2-amino-3,5-di-(halomethyl)-pyrazines and their preparation
    1.
    发明授权
    2-amino-3,5-di-(halomethyl)-pyrazines and their preparation 失效
    2-氨基-3,5-二(卤代甲基) - 吡嗪及其制备方法

    公开(公告)号:US4692527A

    公开(公告)日:1987-09-08

    申请号:US776460

    申请日:1985-09-16

    IPC分类号: C07D241/20 C07D403/04

    摘要: 2-Amino-3,5-di-(halomethyl)-pyrazines of the general formula I ##STR1## where X is either chlorine or bromine, m and n may each be 0, 1, 2 or 3 and R.sup.1 and R.sup.2 are each hydrogen or a protective group or may furthermore be bonded to one another, in particular those compounds of the formula I in which m is 1 and n is 2 and/or R.sup.1 and R.sup.2 together form a phthaloyl radical, are useful intermediates for the pteridine building block of folic acid or folic acid analogs.They are obtained by a method in which a 2-amino-3,5-dimethylpyrazine of the general formula II ##STR2## is treated with a chlorinating or brominating agent and, where R.sup.1 and/or R.sup.2 are protective groups, these are, if desired, eliminated when the chlorination or bromination is complete.

    摘要翻译: 其中X是氯或溴,m和n的通式I(I)的2-氨基-3,5-二(卤代甲基) - 吡嗪可以各自为0,1,2或3,R1和 R2各自为氢或保护基,或者还可以彼此键合,特别是其中m为1且n为2的式I化合物和/或R 1和R 2一起形成邻苯二甲酰基的有用的中间体 叶酸或叶酸类似物的蝶啶结构单元。 它们是通过一种方法获得的,其中通式II的2-氨基-3,5-二甲基吡嗪用氯化或溴化剂处理,其中R 1和/或R 2是保护基,这些 如果需要,当氯化或溴化完成时,它们被消除。

    Preparation of 2-amino-3-cyano-5-dialkoxymethylpyrazines and
intermediates for this method
    2.
    发明授权
    Preparation of 2-amino-3-cyano-5-dialkoxymethylpyrazines and intermediates for this method 失效
    2-氨基-3-氰基-5-二烷氧基甲基吡嗪的制备及其制备方法

    公开(公告)号:US4725689A

    公开(公告)日:1988-02-16

    申请号:US776462

    申请日:1985-09-16

    摘要: 2-Amino-3-cyano-5-dialkoxymethylpyrazine derivatives of the general formula III ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or a protective group usually employed for amino groups and R.sup.5 and R.sup.6 are each alkyl of 1 to 4 carbon atoms, or together form an ethylene or propylene radical which is unsubstituted or substituted by methyl, are prepared starting from a novel 3-halomethyl-5-dihalomethyl-2-aminopyrazine derivative of the formula IV ##STR2## where X is Cl or Br, via a novel intermediate of the general formula I ##STR3## where R.sup.3 is --CH.sub.2 --O--CO--CH.sub.3 (a), --CH.sub.2 OH (b), ##STR4## or --C.tbd.N (d) and R.sup.4 is --CHCl.sub.2 or --CHBr.sub.2 or, where R.sup.1 and R.sup.2 are each a protective group, R.sup.4 may furthermore be ##STR5##The compounds according to the invention are useful intermediates for the preparation of folic acid and active compounds derived from this.

    摘要翻译: 通式III(III)的2-氨基-3-氰基-5-二烷氧基甲基吡嗪衍生物其中R 1和R 2各自为氢或通常用于氨基的保护基,R 5和R 6各自为1-4的烷基 碳原子,或一起形成未被取代或被甲基取代的乙烯或丙烯基团,由式IV(IV)的新型3-卤代甲基-5-二卤代甲基-2-氨基吡嗪衍生物制备,其中X为 Cl或Br通过通式I的新型中间体(I),其中R 3是-CH 2 -O-CO-CH 3(a),-CH 2 OH(b),(c)或-C 3 N(d)和R4是-CHCl 2或-CHBr 2,或者其中R 1和R 2各自是保护基,R 4还可以是本发明的化合物是用于制备叶酸和活性化合物的有用中间体 由此。

    Units and methods for energy storage

    公开(公告)号:US09726150B2

    公开(公告)日:2017-08-08

    申请号:US14355994

    申请日:2012-07-18

    摘要: The invention relates to a pumped storage power plant (1) comprising at least one lower storage space (11) that is arranged underground and at least one upper storage space (12) that is separate from the lower storage space and arranged above ground or underground, wherein the lower storage space (11) is arranged in a greater depth than the upper storage space (12), and comprising at least one liquid line (15, 16) that is/are guided within the upper storage space (12) and within the lower storage space (11) respectively and that is/are connected to at least one hydraulic force and/or work machine (26, 27) of the pumped storage plant or can be connected via switchable valves (28, 29), and comprising at least one pressurized gas line (17, 18) that is/are guided within the upper storage space (12) and within the lower storage space (11) respectively and that is/are connected to a pressurized gas force and/or work machine (21, 22) of the pumped storage power plant or can be connected via switchable valves (24, 25), wherein the pumped storage power plant is configured for transporting a liquid medium (5, 7) from the upper storage space (12) into the lower storage space (11) and vice versa through the liquid lines (15, 16) and the hydraulic force and/or work machine (26, 27), and the pressurized gas force and/or working machine (21, 22) is configured for optionally producing a pressurized gas pressure of a pressurized gas (4, 6) at least in the lower storage space (11), which gas pressure can differ from a gas pressure in the upper storage space (12). Furthermore, the invention relates to a power plant and to methods for energy storage.

    UNITS AND METHODS FOR ENERGY STORAGE
    6.
    发明申请
    UNITS AND METHODS FOR ENERGY STORAGE 有权
    单位和能源储存方法

    公开(公告)号:US20150091301A1

    公开(公告)日:2015-04-02

    申请号:US14355994

    申请日:2012-07-18

    IPC分类号: F03B13/06 H02P9/04 H02K7/18

    摘要: The invention relates to a pumped storage power plant (1) comprising at least one lower storage space (11) that is arranged underground and at least one upper storage space (12) that is separate from the lower storage space and arranged above ground or underground, wherein the lower storage space (11) is arranged in a greater depth than the upper storage space (12), and comprising at least one liquid line (15, 16) that is/are guided within the upper storage space (12) and within the lower storage space (11) respectively and that is/are connected to at least one hydraulic force and/or work machine (26, 27) of the pumped storage plant or can be connected via switchable valves (28, 29), and comprising at least one pressurized gas line (17, 18) that is/are guided within the upper storage space (12) and within the lower storage space (11) respectively and that is/are connected to a pressurized gas force and/or work machine (21, 22) of the pumped storage power plant or can be connected via switchable valves (24, 25), wherein the pumped storage power plant is configured for transporting a liquid medium (5, 7) from the upper storage space (12) into the lower storage space (11) and vice versa through the liquid lines (15, 16) and the hydraulic force and/or work machine (26, 27), and the pressurized gas force and/or working machine (21, 22) is configured for optionally producing a pressurized gas pressure of a pressurized gas (4, 6) at least in the lower storage space (11), which gas pressure can differ from a gas pressure in the upper storage space (12). Furthermore, the invention relates to a power plant and to methods for energy storage.

    摘要翻译: 本发明涉及一种抽水蓄能发电厂(1),其包括至少一个位于地下的下部存储空间(11)和与下部存储空间分离并布置在地面或地下的至少一个上部存储空间(12) ,其中所述下部存储空间(11)布置成比所述上部存储空间(12)更深的深度,并且包括在所述上部存储空间(12)内被引导的至少一个液体线(15,16)和 分别在下部存储空间(11)内并且连接到所抽吸的储存设备的至少一个液压力和/或作业机械(26,27),或者可以经由可切换阀(28,29)连接,并且 包括至少一个加压气体管线(17,18),所述至少一个加压气体管线(17,18)分别在所述上部存储空间(12)内和所述下部存储空间(11)内被引导并且被连接到加压气体力和/或工作 抽水蓄能电站的机器(21,22),或者可以通过s连接 有用的阀门(24,25),其中所述泵送的储存发电厂被配置为将液体介质(5,7)从所述上部存储空间(12)输送到所述下部存储空间(11)中,反之亦然地通过所述液体管线 15,26)以及液压力和/或作业机械(26,27),并且所述加压气体力和/或加工机构(21,22)构造成可选地产生加压气体(4, 6)至少在下部存储空间(11)中,该气体压力可以与上部存储空间(12)中的气体压力不同。 此外,本发明涉及发电厂和能量储存方法。

    Device for fine honing crankshafts
    7.
    发明授权
    Device for fine honing crankshafts 失效
    精密珩磨曲轴的装置

    公开(公告)号:US4023311A

    公开(公告)日:1977-05-17

    申请号:US566684

    申请日:1975-04-10

    CPC分类号: B24B33/04 B24B5/42

    摘要: A device for fine honing cylindrical surfaces, such as the bearings of a crankshaft, in which the surface is stationarily supported while an annular tool holder separable along a diameter is disposed around the surface. The tool holder has housing elements therein and is rotated about the axis of the surface while being oscillated in a direction parallel to the axis. The tool holder is rotatable in a housing which is also separable along a diameter of the tool holder while the housing is supported for adjustable positioning to align the tool holder with the surface.

    摘要翻译: 用于精细珩磨圆柱形表面的装置,例如曲轴的轴承,其中表面被固定地支撑,同时沿着直径可分离的环形工具架设置在表面周围。 工具架具有壳体元件,并且在平行于轴线的方向上摆动的同时围绕表面的轴线旋转。 工具架可旋转在壳体中,壳体也可沿刀具保持器的直径分离,同时壳体被支撑用于可调整的定位以使刀架与表面对准。