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    METHOD FOR DERIVING METHANOL FROM WASTE GENERATED METHANE AND STRUCTURED PRODUCT FORMULATED THEREFROM
    5.
    发明申请
    METHOD FOR DERIVING METHANOL FROM WASTE GENERATED METHANE AND STRUCTURED PRODUCT FORMULATED THEREFROM 失效
    从废物生成甲烷中衍生甲醇的方法及其配制的结构化产物

    公开(公告)号：US20060264683A1

    公开(公告)日：2006-11-23

    申请号：US11382923

    申请日：2006-05-11

    申请人： Walter Knox ,  Carol Knox

    发明人： Walter Knox ,  Carol Knox

    IPC分类号： C07C27/12

    CPC分类号： C07C29/00 ,  C07C67/035 ,  C07C69/80 ,  C07C31/04

    摘要： Methanol is produced from bacterially oxidized waste methane by reaction with Pd+2, Cu+2 air, and molten phthalic anhydride in an entrained oxidizer generating half ester of methyl phthalate which is reaction distilled to prodtice methanol and recycle phthalic anliydride containing the Pd+2,Cu+2 phthalate catalyst.

    摘要翻译： 甲醇由细菌氧化的废甲烷通过与Pd + 2 +，CO + 2空气和熔融的邻苯二甲酸酐在夹带的氧化剂中反应生成，产生邻苯二甲酸甲酯的半酯， 反应蒸馏生成甲醇，并回收含有Pd + + 2，邻苯二甲酸+邻苯二甲酸二甲酯催化剂的邻苯二甲酸酐。

    Process for preparing aliphatic monocarboxylic acid ester of hydroxymethyl-substituted monoaromatic compound
    8.
    发明授权
    Process for preparing aliphatic monocarboxylic acid ester of hydroxymethyl-substituted monoaromatic compound 失效
    制备羟甲基取代的单芳族化合物的脂族一元羧酸酯的方法

    公开(公告)号：US4224456A

    公开(公告)日：1980-09-23

    申请号：US908732

    申请日：1978-05-23

    申请人： Sumio Umemura ,  Kanenobu Matsui ,  Kunitoshi Koga ,  Mineo Kuniyoshi

    发明人： Sumio Umemura ,  Kanenobu Matsui ,  Kunitoshi Koga ,  Mineo Kuniyoshi

    IPC分类号： C07C69/035 ,  B01J23/00 ,  C07B61/00 ,  C07C69/025 ,  C07C69/12 ,  C07C69/157 ,  C07C67/05

    CPC分类号： C07C67/035

    摘要： Disclosed is a vapor phase catalytic oxidation process for preparing an aliphatic carboxylic acid ester of a monoaromatic compound having 1 to 2 hydroxymethyl substituents, such as benzyl acetate, p-methylbenzyl acetate, p-xylylenediacetate, benzyl propionate and benzyl butyrate. A gaseous feed comprised of a benzene compound having 1 to 2 methyl substituents, an aliphatic monocarboxylic acid having 2 to 4 carbon atoms and molecular oxygen is contacted with an improved catalyst. The metal ingredients of the catalyst consist essentially of (a) palladium, (b) arsenic and (c) at least one metal selected from alkali metals and alkali earth metals, and the atomic ratio of palladium:arsenic:the alkali or alkali earth metal is 1:0.05-4:0.1-10.

    摘要翻译： 公开了一种用于制备具有1至2个羟甲基取代基的单芳族化合物的脂肪族羧酸酯的气相催化氧化方法，例如乙酸苄酯，乙酸对甲基苄酯，对二甲苯基二乙酸酯，丙酸苄酯和丁酸苄酯。 由具有1至2个甲基取代基的苯化合物，具有2至4个碳原子的脂族单羧酸和分子氧组成的气态进料与改进的催化剂接触。 催化剂的金属成分基本上由（a）钯，（b）砷和（c）至少一种选自碱金属和碱土金属的金属，钯：砷的原子比：碱金属或碱土金属 为1：0.05-4：0.1-10。

    Process for preparing a carboxylic ester
    9.
    发明授权
    Process for preparing a carboxylic ester 失效
    羧酸酯的制备方法

    公开(公告)号：US4033999A

    公开(公告)日：1977-07-05

    申请号：US683529

    申请日：1976-05-05

    申请人： Takeru Onoda ,  Keisuke Wada

    发明人： Takeru Onoda ,  Keisuke Wada

    IPC分类号： B01J21/08 ,  B01J23/644 ,  B01J31/04 ,  B01J31/30 ,  C07C67/035 ,  C07C67/05

    CPC分类号： B01J31/30 ,  B01J23/6445 ,  B01J31/04 ,  B01J31/1616 ,  B01J31/26 ,  C07C67/035 ,  B01J21/08

    摘要： A carboxylic ester of a substituted benzene compound having one or two hydroxymethyl groups on the benzene ring is prepared by reacting a benzene compound selected from the group consisting of toluene and xylene, an aliphatic carboxylic acid, and molecular oxygen in the gaseous phase, in the presence of a catalyst, wherein the improvement comprises reacting said reactants over a supported catalyst wherein the active constituents comprise (1) palladium, (2) an antimony component substantially as the oxide thereof and (3) at least one carboxylic acid salt of an alkali metal, alkaline earth metal, zinc, cadmium or lead, on a carrier.

    摘要翻译： 在苯环上具有一个或两个羟甲基的取代苯化合物的羧酸酯是通过使选自甲苯和二甲苯的苯化合物，脂肪族羧酸和分子氧在气相中反应来制备的 催化剂的存在，其中改进包括使所述反应物在负载催化剂上反应，其中活性成分包括（1）钯，（2）基本上作为其氧化物的锑组分和（3）至少一种碱的羧酸盐 金属，碱土金属，锌，镉或铅。

    Process for preparing carboxylic acid esters from toluene and xylene
    10.
    发明授权
    Process for preparing carboxylic acid esters from toluene and xylene 失效
    从甲苯和二甲苯制备羧酸酯的方法

    公开(公告)号：US4016200A

    公开(公告)日：1977-04-05

    申请号：US658766

    申请日：1976-02-17

    申请人： Takeru Onoda ,  Keisuke Wada ,  Masayuki Otake

    发明人： Takeru Onoda ,  Keisuke Wada ,  Masayuki Otake

    IPC分类号： B01J31/04 ,  C07C67/055 ,  C07C67/05

    CPC分类号： B01J31/1616 ,  B01J31/04 ,  B01J31/223 ,  B01J31/26 ,  B01J31/30 ,  C07C67/035 ,  C07C67/055 ,  B01J2531/52

    摘要： A carboxylic ester is prepared by reacting a hydrocarbon selected from monoolefins having 2 to 6 carbon atoms, benzene, toluene and xylene with an aliphatic saturated carboxylic acid having 2 to 4 carbon atoms and molecular oxygen in the vapor phase in the presence of a supported solid catalyst of palladium metal, an antimony component and a carboxylic acid salt of alkali metal, alkaline earth metal, zinc, cadmium, lead or tin, with the improvement comprising: adding said antimony compound to the support of said catalyst by dipping a carrier into an aqueous solution of water-soluble antimony compound selected from the group consisting of antimonic acid, antimonates and antimony complexes of organic acids.

    摘要翻译： 羧酸酯是通过使选自具有2至6个碳原子的单烯烃，苯，甲苯和二甲苯的烃与具有2至4个碳原子的脂族饱和羧酸和分子氧在气相中在负载的固体存在下反应来制备的 钯金属的催化剂，锑成分和碱金属，碱土金属，锌，镉，铅或锡的羧酸盐，其改进包括：通过将载体浸渍到所述催化剂的载体中而将所述锑化合物加入到所述催化剂的载体中 水溶性锑化合物的水溶液，其选自锑酸盐，锑酸盐和有机酸的锑络合物。