

    公开(公告)号：US10323202B2

    公开(公告)日：2019-06-18

    申请号：US15531659

    申请日：2015-12-03

    申请人： HALDOR TOPSØE A/S

    发明人： Niklas Bengt Jakobsson ,  Claus Friis Pedersen

    IPC分类号： B01D53/86 ,  B01D53/22 ,  B01D53/52 ,  B01D53/75 ,  C10L3/10

    摘要： A method for removing hydrogen sulfide (H2S) from an acid gas comprises feeding the gas to a membrane separation unit, collecting the product gas from the membrane unit, heating the permeate stream to the necessary inlet temperature for catalytic oxidation of H2S and feeding the heated permeate stream to a catalytic oxidation unit, where H2S is oxidized to SO2. The heating of the permeate stream is accomplished by using a fraction of the feed gas to heat the permeate stream in a separate heater or by using a steam-fired heater. The method is especially suited for use on an off-shore facility.

    Process for the production of chemical compounds from carbon dioxide
    7.
    发明授权
    Process for the production of chemical compounds from carbon dioxide 有权
    从二氧化碳生产化学化合物的方法

    公开(公告)号：US09273020B2

    公开(公告)日：2016-03-01

    申请号：US14394508

    申请日：2013-04-11

    申请人： Haldor Topsøe A/S

    发明人： Niels Christian Schjødt ,  John Bøgild Hansen ,  Claus Friis Pedersen

    IPC分类号： C07D305/00 ,  C07C69/96 ,  C07C51/14 ,  C07D305/12 ,  C07C67/38 ,  C07C68/00 ,  C07C201/02 ,  C07D301/04 ,  C25B1/02 ,  C25B15/08 ,  C25B1/00 ,  C07C67/035 ,  C07C68/04

    CPC分类号： C07D305/12 ,  C07C51/14 ,  C07C67/035 ,  C07C67/38 ,  C07C68/005 ,  C07C68/04 ,  C07C201/02 ,  C07D301/04 ,  C25B1/00 ,  C25B1/02 ,  C25B15/08 ,  Y02E60/366 ,  Y02P20/133 ,  Y02P20/134 ,  Y02P20/582 ,  C07C203/04 ,  C07C69/96 ,  C07C53/124 ,  C07C69/24

    摘要： Process for the production of a chemical compound from a carbon dioxide starting material, comprising the steps of a) providing a feed stream consisting mainly of carbon dioxide; b) electrolyzing in an electrolysis stage the carbon dioxide in the feed stream to a first gas stream containing carbon monoxide and a second gas stream containing oxygen, wherein the molar ratio between carbon monoxide and oxygen is about 1:0.5 in an electrolysis stage; c) adjusting the composition of the first gas stream or the second gas stream or both gas streams to include carbon dioxide, either by operating at less than full conversion of CO2 or by sweeping one or both gas streams with a gas containing CO2 or by at some stage between the electrolysis cell and the oxidative carbonylation reactor diluting one or both gas streams with a gas containing CO2; all while maintaining an overall molar ratio of carbon monoxide to oxygen of about 1:0.5; and d) introducing the first and second process stream into a reaction stage and reacting the first and second process stream combined or in succession with a substrate to the chemical compound by means of an oxidative carbonylation reaction with the carbon monoxide and oxygen contained in the process feed stream.

    摘要翻译： 用于从二氧化碳原料生产化合物的方法，包括以下步骤：a）提供主要由二氧化碳组成的进料流; b）在电解阶段中将进料流中的二氧化碳电解成含有一氧化碳和含有氧的第二气流的第一气流，其中在电解阶段一氧化碳和氧之间的摩尔比为约1:0.5; c）调节第一气流或第二气流或两种气流的组成以包括二氧化碳，或者通过以少于二氧化碳的全部转化率进行操作，或者通过用含有CO 2的气体或通过在 在电解池和氧化羰基化反应器之间的某个阶段，用含CO 2的气体稀释一种或两种气流; 同时保持一氧化碳与氧的总摩尔比为约1:0.5; 和d）将第一和第二工艺流引入反应阶段，并通过与该方法中所含的一氧化碳和氧气进行氧化羰基化反应，将第一和第二工艺流与底物组合或连续地与化学化合物反应 饲料流。

    PROCESS FOR MONITORING, PROTECTION AND SAFETY SHUT-DOWN OF AN ELECTROLYSER SYSTEM
    8.
    发明申请
    PROCESS FOR MONITORING, PROTECTION AND SAFETY SHUT-DOWN OF AN ELECTROLYSER SYSTEM 审中-公开
    电子系统监控，保护和安全切断的过程

    公开(公告)号：US20150329980A1

    公开(公告)日：2015-11-19

    申请号：US14763226

    申请日：2013-01-25

    申请人： HALDOR TOPSØE A/S

    发明人： Claus Friis Pedersen ,  Lone Bech ,  Thomas Heiredal-Clausen ,  Niklas Bengt Jakobsson

    IPC分类号： C25B15/02

    CPC分类号： C25B15/02 ,  C25B1/10

    摘要： The invention concerns a process for monitoring failure situations related to feed and/or purge flow in electrolyser cells, stacks or systems, said monitoring process being combined with appropriate actions to be taken in case of such failure situations, wherein (a) the current and/or the voltage are monitored and controlled over a single cell, over all the cells or over one or more selected cells in a stack or a system of stacks, (b) in case the current, the voltage or the ratio between voltage and current crosses its pre-defined threshold value, a failure mode is detected and communicated to the control system, and c) the voltage levels of the system are adjusted to be within safe limits (safe-mode limits).

    摘要翻译： 本发明涉及用于监测与电解槽单元，堆叠或系统中的进料和/或吹扫流相关的故障情况的过程，所述监测过程与在这种故障情况下采取的适当动作组合，其中（a）当前和 /或电压通过单个电池，在所有电池上或在堆叠或堆叠系统中的一个或多个选定电池上进行监测和控制，（b）在电流，电压或电压与电流之间的情况下 跨越其预定义的阈值，检测故障模式并传送到控制系统，以及c）将系统的电压电平调整到安全限制（安全模式限制）内。

    PROCESS FOR THE PRODUCTION OF CHEMICAL COMPOUNDS FROM CARBON DIOXIDE
    9.
    发明申请
    PROCESS FOR THE PRODUCTION OF CHEMICAL COMPOUNDS FROM CARBON DIOXIDE 有权
    从二氧化碳生产化学化合物的方法

    公开(公告)号：US20150057458A1

    公开(公告)日：2015-02-26

    申请号：US14394508

    申请日：2013-04-11

    申请人： Haldor Topsøe A/S

    发明人： Niels Christian Schjødt ,  John Bøgild Hansen ,  Claus Friis Pedersen

    IPC分类号： C07D305/12 ,  C25B1/02 ,  C25B1/00 ,  C07C68/04 ,  C07C67/035

    CPC分类号： C07D305/12 ,  C07C51/14 ,  C07C67/035 ,  C07C67/38 ,  C07C68/005 ,  C07C68/04 ,  C07C201/02 ,  C07D301/04 ,  C25B1/00 ,  C25B1/02 ,  C25B15/08 ,  Y02E60/366 ,  Y02P20/133 ,  Y02P20/134 ,  Y02P20/582 ,  C07C203/04 ,  C07C69/96 ,  C07C53/124 ,  C07C69/24

    摘要： Process for the production of a chemical compound from a carbon dioxide starting material, comprising the steps of a) providing a feed stream consisting mainly of carbon dioxide; b) electrolysing in an electrolysis stage the carbon dioxide in the feed stream to a first gas stream containing carbon monoxide and a second gas stream containing oxygen, wherein the molar ratio between carbon monoxide and oxygen is about 1:0.5 in an electrolysis stage; c) adjusting the composition of the first gas stream or the second gas stream or both gas streams to include carbon dioxide, either by operating at less than full conversion of CO2 or by sweeping one or both gas streams with a gas containing CO2 or by at some stage between the electrolysis cell and the oxidative carbonylation reactor diluting one or both gas streams with a gas containing CO2; all while maintaining an overall molar ratio of carbon monoxide to oxygen of about 1:0.5; and d) introducing the first and second process stream into a reaction stage and reacting the first and second process stream combined or in succession with a substrate to the chemical compound by means of an oxidative carbonylation reaction with the carbon monoxide and oxygen contained in the process feed stream.

    摘要翻译： 用于从二氧化碳原料生产化合物的方法，包括以下步骤：a）提供主要由二氧化碳组成的进料流; b）在电解阶段将电解中的二氧化碳电解成含有一氧化碳和含有氧的第二气流的第一气流，其中一氧化碳与氧之间的摩尔比在电解阶段为约1:0.5; c）调节第一气流或第二气流或两种气流的组成以包括二氧化碳，或者通过以少于二氧化碳的全部转化率进行操作，或者通过用含有CO 2的气体或通过在 在电解池和氧化羰基化反应器之间的某个阶段，用含CO 2的气体稀释一种或两种气流; 同时保持一氧化碳与氧的总摩尔比为约1:0.5; 和d）将第一和第二工艺流引入反应阶段，并通过与该方法中所含的一氧化碳和氧气进行氧化羰基化反应，将第一和第二工艺流与底物组合或连续地与化学化合物反应 饲料流。