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    Stable peroxycarboxylic acid granules
    1.
    发明授权
    Stable peroxycarboxylic acid granules 失效
    稳定的过氧羧酸乳液颗粒

    公开(公告)号：US5246620A

    公开(公告)日：1993-09-21

    申请号：US687236

    申请日：1991-04-18

    申请人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Christoph Porz

    发明人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Christoph Porz

    IPC分类号： A01N37/22 ,  A01N43/40 ,  A01N43/46 ,  C11D3/37 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54

    CPC分类号： C11D3/3784 ,  C11D3/3761 ,  C11D3/3945

    摘要： Stable peroxycarboxylic acid granules, consisting essentially of (1) an imidoperoxycarboxylic acid or a salt thereof of the formula ##STR1## wherein A is a group of the formulae ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkenyl, aryl or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine or a group of the formula --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or one equivalent of an alkaline earth metal ion andX is C.sub.1 -C.sub.19 -alkylene or arylene, and(2) an inorganic sulfate and/or phosphate salt and/or a nonoxidizable surfactant as granulation auxiliary and a copolymer based on alkenylaminomethylenephosphonic acids as a film-forming coating substance.

    摘要翻译： 稳定的过氧羧酸颗粒，其主要由（1）式（I）所示的亚氨基过氧羧酸或其盐组成，其中A是下式的基团：n是数字0,1或2 ，R1是氢，氯，溴，C1-C20-烷基，C1-C20-烯基，芳基或烷基芳基，R2是氢，氯，溴或式-SO3M，-CO2M或-OSO3M的基团，M是氢 ，碱金属或铵离子或一当量碱土金属离子，X为C 1 -C 19 - 亚烷基或亚芳基，（2）无机硫酸盐和/或磷酸盐和/或不可氧化的表面活性剂作为造粒助剂和 基于链烯基氨基亚甲基膦酸的共聚物作为成膜涂层物质。

    Stable peroxycarboxylic acid granule comprising an imidoperoxycarboxylic acid or salt thereof
    2.
    发明授权
    Stable peroxycarboxylic acid granule comprising an imidoperoxycarboxylic acid or salt thereof 失效
    稳定的过氧羧酸颗粒，其包含亚氨基过氧羧酸或其盐

    公开(公告)号：US5279757A

    公开(公告)日：1994-01-18

    申请号：US958602

    申请日：1992-10-06

    申请人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Rudiger Funk

    发明人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Gerhard Noltner ,  Rudiger Funk

    IPC分类号： C07D209/48 ,  C11D3/39 ,  C11D17/00 ,  C11D3/395 ,  C11D7/54 ,  C11D9/42

    CPC分类号： C11D17/0039 ,  C07D209/48 ,  C11D3/3945

    摘要： Stable peroxycarboxylic acid granules composed essentially of (1) an imidoperoxycarboxylic acid or its salts of the formula ##STR1## in which A is a group of the formula ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkenyl, aryl or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine or a group of the formula --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or the equivalent of an alkaline earth metal ion, andX is C.sub.1 -C.sub.19 -alkylene or arylene,(2) an inorganic sulfate and/or phosphate salt and/or a non-oxidizable surfactant as granulating auxiliaries and (3) a homo- or copolymer of (meth)acrylic acid or its salts or a copolymer of (meth)acrylic acid or its salts and other carboxylic acids polymerizable therewith as a film-forming coating substance.

    摘要翻译： 基本上由（1）亚氨基过氧羧酸或其盐（*化学结构*）的盐组成的稳定的过氧羧酸颗粒，其中A是式（*化学结构*）（*化学结构*）或（*化学结构*） 结构*）n是数字0,1或2，R1是氢，氯，溴，C1-C20-烷基，C1-C20-烯基，芳基或烷基芳基，R2是氢，氯，溴或式 -SO 3 M，-CO 2 M或-OSO 3 M，M为氢，碱金属或铵离子或碱金属离子当量，X为C 1 -C 19 - 亚烷基或亚芳基，（2）无机硫酸盐和/或磷酸盐 盐和/或不可氧化的表面活性剂作为造粒助剂和（3）（甲基）丙烯酸或其盐的均聚物或共聚物或（甲基）丙烯酸或其盐与其可与其聚合的其它羧酸的共聚物，作为 成膜涂层物质。

    Ureidoperoxycarboxylic acids and preparation and use thereof
    3.
    发明授权
    Ureidoperoxycarboxylic acids and preparation and use thereof 失效
    尿嘧啶羧酸和其制备和用途

    公开(公告)号：US5149864A

    公开(公告)日：1992-09-22

    申请号：US703461

    申请日：1991-05-21

    申请人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    发明人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    IPC分类号： A01N47/28 ,  C07C407/00 ,  C07C409/40 ,  C11D3/39 ,  C11D7/54

    CPC分类号： C07C409/40 ,  C11D3/3945

    摘要： Compounds of the formula ##STR1## where y is 1 or 2,A is hydrogen, C.sub.1 -C.sub.2 -alkyl, aryl or a group of the formula ##STR2## if y is 1, or C.sub.2 -C.sub.20 -alkylene or arylene if y is 2, R.sup.1 and R.sup.2 can be identical or different and each is hydrogen, C.sub.1 -C.sub.20 -alkyl, aryl, haloaryl, alkoxyaryl or alkylaryl, or else R.sup.1 and R.sup.2 together are a C.sub.2 -C.sub.4 -alkylene radical,x is 0 or 1,B is a group of the formula ##STR3## n is from 1 to 20, m is 0, 1 or 2,R.sup.3 is C.sub.1 -C.sub.20 -alkyl andR.sup.4 is in each case hydrogen or C.sub.1 -C.sub.20 -alkyl.These compounds are suitable for use as bleaching, oxidizing or disinfecting agents.

    摘要翻译： 其中y为1或2的化合物，如果y为1，则A为氢，C1-C2-烷基，芳基或式为IMA的基团，如果y为1，则为C2-C20-亚烷基或亚芳基 2，R 1和R 2可以相同或不同，各自为氢，C 1 -C 20 - 烷基，芳基，卤代芳基，烷氧基芳基或烷基芳基，或者R 1和R 2一起为C 2 -C 4亚烷基，x为0或1， B是下式的基团：n为1至20，m为0,1或2，R 3为C 1 -C 20烷基，R 4为氢或C 1 -C 20 - 烷基。 这些化合物适用于漂白，氧化或消毒剂。

    Sulfimidoperoxycarboxylic acids
    4.
    发明授权
    Sulfimidoperoxycarboxylic acids 失效
    磺酰氧基羧基酸

    公开(公告)号：US5153189A

    公开(公告)日：1992-10-06

    申请号：US793803

    申请日：1991-11-18

    申请人： Walter Rupp ,  Hanspeter Gethoffer ,  Gerd Reinhardt ,  Frank Jaekel

    发明人： Walter Rupp ,  Hanspeter Gethoffer ,  Gerd Reinhardt ,  Frank Jaekel

    IPC分类号： A01N43/80 ,  C07D275/02 ,  C07D275/03 ,  C07D275/06 ,  C07D279/02 ,  C07D281/02 ,  C11D3/39 ,  C11D7/54

    CPC分类号： C07D275/02 ,  C07D275/03 ,  C07D275/06 ,  C11D3/3945

    摘要： Sulfimidoperoxycarboxylic acids of the formula ##STR1## in which A is a group of the formula ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, fluorine, chlorine, bromine, C.sub.1 -C.sub.20 - alkyl, C.sub.2 -C.sub.20 -alkenyl, aryl or C.sub.1 -C.sub.10 -alkylaryl,R.sup.2 is hydrogen, fluorine, chlorine, bromine or a group of the formula SO.sub.3 M, CO.sub.2 M or OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or the stoichiometric amount of an alkaline earth metal ion andX is C.sub.1 -C.sub.19 -alkylene or ortho-, meta- or para-arylene.These sulfimidoperoxycarboxylic acids are suitable as bleaches, oxidants or disinfectants.

    摘要翻译： 式中，A为式（1）的基团的亚磺酰基过氧羧酸为数字0,1或2，R 1为氢，氟，氯，溴，C 1 -C 20烷基，C 2 C 20 - 烯基，芳基或C 1 -C 10烷基芳基，R 2是氢，氟，氯，溴或式SO 3 M，CO 2 M或OSO 3 M的基团，M是氢，碱金属或铵离子或化学计量的 碱土金属离子和X是C 1 -C 19 - 亚烷基或邻 - 间 - 或对 - 亚芳基。 这些亚磺酰过氧羧酸适合作为漂白剂，氧化剂或消毒剂。

    Ureidoperoxycarboxylic acids and preparation and use thereof
    7.
    发明授权
    Ureidoperoxycarboxylic acids and preparation and use thereof 失效
    尿过氧羧酸及其制备及应用

    公开(公告)号：US5292451A

    公开(公告)日：1994-03-08

    申请号：US893772

    申请日：1992-06-05

    申请人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    发明人： Hanspeter Gethoffer ,  Gerd Reinhardt ,  Peter Naumann

    IPC分类号： A01N47/28 ,  C07C407/00 ,  C07C409/40 ,  C11D3/39 ,  C11D7/54 ,  C01B15/00 ,  C11D7/38

    CPC分类号： C07C409/40 ,  C11D3/3945

    摘要： Compounds of the formula ##STR1## where y is 1 or 2,A is hydrogen, C.sub.1 -C.sub.2 -alkyl, aryl or a group of the formula ##STR2## if y is 1, or C.sub.2 -C.sub.20 -alkylene or arylene if y is 2, R.sup.1 and R.sup.2 can be identical or different and each is hydrogen, C.sub.1 -C.sub.20 -alkyl, aryl, haloaryl, alkoxyaryl or alkylaryl, or else R.sup.1 and R.sup.2 together are a C.sub.2 -C.sub.4 -alkylene radical,x is 0 or 1,B is a group of the formula ##STR3## n is from 1 to 20, m is 0, 1 or 2,R.sup.3 is C.sub.1 -C.sub.20 -alkyl andR.sup.4 is in each case hydrogen or C.sub.1 -C.sub.20 -alkyl.These compounds are suitable for use as bleaching, oxidizing or disinfecting agents.

    摘要翻译： 其中y为1或2的化合物，如果y为1，则A为氢，C1-C2-烷基，芳基或式为IMA的基团，如果y为1，则为C2-C20-亚烷基或亚芳基 2，R 1和R 2可以相同或不同，各自为氢，C 1 -C 20 - 烷基，芳基，卤代芳基，烷氧基芳基或烷基芳基，或者R 1和R 2一起为C 2 -C 4亚烷基，x为0或1， B是下式的基团：n为1至20，m为0,1或2，R 3为C 1 -C 20烷基，R 4为氢或C 1 -C 20 - 烷基。 这些化合物适用于漂白，氧化或消毒剂。

    Use of triacylated ethanolamines as liquid, water-miscible peroxide activators
    9.
    发明授权
    Use of triacylated ethanolamines as liquid, water-miscible peroxide activators 失效
    使用三酰化乙醇胺作为液体，水混溶性过氧化物活化剂

    公开(公告)号：US5045222A

    公开(公告)日：1991-09-03

    申请号：US449990

    申请日：1989-12-13

    申请人： Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

    发明人： Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

    IPC分类号： C11D3/395 ,  C11D3/39 ,  C11D7/32 ,  C11D7/54 ,  D06L3/02

    CPC分类号： C11D3/3917

    摘要： Use of triacylated ethanolamines as liquid, water-miscible peroxide activatorsTriacylated ethanolamines of the formula(RCO)(R.sub.1 CO)N-(CH.sub.2).sub.2 -OCOR.sub.2where R, R.sub.1 and R.sub.2, which may be identical to or different from one another, are each alkyl, alkenyl or aryl, and the total number of carbon atoms in the molecule is from 8 to 14, are liquid and readily water-miscible. Owing to these properties, they are very useful as peroxide activators in liquid detergent compositions.

    摘要翻译： 使用三酰化乙醇胺作为液体，水混溶性过氧化物活化剂式（RCO）（R1CO）N-（CH2）2-OCOR2的三酰化乙醇胺其中R，R 1和R 2可以彼此相同或不同， 每个烷基，烯基或芳基，并且分子中的总碳原子数为8至14，是液体且容易与水混溶。 由于这些性质，它们作为液体洗涤剂组合物中的过氧化物活化剂是非常有用的。

    Alkenylaminomethylenephosphonic acids and copolymers thereof with unsaturated carboxylic acids
    10.
    发明授权
    Alkenylaminomethylenephosphonic acids and copolymers thereof with unsaturated carboxylic acids 失效
    具有不饱和羧酸的亚甲基氨基磺酰脲类和共聚物

    公开(公告)号：US5126418A

    公开(公告)日：1992-06-30

    申请号：US642519

    申请日：1991-01-17

    申请人： Christoph Porz ,  Gerd Reinhardt ,  Hermann Hoffmann

    发明人： Christoph Porz ,  Gerd Reinhardt ,  Hermann Hoffmann

    IPC分类号： B01F17/52 ,  C07F9/38 ,  C08F26/00 ,  C08F26/02 ,  C08F30/02 ,  C23F11/167 ,  E21B43/22

    CPC分类号： C08F30/02 ,  C07F9/3808

    摘要： Alkenylaminomethylenephosphonic acids of the formula ##STR1## in which R.sub.1 is hydrogen, C.sub.4 -C.sub.10 -alkyl, phenyl, naphthyl, methylphenyl, hydroxyphenyl, methoxyphenyl, methylnaphthyl, hydroxynaphthyl or methoxynaphthyl,R.sub.2 is hydrogen,R.sub.3, R.sub.4, R.sub.5 are hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl, andM is hydrogen or a cation,and copolymers comprising 0.1-99.9% by weight, preferably 1-50% by weight, of one or more monomers of the formula I, in which R.sub.2 is hydrogen or a group of the formula--CH.sub.2 PO.sub.3 M.sub.2, and 99.9-0.1% by weight, preferably 99-50% by weight, of one or more monomers of the formula IIR.sub.1 'R.sub.2 'C.dbd.CR.sub.3 'X (II)in whichR.sub.1 ' is hydrogen or a group of the formula --COOM,R.sub.2 ' is hydrogen, phenyl or a group of the formula --COOM,R.sub.3 ' is hydrogen, methyl or a group of the formula --COOM or --CH.sub.2 COOM,X is a group of the formula --COOM orR.sub.2 ' and R.sub.3 ' together are a C.sub.4 -alkylene orR.sub.1 ' X together are a group of the formula ##STR2## or R.sub.3 ' and X together are a group of the formula ##STR3## These copolymers are suitable as complexing agents, in particular detergents as builder and co-builder, peroxide stabilizers and as granulating aids for bleaching activators and in crude oil recovery as scale inhibitors having anti-corrosive action.

    摘要翻译： 式（Ⅰ）的烯基氨基亚甲基膦酸，其中R1是氢，C4-C10-烷基，苯基，萘基，甲基苯基，羟基苯基，甲氧基苯基，甲基萘基，羟基萘基或甲氧基萘基，R2是氢，R3，R4，R5是氢 或甲基，R 5是氢，C 1 -C 4 - 烷基或苯基，M是氢或阳离子，和包含0.1-99.9重量％，优选1-50重量％的一种或多种式I单体的共聚物 ，其中R 2是氢或式-CH 2 PO 3 M 2的基团，和99.9-0.1重量％，优选99-50重量％的一种或多种式II的R 1'R 2 C = CR 3'X（ II）其中R1'是氢或式-COOM，R2'是氢，苯基或式-COOM的基团，R3'是氢，甲基或式-COOM或-CH2COOM的基团， X是式-COOM或R 2'的基团，R 3'一起是C 4 - 亚烷基或R 1'X一起是下式的基团，或者R 3'和X一起是式 这些共聚物适合作为络合剂，特别是作为助洗剂和助洗剂，过氧化物稳定剂的洗涤剂，以及作为漂白活化剂的造粒助剂和作为具有抗腐蚀作用的防垢剂的原油回收。