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    Ureidoperoxycarboxylic acids and preparation and use thereof
    1.
    发明授权
    Ureidoperoxycarboxylic acids and preparation and use thereof 失效
    尿嘧啶羧酸和其制备和用途

    公开(公告)号：US5149864A

    公开(公告)日：1992-09-22

    申请号：US703461

    申请日：1991-05-21

    Applicant: Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    Inventor： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    IPC: A01N47/28 ,  C07C407/00 ,  C07C409/40 ,  C11D3/39 ,  C11D7/54

    CPC classification number: C07C409/40 ,  C11D3/3945

    Abstract: Compounds of the formula ##STR1## where y is 1 or 2,A is hydrogen, C.sub.1 -C.sub.2 -alkyl, aryl or a group of the formula ##STR2## if y is 1, or C.sub.2 -C.sub.20 -alkylene or arylene if y is 2, R.sup.1 and R.sup.2 can be identical or different and each is hydrogen, C.sub.1 -C.sub.20 -alkyl, aryl, haloaryl, alkoxyaryl or alkylaryl, or else R.sup.1 and R.sup.2 together are a C.sub.2 -C.sub.4 -alkylene radical,x is 0 or 1,B is a group of the formula ##STR3## n is from 1 to 20, m is 0, 1 or 2,R.sup.3 is C.sub.1 -C.sub.20 -alkyl andR.sup.4 is in each case hydrogen or C.sub.1 -C.sub.20 -alkyl.These compounds are suitable for use as bleaching, oxidizing or disinfecting agents.

    Abstract translation: 其中y为1或2的化合物，如果y为1，则A为氢，C1-C2-烷基，芳基或式为IMA的基团，如果y为1，则为C2-C20-亚烷基或亚芳基 2，R 1和R 2可以相同或不同，各自为氢，C 1 -C 20 - 烷基，芳基，卤代芳基，烷氧基芳基或烷基芳基，或者R 1和R 2一起为C 2 -C 4亚烷基，x为0或1， B是下式的基团：n为1至20，m为0,1或2，R 3为C 1 -C 20烷基，R 4为氢或C 1 -C 20 - 烷基。 这些化合物适用于漂白，氧化或消毒剂。

    Sulfimidoperoxycarboxylic acids
    2.
    发明授权
    Sulfimidoperoxycarboxylic acids 失效
    磺酰氧基羧基酸

    公开(公告)号：US5153189A

    公开(公告)日：1992-10-06

    申请号：US793803

    申请日：1991-11-18

    Applicant: Walter Rupp ,  Hanspeter Gethoffer ,  Gerd Reinhardt ,  Frank Jaekel

    Inventor： Walter Rupp ,  Hanspeter Gethoffer ,  Gerd Reinhardt ,  Frank Jaekel

    IPC: A01N43/80 ,  C07D275/02 ,  C07D275/03 ,  C07D275/06 ,  C07D279/02 ,  C07D281/02 ,  C11D3/39 ,  C11D7/54

    CPC classification number: C07D275/02 ,  C07D275/03 ,  C07D275/06 ,  C11D3/3945

    Abstract: Sulfimidoperoxycarboxylic acids of the formula ##STR1## in which A is a group of the formula ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, fluorine, chlorine, bromine, C.sub.1 -C.sub.20 - alkyl, C.sub.2 -C.sub.20 -alkenyl, aryl or C.sub.1 -C.sub.10 -alkylaryl,R.sup.2 is hydrogen, fluorine, chlorine, bromine or a group of the formula SO.sub.3 M, CO.sub.2 M or OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or the stoichiometric amount of an alkaline earth metal ion andX is C.sub.1 -C.sub.19 -alkylene or ortho-, meta- or para-arylene.These sulfimidoperoxycarboxylic acids are suitable as bleaches, oxidants or disinfectants.

    Abstract translation: 式中，A为式（1）的基团的亚磺酰基过氧羧酸为数字0,1或2，R 1为氢，氟，氯，溴，C 1 -C 20烷基，C 2 C 20 - 烯基，芳基或C 1 -C 10烷基芳基，R 2是氢，氟，氯，溴或式SO 3 M，CO 2 M或OSO 3 M的基团，M是氢，碱金属或铵离子或化学计量的 碱土金属离子和X是C 1 -C 19 - 亚烷基或邻 - 间 - 或对 - 亚芳基。 这些亚磺酰过氧羧酸适合作为漂白剂，氧化剂或消毒剂。

    Ureidoperoxycarboxylic acids and preparation and use thereof
    5.
    发明授权
    Ureidoperoxycarboxylic acids and preparation and use thereof 失效
    尿过氧羧酸及其制备及应用

    公开(公告)号：US5292451A

    公开(公告)日：1994-03-08

    申请号：US893772

    申请日：1992-06-05

    Applicant: Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    Inventor： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    IPC: A01N47/28 ,  C07C407/00 ,  C07C409/40 ,  C11D3/39 ,  C11D7/54 ,  C01B15/00 ,  C11D7/38

    CPC classification number: C07C409/40 ,  C11D3/3945

    Abstract: Compounds of the formula ##STR1## where y is 1 or 2,A is hydrogen, C.sub.1 -C.sub.2 -alkyl, aryl or a group of the formula ##STR2## if y is 1, or C.sub.2 -C.sub.20 -alkylene or arylene if y is 2, R.sup.1 and R.sup.2 can be identical or different and each is hydrogen, C.sub.1 -C.sub.20 -alkyl, aryl, haloaryl, alkoxyaryl or alkylaryl, or else R.sup.1 and R.sup.2 together are a C.sub.2 -C.sub.4 -alkylene radical,x is 0 or 1,B is a group of the formula ##STR3## n is from 1 to 20, m is 0, 1 or 2,R.sup.3 is C.sub.1 -C.sub.20 -alkyl andR.sup.4 is in each case hydrogen or C.sub.1 -C.sub.20 -alkyl.These compounds are suitable for use as bleaching, oxidizing or disinfecting agents.

    Abstract translation: 其中y为1或2的化合物，如果y为1，则A为氢，C1-C2-烷基，芳基或式为IMA的基团，如果y为1，则为C2-C20-亚烷基或亚芳基 2，R 1和R 2可以相同或不同，各自为氢，C 1 -C 20 - 烷基，芳基，卤代芳基，烷氧基芳基或烷基芳基，或者R 1和R 2一起为C 2 -C 4亚烷基，x为0或1， B是下式的基团：n为1至20，m为0,1或2，R 3为C 1 -C 20烷基，R 4为氢或C 1 -C 20 - 烷基。 这些化合物适用于漂白，氧化或消毒剂。

    Stable peroxycarboxylic acid granule comprising an imidoperoxycarboxylic acid or salt thereof
    6.
    发明授权
    Stable peroxycarboxylic acid granule comprising an imidoperoxycarboxylic acid or salt thereof 失效
    稳定的过氧羧酸颗粒，其包含亚氨基过氧羧酸或其盐

    公开(公告)号：US5279757A

    公开(公告)日：1994-01-18

    申请号：US958602

    申请日：1992-10-06

    Applicant: Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Rudiger Funk

    Inventor： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Rudiger Funk

    IPC: C07D209/48 ,  C11D3/39 ,  C11D17/00 ,  C11D3/395 ,  C11D7/54 ,  C11D9/42

    CPC classification number: C11D17/0039 ,  C07D209/48 ,  C11D3/3945

    Abstract: Stable peroxycarboxylic acid granules composed essentially of (1) an imidoperoxycarboxylic acid or its salts of the formula ##STR1## in which A is a group of the formula ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkenyl, aryl or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine or a group of the formula --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or the equivalent of an alkaline earth metal ion, andX is C.sub.1 -C.sub.19 -alkylene or arylene,(2) an inorganic sulfate and/or phosphate salt and/or a non-oxidizable surfactant as granulating auxiliaries and (3) a homo- or copolymer of (meth)acrylic acid or its salts or a copolymer of (meth)acrylic acid or its salts and other carboxylic acids polymerizable therewith as a film-forming coating substance.

    Abstract translation: 基本上由（1）亚氨基过氧羧酸或其盐（*化学结构*）的盐组成的稳定的过氧羧酸颗粒，其中A是式（*化学结构*）（*化学结构*）或（*化学结构*） 结构*）n是数字0,1或2，R1是氢，氯，溴，C1-C20-烷基，C1-C20-烯基，芳基或烷基芳基，R2是氢，氯，溴或式 -SO 3 M，-CO 2 M或-OSO 3 M，M为氢，碱金属或铵离子或碱金属离子当量，X为C 1 -C 19 - 亚烷基或亚芳基，（2）无机硫酸盐和/或磷酸盐 盐和/或不可氧化的表面活性剂作为造粒助剂和（3）（甲基）丙烯酸或其盐的均聚物或共聚物或（甲基）丙烯酸或其盐与其可与其聚合的其它羧酸的共聚物，作为 成膜涂层物质。

    Stable peroxycarboxylic acid granules
    7.
    发明授权
    Stable peroxycarboxylic acid granules 失效
    稳定的过氧羧酸乳液颗粒

    公开(公告)号：US5246620A

    公开(公告)日：1993-09-21

    申请号：US687236

    申请日：1991-04-18

    Applicant: Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Christoph Porz

    Inventor： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Christoph Porz

    IPC: A01N37/22 ,  A01N43/40 ,  A01N43/46 ,  C11D3/37 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54

    CPC classification number: C11D3/3784 ,  C11D3/3761 ,  C11D3/3945

    Abstract: Stable peroxycarboxylic acid granules, consisting essentially of (1) an imidoperoxycarboxylic acid or a salt thereof of the formula ##STR1## wherein A is a group of the formulae ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkenyl, aryl or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine or a group of the formula --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or one equivalent of an alkaline earth metal ion andX is C.sub.1 -C.sub.19 -alkylene or arylene, and(2) an inorganic sulfate and/or phosphate salt and/or a nonoxidizable surfactant as granulation auxiliary and a copolymer based on alkenylaminomethylenephosphonic acids as a film-forming coating substance.

    Abstract translation: 稳定的过氧羧酸颗粒，其主要由（1）式（I）所示的亚氨基过氧羧酸或其盐组成，其中A是下式的基团：n是数字0,1或2 ，R1是氢，氯，溴，C1-C20-烷基，C1-C20-烯基，芳基或烷基芳基，R2是氢，氯，溴或式-SO3M，-CO2M或-OSO3M的基团，M是氢 ，碱金属或铵离子或一当量碱土金属离子，X为C 1 -C 19 - 亚烷基或亚芳基，（2）无机硫酸盐和/或磷酸盐和/或不可氧化的表面活性剂作为造粒助剂和 基于链烯基氨基亚甲基膦酸的共聚物作为成膜涂层物质。

    Use of triacylated ethanolamines as liquid, water-miscible peroxide activators
    9.
    发明授权
    Use of triacylated ethanolamines as liquid, water-miscible peroxide activators 失效
    使用三酰化乙醇胺作为液体，水混溶性过氧化物活化剂

    公开(公告)号：US5045222A

    公开(公告)日：1991-09-03

    申请号：US449990

    申请日：1989-12-13

    Applicant: Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

    Inventor： Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

    IPC: C11D3/395 ,  C11D3/39 ,  C11D7/32 ,  C11D7/54 ,  D06L3/02

    CPC classification number: C11D3/3917

    Abstract: Use of triacylated ethanolamines as liquid, water-miscible peroxide activatorsTriacylated ethanolamines of the formula(RCO)(R.sub.1 CO)N-(CH.sub.2).sub.2 -OCOR.sub.2where R, R.sub.1 and R.sub.2, which may be identical to or different from one another, are each alkyl, alkenyl or aryl, and the total number of carbon atoms in the molecule is from 8 to 14, are liquid and readily water-miscible. Owing to these properties, they are very useful as peroxide activators in liquid detergent compositions.

    Abstract translation: 使用三酰化乙醇胺作为液体，水混溶性过氧化物活化剂式（RCO）（R1CO）N-（CH2）2-OCOR2的三酰化乙醇胺其中R，R 1和R 2可以彼此相同或不同， 每个烷基，烯基或芳基，并且分子中的总碳原子数为8至14，是液体且容易与水混溶。 由于这些性质，它们作为液体洗涤剂组合物中的过氧化物活化剂是非常有用的。

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