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1.发明授权Thermotropic aromatic polyesters having a high tenacity and an improved melt viscosity, and mouldings, filaments, fibres and films thereof 失效具有高强度和改善的熔融粘度的热致变性芳族聚酯，以及其成型品，长丝，纤维及其膜
公开(公告)号：US4564669A
公开(公告)日：1986-01-14
申请号：US627971
申请日：1984-07-03
申请人： Hans-Rudolf Dicke , Manfred Schmidt , Aziz El-Sayed , Ulrich Biskup , Ludwig Bottenbruch , Dieter Freitag
发明人： Hans-Rudolf Dicke , Manfred Schmidt , Aziz El-Sayed , Ulrich Biskup , Ludwig Bottenbruch , Dieter Freitag
IPC分类号： C08G63/00 , C08G63/60 , C08G63/66 , C08G63/68 , C08G63/688
CPC分类号： C08G63/605
摘要： Thermotropic fully aromatic polyesters which contain radicals of p-hydroxybenzoic acid, iso- and/or terephthalic acid and 2,7-dihydroxynaphthalene condensed therein, having outstanding mechanical properties and accordingly are very easy to process.
摘要翻译： 含有对羟基苯甲酸，异 - 和/或对苯二甲酸和2,7-二羟基萘的基团的热致全芳族聚酯具有突出的机械性能，因此非常容易加工。
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2.发明授权Thermotropic aromatic polyesters having high rigidity and toughness, process for the production thereof and the use thereof for the production of moulded articles, filaments, fibres and films 失效具有高刚性和韧性的热致变性芳族聚酯，其生产方法及其用于生产模塑制品，长丝，纤维和薄膜的用途
公开(公告)号：US4603190A
公开(公告)日：1986-07-29
申请号：US627965
申请日：1984-07-03
IPC分类号： C08G63/60
CPC分类号： C08G63/605
摘要： Thermotropic wholly aromatic polyesters containing condensed residues of p-hydroxybenzoic acid, isophthalic and optionally terephthalic acid, hydroquinone and 3.4'- and/or 4.4'-dihydroxy diphenyl, -diphenyl ether and/or -diphenyl sulphide, have excellent mechanical properties and are nevertheless not difficult to process.
摘要翻译： 含有对羟基苯甲酸，间苯二甲酸和任选的对苯二甲酸，对苯二酚和3.4'-和/或4.4'-二羟基二苯基，二苯基醚和/或二苯基硫醚的缩合残基的热致全芳族聚酯具有优异的机械性能， 不难处理。
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3.发明授权Thermotropic, aromatic polyesters having good mechanical strength, containing sulfonic acid groups or metal sulfonate groups a process for the production thereof 失效具有良好机械强度的含有磺酸基或金属磺酸盐基团的热致变性芳族聚酯，其制备方法
公开(公告)号：US4599395A
公开(公告)日：1986-07-08
申请号：US659160
申请日：1984-10-09
申请人： Hans-Rudolf Dicke , Manfred Schmidt , Mark Witman , Aziz El-Sayed
发明人： Hans-Rudolf Dicke , Manfred Schmidt , Mark Witman , Aziz El-Sayed
CPC分类号： C08G63/688 , C09K19/3809
摘要： Thermotropic fully-aromatic polyesters which contain sulphonic acid and/or metal sulphonate groups bound to the aromatic rings of the polyester, have improved mechanical properties.
摘要翻译： 含有与聚酯芳族环结合的磺酸和/或金属磺酸盐基团的热致全芳族聚酯具有改善的机械性能。
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4.发明授权
公开(公告)号：US4481350A
公开(公告)日：1984-11-06
申请号：US595461
申请日：1984-03-30
CPC分类号： C08G64/083 , C08G79/04
摘要： The subject of the present invention is a process for the preparation of polyphosphonates containing carbonate structures in amounts of 0.3 to 4.5 mol %, relative to the sum of phosphonate and carbonate structural units, which is characterized in that diaryl phosphonates are reacted with diphenols in the presence of neutral transesterification catalysts, and the reaction is then completed by adding diaryl carbonate.
摘要翻译： 本发明的主题是相对于膦酸酯和碳酸酯结构单元的总和，制备含有碳酸酯结构的聚磷酸酯的量为0.3〜4.5摩尔％的方法，其特征在于使二芳基膦酸酯与二酚在 存在中性酯交换催化剂，然后通过加入碳酸二芳基来完成反应。
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5.发明授权Process for the preparation of thermoplastic aromatic polyphosphonatocarbonates with improved heat-ageing resistance, and their use 失效具有改善耐热老化性的热塑性芳族聚碳酸亚烃酯的制备方法及其用途
公开(公告)号：US4401802A
公开(公告)日：1983-08-30
申请号：US224077
申请日：1981-01-12
摘要： Thermoplastic polyphosphonatocarbonates prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a catalyst selected from the group consisting of (a) tetra-C.sub.1 -C.sub.18 -alkyl titanates, (b) di-C.sub.2 -C.sub.4 -alkyl-tin oxides, (c) di-C.sub.2 -C.sub.4 -alkyl-di-C.sub.1 -C.sub.4 -alkoxy-tin compounds, (d) tetra-C.sub.3 -C.sub.18 -alkyl zirconates, (e) tri-C.sub.2 -C.sub.18 -alkyl vanadylates and (f) mixtures of germanium dioxide or titanium dioxide and at least one of (a) to (e) in a weight ratio of 1:3 to 3:1 at a temperature of from 80.degree.-340.degree. C. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonates and phosphonic diaryl ester being from 0.91:1 to 0.99:1.
摘要翻译： 在选自以下的催化剂存在下，将至少一种芳族二羟基化合物与碳酸二芳酯和膦酸二芳基酯缩聚制备的热塑性聚膦酸碳酸酯：（a）四-C1-烷基钛酸酯，（b）二 - （c）二-C2-C4-烷基 - 二-C1-C4烷氧基锡化合物，（d）四-C 3 -C 18烷基锆酸盐，（e）三-C2-烷基 - C18烷基氧钒酸酯和（f）二氧化锗或二氧化钛与至少一种（a）至（e）的混合物，重量比为1:3至3:1，温度为80-340℃ 并且在惰性气体气氛中在600至0.1mm Hg的压力下，碳酸二芳酯与膦酸二芳基酯的摩尔比为5:95至95:5，芳族二羟基化合物与碳酸二芳基酯的摩尔比 和膦酸二芳基酯为0.91:1至0.99:1。
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6.发明授权Aromatic polyester carbonates having a high notched impact strength and a process for the production thereof 失效具有高缺口冲击强度的芳族聚酯碳酸酯及其制备方法
公开(公告)号：US4533702A
公开(公告)日：1985-08-06
申请号：US623823
申请日：1984-06-22
CPC分类号： C08G63/64
摘要： Aromatic polyester carbonates may be produced by melt-extruding solutions of aromatic polyesters and aromatic polycarbonates.
摘要翻译： 芳族聚酯碳酸酯可以通过熔融挤出芳族聚酯和芳族聚碳酸酯的溶液来制备。
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公开(公告)号：US4382898A
公开(公告)日：1983-05-10
申请号：US312224
申请日：1981-10-19
CPC分类号： C07C51/60
摘要： A single-stage process for the production of pure, particularly sulphur-free, aromatic carboxylic acid chlorides by reacting an aromatic carboxylic acid containing from 1 to 3 carboxyl groups or a corresponding mixture of aromatic carboxylic acids with thionyl chloride in the presence of a catalyst, wherein tertiary phosphine oxides or their reaction products with thionyl chloride and/or the acid chloride to be formed are used as catalysts, and the use of the aromatic dicarboxylic acid dichlorides and tricarboxylic acid trichlorides obtained for the production of polycondensates.
摘要翻译： 通过在催化剂存在下使含有1至3个羧基的芳族羧酸或芳族羧酸的相应混合物与亚硫酰氯反应生产纯的，特别是无硫的芳族羧酸氯化物的单阶段方法 其中使用叔膦氧化物或其与亚硫酰氯和/或酰氯的反应产物作为催化剂，并且使用获得的芳族二羧酸二氯化物和三羧酸三氯化物来制备缩聚物。
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公开(公告)号：US4322520A
公开(公告)日：1982-03-30
申请号：US160644
申请日：1980-06-18
CPC分类号： C08G79/04 , C08G64/083
摘要： Thermoplastic polyphosphonatocarbonate prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a basic polycondensation catalyst at a temperature of from 80.degree. to 340.degree. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonate and phosphonic acid diaryl ester being from 0.91:1 to 0.99:1, and following polycondensation, neutralizing said basic catalyst.
摘要翻译： 在碱性缩聚催化剂存在下，在80〜340℃，600〜0.1mmHg的压力下，使至少一种芳族二羟基化合物与碳酸二芳基酯和膦酸二芳基酯缩聚而得到的热塑性聚磷酸酯 惰性气体气氛中，碳酸二芳酯与膦酸二芳基酯的摩尔比为5:95至95:5，芳族二羟基化合物与碳酸二芳基酯和膦酸二芳基酯的摩尔比为0.91:1至0.99 ：1，并进行缩聚，中和所述碱性催化剂。
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公开(公告)号：US4308216A
公开(公告)日：1981-12-29
申请号：US164046
申请日：1980-06-30
IPC分类号： C07C63/15 , B01J31/00 , B01J31/02 , C07B61/00 , C07C51/00 , C07C51/60 , C07C63/33 , C07C65/21 , C07C67/00 , C07C313/00 , C07C323/62
CPC分类号： C07C51/60 , B01J31/0267
摘要： A one-step process for the preparation of pure aromatic dicarboxylic acid dichlorides by reacting an aromatic dicarboxylic acid or an aromatic dicarboxylic acid mixture with phosgene in the presence of a catalyst and, optionally, in a solvent or diluent, by using tertiary phosphines as catalysts, and the use of the dicarboxylic acid dichlorides obtained for the production of polycondensates.
摘要翻译： 通过使用叔膦作为催化剂，在催化剂和任选的溶剂或稀释剂的存在下，使芳族二羧酸或芳族二羧酸混合物与光气反应制备纯芳族二羧酸二氯化物的一步法 ，以及使用得到的用于制备缩聚物的二羧酸二氯化物。
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10.发明授权Process for the preparation of thermoplastic aromatic polyphosphonatocarbonates with improved heat-aging resistance, and their use 失效具有改善耐热老化性的热塑性芳族聚碳酸亚烃酯的制备方法及其用途
公开(公告)号：US4508890A
公开(公告)日：1985-04-02
申请号：US493793
申请日：1983-05-12
摘要： Thermoplastic polyphosphonatocarbonates prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a catalyst selected from the group consisting of (a) tetra-C.sub.1 -C.sub.18 -alkyl titanates, (b) di-C.sub.2 -C.sub.4 -alkyl-tin oxides, (c) di-C.sub.2 -C.sub.4 -alkyl-di-C.sub.1 -C.sub.4 -alkoxy-tin compounds, (d) tetra-C.sub.3 -C.sub.18 -alkyl zirconates, (e) tri-C.sub.2 -C.sub.18 -alkyl vanadylates and (f) mixtures of germanium dioxide or titanium dioxide and at least one of (a) to (e) in a weight ratio of 1:3 to 3:1 at a temperature of from 80.degree.-340.degree. C. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonates and phosphonic diaryl ester being from 0.91:1 to 0.99:1.
摘要翻译： 在选自以下的催化剂存在下，将至少一种芳族二羟基化合物与碳酸二芳酯和膦酸二芳基酯缩聚制备的热塑性聚膦酸碳酸酯：（a）四-C1-烷基钛酸酯，（b）二 - （c）二-C2-C4-烷基 - 二-C1-C4烷氧基锡化合物，（d）四-C 3 -C 18烷基锆酸盐，（e）三-C2-烷基 - C18烷基氧钒酸酯和（f）二氧化锗或二氧化钛与至少一种（a）至（e）的混合物，重量比为1:3至3:1，温度为80-340℃ 并且在惰性气体气氛中在600至0.1mm Hg的压力下，碳酸二芳酯与膦酸二芳基酯的摩尔比为5:95至95:5，芳族二羟基化合物与碳酸二芳基酯的摩尔比 和膦酸二芳基酯为0.91:1至0.99:1。
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