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    Process for producing low molecular-weight poly-1-olefins
    1.
    发明授权
    Process for producing low molecular-weight poly-1-olefins 失效
    低分子量聚-1-烯烃的制备方法

    公开(公告)号：US5917100A

    公开(公告)日：1999-06-29

    申请号：US864211

    申请日：1997-05-28

    申请人： Ludwig Bohm ,  Hans-Friedrich Herrmann ,  Joachim Berthold ,  Gerd Hohner ,  Rainer Lecht ,  Hans Joachim Vetter

    发明人： Ludwig Bohm ,  Hans-Friedrich Herrmann ,  Joachim Berthold ,  Gerd Hohner ,  Rainer Lecht ,  Hans Joachim Vetter

    IPC分类号： C08F4/654 ,  C08F4/60 ,  C08F4/626 ,  C08F4/634 ,  C08F4/635 ,  C08F10/00 ,  C08F110/00 ,  C10L1/16 ,  C07C2/24

    CPC分类号： C08F10/00 ,  Y10S526/905

    摘要： A catalyst formed by the reaction of a magnesium alkoxide dispersion having a particle size of from 100 to 3000 nm with a compound of a metal selected from the group comprising titanium, zirconium, vanadium and chromium and then with a chlorine-containing organoaluminum compound possesses a very good hydrogen responsiveness and a high activity even in the presence of molecular-weight regulators such as hydrogen. The catalyst is therefore outstandingly suitable for the production of low molecular-weight polyolefins. The catalyst makes possible the production of waxes having a reduced residual ash content. The large particle diameter and the low fines content of the polymer powder produced by suspension polymerization with this catalyst enables easy removal of the suspension medium and drying. The catalyst is furthermore advantageously used in solution polymerization and, because of the large particle diameter, in gas phase polymerization for producing low molecular-weight poly-1-olefins.

    摘要翻译： 由粒径为100〜3000nm的烷氧基镁分散体与选自钛，锆，钒，铬的金属化合物反应形成的催化剂，然后与含氯有机铝化合物反应形成的催化剂具有 甚至在分子量调节剂如氢气的存在下也具有非常好的氢响应性和高活性。 因此，催化剂非常适合于生产低分子量聚烯烃。 该催化剂使得生产具有减少的残余灰分含量的蜡成为可能。 通过与该催化剂的悬浮聚合制备的聚合物粉末的大粒径和低细粉含量可以容易地除去悬浮介质并干燥。 此外，催化剂有利地用于溶液聚合，并且由于粒径大，用于制备低分子量聚-1-烯烃的气相聚合。

    Process for the preparation of polyolefin waxes
    2.
    发明授权
    Process for the preparation of polyolefin waxes 失效
    制备聚烯烃蜡的方法

    公开(公告)号：US5750813A

    公开(公告)日：1998-05-12

    申请号：US353144

    申请日：1994-12-09

    申请人： Reiner Hess ,  Hartmut Voigt ,  Hans-Friedrich Herrmann ,  Ludwig Bohm ,  Walter Spaleck ,  Gerd Hohner

    发明人： Reiner Hess ,  Hartmut Voigt ,  Hans-Friedrich Herrmann ,  Ludwig Bohm ,  Walter Spaleck ,  Gerd Hohner

    IPC分类号： B01J19/00 ,  B01J19/18 ,  C08F4/62 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C10L1/16

    CPC分类号： C08F10/00 ,  B01J19/0013 ,  B01J19/1881 ,  B01J2219/00128 ,  C08F110/06 ,  C08F4/65912 ,  Y10S585/946

    摘要： A process for the preparation of a polyolefin wax by polymerization or copolymerization of olefins or diolefins in suspension and in the presence of a catalyst. The process utilizes a metallocene and a cocatalyst, wherein the metallocene is a compound of the formula I ##STR1## in which M.sup.1 is a metal of group IVb, Vb or VIb of the Periodic Table of Elements, R.sup.1 and R.sup.2 are identical or different and are a hydrogen atom, a C.sub.1 -C.sub.10 -alkyl group, a C.sub.1 -C.sub.10 -alkoxy group, a C.sub.6 -C.sub.10 -aryl group, a C.sub.6 -C.sub.10 -aryloxy group, a C.sub.2 -C.sub.10 -alkenyl group, a C.sub.7 -C.sub.40 -arylalkyl group, a C.sub.7 -C.sub.40 -alkylaryl group, a C.sub.8 -C.sub.40 -arylalkenyl group or a halogen atom and R.sup.3 and R.sup.4 are identical or different and are a mononuclear or polynuclear hydrocarbon radical which may form a sandwich structure with the central atom M.sup.1, low-boiling hydrocarbons having 3 or 4 carbon atoms or low-boiling halogenated hydrocarbons are used as suspending agents and the heat of reaction is removed by evaporative cooling.

    摘要翻译： 一种通过在悬浮液中和在催化剂存在下聚合或共聚烯烃或二烯烃来制备聚烯烃蜡的方法。 该方法使用金属茂和助催化剂，其中茂金属是式I的化合物（Ⅰ），其中M1是元素周期表IVb族，Vb或VIb族的金属，R1和R2是相同的 或不同，为氢原子，C1-C10-烷基，C1-C10-烷氧基，C6-C10-芳基，C6-C10-芳氧基，C2-C10-烯基，C7 -C 40 - 芳基烷基，C 7 -C 40 - 烷基芳基，C 8 -C 40 - 芳基烯基或卤素原子，R 3和R 4相同或不同，并且是单核或多核烃基，其可形成具有中心 使用原子M1，具有3或4个碳原子的低沸点烃或低沸点卤代烃作为悬浮剂，通过蒸发冷却除去反应热。

    Process for preparing a poly-1-olefin
    5.
    发明授权
    Process for preparing a poly-1-olefin 失效
    制备聚-1-烯烃的方法

    公开(公告)号：US5798309A

    公开(公告)日：1998-08-25

    申请号：US576858

    申请日：1995-12-22

    申请人： Werner Breuers ,  Rainer Lecht ,  Ludwig Bohm

    发明人： Werner Breuers ,  Rainer Lecht ,  Ludwig Bohm

    IPC分类号： C08F4/658 ,  B01J8/00 ,  B01J8/24 ,  B01J8/26 ,  C08F2/34 ,  C08F4/02 ,  C08F4/60 ,  C08F4/645 ,  C08F4/646 ,  C08F4/654 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00 ,  B01J8/003 ,  B01J8/24 ,  B01J8/26 ,  B01J2208/00761 ,  Y10S526/901 ,  Y10S526/904

    摘要： Process for preparing a poly-1-olefin By means of a highly active spherical Ziegler catalyst based on a dialkylmagnesium, spherical polymers can be obtained in the polymerization of alpha-olefins. A further advantage of the catalyst of the invention lies in the high catalyst activity, so that only very small amounts of the catalyst are required for the polymerization. The residual titanium and/or zirconium content in the polymers prepared according to the invention is less than 10 ppm. Owing to its good responsiveness to hydrogen, the catalyst is particularly suited to two-stage processes for preparing polymers having a broad bimodal molecular weight distribution. The replacement of sulfur-containing electron donors such as diethyl sulfite by alcohols such as ethanol leads to less odor problems and broadened opportunities for use of the polymer. Owing to the spherical shape of the particles and the associated very good flow behavior of the polymers and copolymers, considerable simplification and advantages in handling, drying and processing are achieved.

    摘要翻译： 制备聚-1-烯烃的方法通过基于二烷基镁的高活性球形齐格勒催化剂，可以在α-烯烃的聚合中获得球形聚合物。 本发明的催化剂的另一个优点在于高催化剂活性，因此仅需要极少量的催化剂进行聚合。 根据本发明制备的聚合物中残留的钛和/或锆含量小于10ppm。 由于其对氢的响应性良好，催化剂特别适用于制备具有宽双峰分子量分布的聚合物的两阶段方法。 通过醇如乙醇代替含硫电子给体如亚硫酸二乙酯，导致较少的气味问题和使用聚合物的机会扩大。 由于颗粒的球形形状和聚合物和共聚物的相关非常好的流动行为，实现了在处理，干燥和加工中的相当大的简化和优点。

    Polyethylene composition for producing l-ring drums
    7.
    发明申请
    Polyethylene composition for producing l-ring drums 审中-公开
    聚乙烯组合物，用于生产l环鼓

    公开(公告)号：US20060052542A1

    公开(公告)日：2006-03-09

    申请号：US10538894

    申请日：2003-12-10

    申请人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    发明人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    IPC分类号： C08L23/04

    CPC分类号： C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2207/068 ,  C08L2666/02 ,  C08L2666/06

    摘要： The invention relates to a polyethylene composition with multimodal molecular mass distribution, which is particularly suitable for the blow molding of L-ring drums having a volume in the range of from 50 to 250 dm3 (I). The composition has a density in the range of from 0.950 to 0.956 g/cm3 at 23° C. and a MFR1gp/21.6 in the range from 1.5 to 3.5 dg/min. It comprises from 35 to 45% by weight of a low-molecular-mass ethylene homopolymer A, from 34 to 44% by weight of a high-molecular-mass copolymer B made from ethylene and from another 1-olefin having from 4 to 8 carbon atoms, and from 18 to 26 % by weight of an ultrahigh-molecular-mass ethylene copolymer C.

    摘要翻译： 本发明涉及具有多峰分子量分布的聚乙烯组合物，其特别适用于体积在50-250dm 3（I）范围内的L型环鼓的吹塑。 组合物在23℃下的密度范围为0.950-0.956g / cm 3，MFR1 / 1cp / 21.6℃范围为1.5-3.5dg /分钟 它包含35至45重量％的低分子量乙烯均聚物A，34至44重量％的由乙烯制成的高分子量共聚物B和具有4至8个的另外的1-烯烃 碳原子和18至26重量％的超高分子量乙烯共聚物C.

    Method for producing a poly-1olefin in the presence of a ziegler catalyst
    8.
    发明申请
    Method for producing a poly-1olefin in the presence of a ziegler catalyst 有权
    在齐格勒催化剂存在下制备聚-1-烯烃的方法

    公开(公告)号：US20050239978A1

    公开(公告)日：2005-10-27

    申请号：US10514095

    申请日：2003-05-22

    申请人： Ludwig Bohm ,  Joachim Berthold

    发明人： Ludwig Bohm ,  Joachim Berthold

    IPC分类号： C08F10/00 ,  C08F4/44 ,  C08F4/60 ,  C08F4/658 ,  C08F10/02 ,  C08F110/02

    CPC分类号： C08F110/02 ,  C08F10/02 ,  C08F4/6555 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    摘要： The invention relates to a method for producing a poly-1-olefin by polymerization of a 1-olefin of the formula R4C═CH2, in which R4 is hydrogen or an alkyl radical having from 1 to 10 carbon atoms, in suspension, in solution or in the gas phase, at a temperature of from 20 to 200° C. and a pressure of from 0.5 to 50 bar, in the presence of a catalyst which consists of the product of the reaction of a magnesium alkoxide with a transition-metal compound (component a) and an organometallic compound (component b), whose component (a) has been produced by reacting a transitionmetal compound of titanium, zirconium, vanadium or chromium with a gelatinous dispersion of the magnesium alkoxide in an inert hydrocarbon. In accordance with the invention, the gelatinous dispersion is obtained by stirring, using a stirring element, or shearing, using a high-performance shearing tool, a suspension of a magnesium alkoxide powder having a mean particle size, expressed as the d50 value, in the range from 50 to 1000 um, in an aliphatic hydrocarbon in which the magnesium alkoxide particles are insoluble. The suspension has, before conversion into the dispersion, been subjected to heat treatment at a temperature in the range from 40 to 150° C. over a period of from 10 to 100 hours.

    摘要翻译： 本发明涉及通过聚合式R 4 C-CH 2 2-的1-烯烃制备聚-1-烯烃的方法，其中R 0 > 4是氢或具有1至10个碳原子的烷基，悬浮液，溶液或气相中，温度为20-200℃，压力为0.5至50 在由醇盐与过渡金属化合物（组分a）的反应产物和有机金属化合物（组分b）组成的催化剂的存在下，其组分（a）通过使 钛，锆，钒或铬的过渡金属化合物与烷氧基镁在惰性烃中的凝胶状分散体。 根据本发明，通过使用搅拌元件搅拌或使用高性能剪切工具剪切平均粒度的烷氧基镁粉末的悬浮液（表示为d＆lt; 在50〜1000μm的范围内，在烷氧基镁颗粒不溶的脂族烃中。 悬浮液在转化成分散体之前，在10〜100小时的时间内，在40〜150℃的温度下进行热处理。

    Polyethylene blow molding composition for producing jerry cans
    9.
    发明申请
    Polyethylene blow molding composition for producing jerry cans 审中-公开
    聚乙烯吹塑组合物，用于生产杰瑞罐

    公开(公告)号：US20060074194A1

    公开(公告)日：2006-04-06

    申请号：US10538896

    申请日：2003-12-06

    申请人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    发明人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    IPC分类号： C08L23/04

    CPC分类号： C08L23/06 ,  C08F297/08 ,  C08F297/086 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2314/02 ,  C08L2666/06 ,  C08L2666/04 ,  C08L2666/02

    摘要： The invention relates to a polyethylene composition with multimodal molecular mass distribution, which is particularly suitable for the blow moulding of canisters having a volume in the range of from 2 to 20 dm3 (I). The composition has a density in the range from 0.950 to 0.958 g/cm3 at 23° C. and an MFR190/5 in the range of from 0.30 to 0.50 dg/min. It comprises from 40 to 50% by weight of a low-molecular-mass ethylene homopolymer A, from 25 to 35% by weight of a high-molecular-mass copolymer B made from ethylene and from another olefin having from 4 to 8 carbon atoms, and from 24 to 28% by weight of an ultrahigh-molecular-mass ethylene copolymer C.

    摘要翻译： 本发明涉及具有多峰分子量分布的聚乙烯组合物，其特别适用于体积在2至20dm 3（I）范围内的罐的吹塑。 组合物在23℃下的密度为0.950至0.958g / cm 3，MFR为190至0.50dg的MFR为190/5 / /分钟 它包含40至50重量％的低分子量乙烯均聚物A，25至35重量％的由乙烯制成的高分子量共聚物B和具有4至8个碳原子的另一种烯烃 ，和24〜28重量％的超高分子量乙烯共聚物C.

    Polyethylene blow molding composition for producing large containers
    10.
    发明申请
    Polyethylene blow molding composition for producing large containers 审中-公开
    用于生产大容器的聚乙烯吹塑组合物

    公开(公告)号：US20060074193A1

    公开(公告)日：2006-04-06

    申请号：US10538895

    申请日：2003-12-10

    申请人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    发明人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    IPC分类号： C08L23/04

    CPC分类号： C08L23/06 ,  C08F297/08 ,  C08F297/086 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2666/06 ,  C08L2666/04 ,  C08L2666/02

    摘要： The invention relates to a polyethylene composition with multimodal molecular mass distribution, which is particularly suitable for the blow molding of large containers with a volume in the range of from 10 to 150 dm3 (I). The composition has a density in the range of from 0.949 to 0.955 g/cm3 at 23° C. and an MFI190/5 in the range of from 0.1 to 0.3 dg/min. It comprises from 38 to 45% by weight of a low-molecular-mass ethylene homopolymer A, from 30 to 40% by weight of a high-molecular-mass copolymer B made from ethylene and from another 1-olefin having from 4 to 8 carbon atoms, and from 18 to 26% by weight of an ultrahigh-molecular-mass ethylene copolymer C.

    摘要翻译： 本发明涉及具有多峰分子量分布的聚乙烯组合物，其特别适用于体积在10至150 dm 3（I）范围内的大容器的吹塑。 组合物在23℃下的密度为0.949〜0.955g / cm 3，MFI为190〜0.5 / 0.1，范围为0.1〜0.3 dg / min。 它包含38至45重量％的低分子量乙烯均聚物A，30至40重量％的由乙烯制成的高分子量共聚物B和具有4至8个的另外的1-烯烃 碳原子和18至26重量％的超高分子量乙烯共聚物C.