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    Highly crystalline polypropylene waxes
    1.
    发明申请
    Highly crystalline polypropylene waxes 审中-公开
    高度结晶的聚丙烯蜡

    公开(公告)号：US20090036619A1

    公开(公告)日：2009-02-05

    申请号：US12221234

    申请日：2008-07-31

    申请人： Hans-Friedrich Herrmann ,  Gerald Mehltretter ,  Hans Rausch ,  Gerd Hohner

    发明人： Hans-Friedrich Herrmann ,  Gerald Mehltretter ,  Hans Rausch ,  Gerd Hohner

    IPC分类号： C08F4/642 ,  C08F110/06 ,  C08F4/16 ,  C08F4/52 ,  C08F4/18 ,  C08F4/64

    CPC分类号： C08F110/06 ,  C08F4/65912 ,  C08F10/06 ,  C08F4/65927 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/23

    摘要： Polypropylene wax having a) a dropping or softening point determined by the ring/ball method of greater than 155° C., b) heats of fusion greater than 80 J/g and c) a DSC melting point of >155° C. The waxes of the invention are prepared by reaction of propylene with metallocene compounds at temperatures in the range from 40 to 140° C. and an olefin partial pressure in the range from 1 to 50 bar in the presence of a cocatalyst. They have a content of unsaturated chain ends of less than 10%. They can, for example, be modified by means of a free-radical grafting reaction with polar monomers and are, for example, suitable in unmodified form as dispersants for pigments, as additive in printing inks and surface coatings or toners or in modified form for producing aqueous dispersions or as bonding agents and compatibilizers in plastic compounds.

    摘要翻译： 聚丙烯蜡，其具有a）通过环/球法测定的滴定或软化点大于155℃，b）大于80J / g的熔融热，c）DSC熔点> 155℃。 在助催化剂存在下，通过丙烯与金属茂化合物在40〜140℃的温度和1〜50巴的烯烃分压反应制备本发明的蜡。 它们的不饱和链端含量小于10％。 它们可以例如通过与极性单体的自由基接枝反应进行改性，并且例如适合于未改性形式作为颜料的分散剂，作为印刷油墨和表面涂料或调色剂中的添加剂或以改性形式用于 生产水分散体或作为粘合剂和增塑剂在塑料化合物中。

    Use of polyolefin waxes in hot melt compositions
    3.
    发明申请
    Use of polyolefin waxes in hot melt compositions 审中-公开
    在热熔组合物中使用聚烯烃蜡

    公开(公告)号：US20060074171A1

    公开(公告)日：2006-04-06

    申请号：US11244475

    申请日：2005-10-06

    申请人： Sebastijan Bach ,  Hans-Friedrich Herrmann ,  Gerd Hohner

    发明人： Sebastijan Bach ,  Hans-Friedrich Herrmann ,  Gerd Hohner

    IPC分类号： C08L91/08

    CPC分类号： C09J123/12 ,  C08L23/10 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/06 ,  C09J123/14

    摘要： The invention relates to hot melt compositions comprising polyolefin waxes prepared using metallocene catalysts, have a dropping point or ring & ball softening point of between 80 and 165° C., have a melt viscosity, measured at a temperature of 170° C., of between 20 and 40 000 mPa·s, and have a glass transition temperature of not more than −10° C. and also to their use as hot melt adhesives and as binders for producing roadmarkings.

    摘要翻译： 本发明涉及包含使用金属茂催化剂制备的聚烯烃蜡的熔融组合物，其滴点或环球软化点在80至165℃之间，在170℃的温度下测得的熔体粘度为 介于20和40 000 mPa.s之间，玻璃化转变温度不超过-10°C，也可用作热熔胶和用于生产路标的粘合剂。

    Polypropylene wax
    4.
    发明授权
    Polypropylene wax 失效
    聚丙烯蜡

    公开(公告)号：US6143846A

    公开(公告)日：2000-11-07

    申请号：US112855

    申请日：1998-07-10

    申请人： Hans-Friedrich Herrmann ,  Gerd Hohner

    发明人： Hans-Friedrich Herrmann ,  Gerd Hohner

    IPC分类号： G03G9/08 ,  C08F2/38 ,  C08F4/659 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C09D123/10 ,  C09J123/10

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  Y10S430/166 ,  Y10S526/905

    摘要： The present invention relates to homopolymer and copolymer waxes which have been prepared by polymerization using metallocene compounds in the presence of hydrogen and have a melt viscosity of less than 100 mPas, measured at 170.degree. C.As a result of their high thermal stability, these waxes display neither discoloration nor crosslinking reactions and are very well suited for use in toners, for plastics processing, for masterbatches, for printing inks, surface coatings and melt adhesives.

    摘要翻译： 本发明涉及通过在氢存在下使用茂金属化合物进行聚合制备的均聚物和共聚物蜡，并且在170℃下测得的熔体粘度小于100mPas。由于它们的高热稳定性，这些 蜡既不显示变色也不显示交联反应，并且非常适合用于调色剂，塑料加工，母料，印刷油墨，表面涂料和熔融粘合剂。

    Process for producing low molecular-weight poly-1-olefins
    7.
    发明授权
    Process for producing low molecular-weight poly-1-olefins 失效
    低分子量聚-1-烯烃的制备方法

    公开(公告)号：US5917100A

    公开(公告)日：1999-06-29

    申请号：US864211

    申请日：1997-05-28

    申请人： Ludwig Bohm ,  Hans-Friedrich Herrmann ,  Joachim Berthold ,  Gerd Hohner ,  Rainer Lecht ,  Hans Joachim Vetter

    发明人： Ludwig Bohm ,  Hans-Friedrich Herrmann ,  Joachim Berthold ,  Gerd Hohner ,  Rainer Lecht ,  Hans Joachim Vetter

    IPC分类号： C08F4/654 ,  C08F4/60 ,  C08F4/626 ,  C08F4/634 ,  C08F4/635 ,  C08F10/00 ,  C08F110/00 ,  C10L1/16 ,  C07C2/24

    CPC分类号： C08F10/00 ,  Y10S526/905

    摘要： A catalyst formed by the reaction of a magnesium alkoxide dispersion having a particle size of from 100 to 3000 nm with a compound of a metal selected from the group comprising titanium, zirconium, vanadium and chromium and then with a chlorine-containing organoaluminum compound possesses a very good hydrogen responsiveness and a high activity even in the presence of molecular-weight regulators such as hydrogen. The catalyst is therefore outstandingly suitable for the production of low molecular-weight polyolefins. The catalyst makes possible the production of waxes having a reduced residual ash content. The large particle diameter and the low fines content of the polymer powder produced by suspension polymerization with this catalyst enables easy removal of the suspension medium and drying. The catalyst is furthermore advantageously used in solution polymerization and, because of the large particle diameter, in gas phase polymerization for producing low molecular-weight poly-1-olefins.

    摘要翻译： 由粒径为100〜3000nm的烷氧基镁分散体与选自钛，锆，钒，铬的金属化合物反应形成的催化剂，然后与含氯有机铝化合物反应形成的催化剂具有 甚至在分子量调节剂如氢气的存在下也具有非常好的氢响应性和高活性。 因此，催化剂非常适合于生产低分子量聚烯烃。 该催化剂使得生产具有减少的残余灰分含量的蜡成为可能。 通过与该催化剂的悬浮聚合制备的聚合物粉末的大粒径和低细粉含量可以容易地除去悬浮介质并干燥。 此外，催化剂有利地用于溶液聚合，并且由于粒径大，用于制备低分子量聚-1-烯烃的气相聚合。

    Process for the preparation of polyolefin waxes
    9.
    发明授权
    Process for the preparation of polyolefin waxes 失效
    制备聚烯烃蜡的方法

    公开(公告)号：US5750813A

    公开(公告)日：1998-05-12

    申请号：US353144

    申请日：1994-12-09

    申请人： Reiner Hess ,  Hartmut Voigt ,  Hans-Friedrich Herrmann ,  Ludwig Bohm ,  Walter Spaleck ,  Gerd Hohner

    发明人： Reiner Hess ,  Hartmut Voigt ,  Hans-Friedrich Herrmann ,  Ludwig Bohm ,  Walter Spaleck ,  Gerd Hohner

    IPC分类号： B01J19/00 ,  B01J19/18 ,  C08F4/62 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C10L1/16

    CPC分类号： C08F10/00 ,  B01J19/0013 ,  B01J19/1881 ,  B01J2219/00128 ,  C08F110/06 ,  C08F4/65912 ,  Y10S585/946

    摘要： A process for the preparation of a polyolefin wax by polymerization or copolymerization of olefins or diolefins in suspension and in the presence of a catalyst. The process utilizes a metallocene and a cocatalyst, wherein the metallocene is a compound of the formula I ##STR1## in which M.sup.1 is a metal of group IVb, Vb or VIb of the Periodic Table of Elements, R.sup.1 and R.sup.2 are identical or different and are a hydrogen atom, a C.sub.1 -C.sub.10 -alkyl group, a C.sub.1 -C.sub.10 -alkoxy group, a C.sub.6 -C.sub.10 -aryl group, a C.sub.6 -C.sub.10 -aryloxy group, a C.sub.2 -C.sub.10 -alkenyl group, a C.sub.7 -C.sub.40 -arylalkyl group, a C.sub.7 -C.sub.40 -alkylaryl group, a C.sub.8 -C.sub.40 -arylalkenyl group or a halogen atom and R.sup.3 and R.sup.4 are identical or different and are a mononuclear or polynuclear hydrocarbon radical which may form a sandwich structure with the central atom M.sup.1, low-boiling hydrocarbons having 3 or 4 carbon atoms or low-boiling halogenated hydrocarbons are used as suspending agents and the heat of reaction is removed by evaporative cooling.

    摘要翻译： 一种通过在悬浮液中和在催化剂存在下聚合或共聚烯烃或二烯烃来制备聚烯烃蜡的方法。 该方法使用金属茂和助催化剂，其中茂金属是式I的化合物（Ⅰ），其中M1是元素周期表IVb族，Vb或VIb族的金属，R1和R2是相同的 或不同，为氢原子，C1-C10-烷基，C1-C10-烷氧基，C6-C10-芳基，C6-C10-芳氧基，C2-C10-烯基，C7 -C 40 - 芳基烷基，C 7 -C 40 - 烷基芳基，C 8 -C 40 - 芳基烯基或卤素原子，R 3和R 4相同或不同，并且是单核或多核烃基，其可形成具有中心 使用原子M1，具有3或4个碳原子的低沸点烃或低沸点卤代烃作为悬浮剂，通过蒸发冷却除去反应热。