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1.发明授权Thermotropic aromatic polyesters having high rigidity and toughness, process for the production thereof and the use thereof for the production of moulded articles, filaments, fibres and films 失效具有高刚性和韧性的热致变性芳族聚酯，其生产方法及其用于生产模塑制品，长丝，纤维和薄膜的用途
公开(公告)号：US4603190A
公开(公告)日：1986-07-29
申请号：US627965
申请日：1984-07-03
IPC分类号： C08G63/60
CPC分类号： C08G63/605
摘要： Thermotropic wholly aromatic polyesters containing condensed residues of p-hydroxybenzoic acid, isophthalic and optionally terephthalic acid, hydroquinone and 3.4'- and/or 4.4'-dihydroxy diphenyl, -diphenyl ether and/or -diphenyl sulphide, have excellent mechanical properties and are nevertheless not difficult to process.
摘要翻译： 含有对羟基苯甲酸，间苯二甲酸和任选的对苯二甲酸，对苯二酚和3.4'-和/或4.4'-二羟基二苯基，二苯基醚和/或二苯基硫醚的缩合残基的热致全芳族聚酯具有优异的机械性能， 不难处理。
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2.发明授权Thermotropic aromatic polyesters having a high tenacity and an improved melt viscosity, and mouldings, filaments, fibres and films thereof 失效具有高强度和改善的熔融粘度的热致变性芳族聚酯，以及其成型品，长丝，纤维及其膜
公开(公告)号：US4564669A
公开(公告)日：1986-01-14
申请号：US627971
申请日：1984-07-03
申请人： Hans-Rudolf Dicke , Manfred Schmidt , Aziz El-Sayed , Ulrich Biskup , Ludwig Bottenbruch , Dieter Freitag
发明人： Hans-Rudolf Dicke , Manfred Schmidt , Aziz El-Sayed , Ulrich Biskup , Ludwig Bottenbruch , Dieter Freitag
IPC分类号： C08G63/00 , C08G63/60 , C08G63/66 , C08G63/68 , C08G63/688
CPC分类号： C08G63/605
摘要： Thermotropic fully aromatic polyesters which contain radicals of p-hydroxybenzoic acid, iso- and/or terephthalic acid and 2,7-dihydroxynaphthalene condensed therein, having outstanding mechanical properties and accordingly are very easy to process.
摘要翻译： 含有对羟基苯甲酸，异 - 和/或对苯二甲酸和2,7-二羟基萘的基团的热致全芳族聚酯具有突出的机械性能，因此非常容易加工。
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3.发明授权Thermotropic, aromatic polyesters having good mechanical strength, containing sulfonic acid groups or metal sulfonate groups a process for the production thereof 失效具有良好机械强度的含有磺酸基或金属磺酸盐基团的热致变性芳族聚酯，其制备方法
公开(公告)号：US4599395A
公开(公告)日：1986-07-08
申请号：US659160
申请日：1984-10-09
申请人： Hans-Rudolf Dicke , Manfred Schmidt , Mark Witman , Aziz El-Sayed
发明人： Hans-Rudolf Dicke , Manfred Schmidt , Mark Witman , Aziz El-Sayed
CPC分类号： C08G63/688 , C09K19/3809
摘要： Thermotropic fully-aromatic polyesters which contain sulphonic acid and/or metal sulphonate groups bound to the aromatic rings of the polyester, have improved mechanical properties.
摘要翻译： 含有与聚酯芳族环结合的磺酸和/或金属磺酸盐基团的热致全芳族聚酯具有改善的机械性能。
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公开(公告)号：US4536561A
公开(公告)日：1985-08-20
申请号：US627972
申请日：1984-07-03
申请人： Manfred Schmidt , Hans-Rudolf Dicke
发明人： Manfred Schmidt , Hans-Rudolf Dicke
IPC分类号： C08G63/00 , C08G63/60 , C08G63/64 , C08G63/682
CPC分类号： C08G63/6822 , C08G63/605
摘要： Thermotropic, wholly aromatic polyesters containing condensed residues of(a) p-hydroxy benzoic acid,(b) 3-chloro-4-hydroxy benzoic acid,(c) isophthalic acid,(d) hydroquinone and(e) 3,4'- and/or 4,4'-dihydroxy-diphenyl, -diphenyl ether and/or -diphenyl sulphidehave high rigidity and toughness and yet are easily processable.
摘要翻译： 含有（a）对羟基苯甲酸，（b）3-氯-4-羟基苯甲酸，（c）间苯二甲酸，（d）氢醌和（e）3,4'-二羟基苯甲酸的缩合残基的热致全芳香族聚酯， 和/或4,4'-二羟基 - 二苯基，二苯基醚和/或二苯基硫化物具有高刚性和韧性，并且易于加工。
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5.发明授权
公开(公告)号：US4481350A
公开(公告)日：1984-11-06
申请号：US595461
申请日：1984-03-30
CPC分类号： C08G64/083 , C08G79/04
摘要： The subject of the present invention is a process for the preparation of polyphosphonates containing carbonate structures in amounts of 0.3 to 4.5 mol %, relative to the sum of phosphonate and carbonate structural units, which is characterized in that diaryl phosphonates are reacted with diphenols in the presence of neutral transesterification catalysts, and the reaction is then completed by adding diaryl carbonate.
摘要翻译： 本发明的主题是相对于膦酸酯和碳酸酯结构单元的总和，制备含有碳酸酯结构的聚磷酸酯的量为0.3〜4.5摩尔％的方法，其特征在于使二芳基膦酸酯与二酚在 存在中性酯交换催化剂，然后通过加入碳酸二芳基来完成反应。
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6.发明授权Process for the preparation of thermoplastic aromatic polyphosphonatocarbonates with improved heat-ageing resistance, and their use 失效具有改善耐热老化性的热塑性芳族聚碳酸亚烃酯的制备方法及其用途
公开(公告)号：US4401802A
公开(公告)日：1983-08-30
申请号：US224077
申请日：1981-01-12
摘要： Thermoplastic polyphosphonatocarbonates prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a catalyst selected from the group consisting of (a) tetra-C.sub.1 -C.sub.18 -alkyl titanates, (b) di-C.sub.2 -C.sub.4 -alkyl-tin oxides, (c) di-C.sub.2 -C.sub.4 -alkyl-di-C.sub.1 -C.sub.4 -alkoxy-tin compounds, (d) tetra-C.sub.3 -C.sub.18 -alkyl zirconates, (e) tri-C.sub.2 -C.sub.18 -alkyl vanadylates and (f) mixtures of germanium dioxide or titanium dioxide and at least one of (a) to (e) in a weight ratio of 1:3 to 3:1 at a temperature of from 80.degree.-340.degree. C. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonates and phosphonic diaryl ester being from 0.91:1 to 0.99:1.
摘要翻译： 在选自以下的催化剂存在下，将至少一种芳族二羟基化合物与碳酸二芳酯和膦酸二芳基酯缩聚制备的热塑性聚膦酸碳酸酯：（a）四-C1-烷基钛酸酯，（b）二 - （c）二-C2-C4-烷基 - 二-C1-C4烷氧基锡化合物，（d）四-C 3 -C 18烷基锆酸盐，（e）三-C2-烷基 - C18烷基氧钒酸酯和（f）二氧化锗或二氧化钛与至少一种（a）至（e）的混合物，重量比为1:3至3:1，温度为80-340℃ 并且在惰性气体气氛中在600至0.1mm Hg的压力下，碳酸二芳酯与膦酸二芳基酯的摩尔比为5:95至95:5，芳族二羟基化合物与碳酸二芳基酯的摩尔比 和膦酸二芳基酯为0.91:1至0.99:1。
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7.发明授权
公开(公告)号：US4260704A
公开(公告)日：1981-04-07
申请号：US949417
申请日：1978-10-10
申请人： Manfred Schmidt , Theo Kemperman , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Theo Kemperman , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08L7/00 , C08G8/00 , C08G8/04 , C08G8/12 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L61/12 , C08L101/00 , C08G8/28 , C08L61/14
摘要： Resins having a softening point of from 50.degree. to 130.degree. C., an OH-number of from 250 to 400 and an iodine number of from 90 to 160, obtainable by reacting an alkyl phenol-formaldehyde novolak or an alkyl phenol mixture-formaldehyde novolak under acid-catalysed conditions with a polunuclear phenol or polynuclear phenol mixture and formaldehyde and/or an aliphatic aldehyde or aliphatic aldehyde mixture, the ratio by weight of the alkyl phenol or alkyl phenol mixture to the polynuclear phenol or polynyclear phenol mixture being from 2.2:1 to 1:10.
摘要翻译： 软化点为50〜130℃，OH值为250〜400，碘值为90〜160的树脂，可通过使烷基酚 - 甲醛酚醛清漆或烷基苯酚混合物 - 甲醛 酚醛清漆在酸催化条件下用聚核苯酚或多核酚混合物和甲醛和/或脂族醛或脂族醛混合物，烷基苯酚或烷基苯酚混合物与多核苯酚或多环苯酚混合物的重量比为2.2 1：1:10。
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公开(公告)号：US4073757A
公开(公告)日：1978-02-14
申请号：US749456
申请日：1976-12-10
申请人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08L7/00 , C08G8/00 , C08G8/20 , C08G8/28 , C08G79/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08C4/00 , C08G8/32
摘要： Boron-containing resins suitable for reinforcing rubber are obtained by reacting diphenylol alkane novolaks with boron compounds and unsaturated fatty acids or fatty acid esters.
摘要翻译： 适用于增强橡胶的含硼树脂通过二羟甲基烷烃酚醛清漆与硼化合物和不饱和脂肪酸或脂肪酸酯反应获得。
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公开(公告)号：US5269887A
公开(公告)日：1993-12-14
申请号：US833105
申请日：1992-02-10
申请人： Wolfgang Jakob , Manfred Schmidt , Dieter Freitag , Klaus D. Berg
发明人： Wolfgang Jakob , Manfred Schmidt , Dieter Freitag , Klaus D. Berg
CPC分类号： C07C37/74
摘要： A process for the purification of bisphenols by distillation.
摘要翻译： 通过蒸馏纯化双酚的方法。
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公开(公告)号：US4668720A
公开(公告)日：1987-05-26
申请号：US762946
申请日：1985-08-06
IPC分类号： C08L25/00 , C08K5/00 , C08K5/49 , C08K5/51 , C08K5/5399 , C08L7/00 , C08L21/00 , C08L25/04 , C08L25/06 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L85/00 , C08K5/34
CPC分类号： C08K5/0066 , C08K5/5399 , C08L25/04 , C08L2201/02 , C08L85/00
摘要： This invention relates to flame resistant moulding compounds produced from mixtures of styrene polymers halogenated organic compounds, special polyphosphonic acid amides and optionally conventional additives.
摘要翻译： 本发明涉及由苯乙烯聚合物卤化有机化合物，特殊聚膦酸酰胺和任选的常规添加剂的混合物制备的阻燃模塑料。
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