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公开(公告)号：US5605942A
公开(公告)日：1997-02-25
申请号：US583746
申请日：1996-01-17
CPC分类号： C08G73/106 , C08G73/1039 , G02B1/043
摘要： A contact lens material comprising a condensation polymer having a recurring unit represented by the formula (I): ##STR1## wherein R.sup.1 is --C(CF.sub.3).sub.2 -- or ##STR2## R.sup.2 is a group represented by the formula: ##STR3## in which l is an integer of 1 to 3, m is an integer of 1 to 15 and n is an integer of 1 to 3, ##STR4## in which u is an integer of 1 to 3 and v is an integer of 1 to 3, a group represented by the formula (II): ##STR5## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and each is hydrogen atom or an alkyl group having 1 to 5 carbon atoms, or a group represented by the formula (III): ##STR6## wherein R.sup.7 is --C(CF.sub.3).sub.2 --, ##STR7## or a direct bond, and R.sup.8 and R.sup.9 are the same or different and each is an alkyl group having 1 to 3 carbon atoms, a fluoroalkyl group having 1 to 3 carbon atoms, hydrogen atom, hydroxyl group or carboxyl group. The contact lens material is excellent in transparency, having high oxygen permeability and moreover, excellent in heat resistance, ultraviolet-ray absorbing property and forming and processing property.
摘要翻译： 包含具有由式（I）表示的重复单元的缩聚物的隐形眼镜材料：其中R 1是-C（CF 3）2 - 或R 2是由下式表示的基团： IMAGE>其中l为1〜3的整数，m为1〜15的整数，n为1〜3的整数，＆lt; IMAGE＆gt;中，u为1〜3的整数，v为 1〜3，式（II）表示的基团：其中R 3，R 4，R 5和R 6相同或不同，各自为氢原子或碳原子数1〜5的烷基， 由式（III）表示的基团：其中R 7是-C（CF 3）2 - ， - 或直接键，其中R 8和R 9相同或不同，并且各自为烷基 具有1至3个碳原子，具有1至3个碳原子的氟代烷基，氢原子，羟基或羧基。 隐形眼镜材料的透明度优异，透氧性高，耐热性，紫外线吸收性，成型加工性优异。
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公开(公告)号：US5703143A
公开(公告)日：1997-12-30
申请号：US590600
申请日：1996-01-24
CPC分类号： G02B1/043
摘要： A transparent ocular lens material comprising a silicon-containing polymer having a recurring unit represented by the general formula (I): ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms or a group represented by the general formula (lI): ##STR2## in which each of R.sup.5, R.sup.6 and R.sup.7 is independently an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms or phenyl group. The ocular lens material has excellent transparency, high oxygen permeability and heat resistance, and excellent ultraviolet-ray absorbing properties and forming and processing properties, and has a relatively high refractive index.
摘要翻译： 一种透明眼透镜材料，其包含具有由通式（I）表示的重复单元的含硅聚合物：其中R 1，R 2，R 3和R 4各自独立地为氢原子，具有1个 具有1至5个碳原子的烷氧基或由通式（I）表示的基团：其中R 5，R 6和R 7各自独立地为具有1至5个碳原子的烷基 碳原子，碳原子数1〜5的烷氧基或苯基。 眼透镜材料具有优异的透明性，高透氧性和耐热性，并且具有优异的紫外线吸收特性和成形加工性能，并且具有较高的折射率。
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公开(公告)号：US5543442A
公开(公告)日：1996-08-06
申请号：US274293
申请日：1994-07-12
CPC分类号： C08G73/106 , C08G73/1039 , G02B1/043
摘要： A transparent ocular lens material comprising a condensation polymer prepared by the condensation polymerization of a monomer mixture comprising (A) an aromatic tetracarboxylic acid dianhydride and (B) at least one diamino compound selected from (a) a silicon-containing diamine, (b) a diamino-substituted benzene and (c) a diamino-substituted diphenyl. The ocular lens material is excellent in transparency, having high oxygen permeability and moreover, excellent in heat resistance, ultraviolet-ray absorbing property and forming and processing property. Therefore, the ocular lens material can be suitably used in contact lenses, intraocular lenses, and the like.
摘要翻译： 一种透明眼用透镜材料，其包含通过包含（A）芳族四羧酸二酐和（B）至少一种选自（a）含硅二胺，（b） 二氨取代的苯和（c）二氨基取代的二苯基。 眼透镜材料的透明度优异，透氧性高，耐热性，紫外线吸收性，成型加工性优异。 因此，眼透镜材料可以适用于隐形眼镜，人工晶状体等。
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公开(公告)号：US5397511A
公开(公告)日：1995-03-14
申请号：US131393
申请日：1993-10-05
CPC分类号： G02B1/043 , B29C43/003 , B29D11/023 , B29K2079/08 , B29K2105/251
摘要： A method of producing an intraocular lens having integrally formed optic and haptic including the steps of: (a) preparing a polyimide powder having a repeated unit represented by the following formula: ##STR1## [in the formula, when R.sub.1 =--C(CF.sub.3).sub.2 --, R.sub.2 is selected from ##STR2## the polyimide powder having a particle size of less than 1 mm; (b) placing the polyimide powder between a pair of dies having a pattern corresponding to a part of the contour of the lens; (c) hot pressing the polyimide powder between the dies, to provide a molding having the above part of the contour of the lens; and (d) machining the molding to form the rest of the contour of the lens to thereby provide the overall shape of the intraocular lens.
摘要翻译： 一种制造具有整体形成的光学和触觉的人工晶状体的方法，包括以下步骤：（a）制备具有由下式表示的重复单元的聚酰亚胺粉末：[式中，当R 1 = -C（CF 3） ）2-，R2选自SO 2，O，R 2是C（CF 3）2，具有小于1mm的粒度的聚酰亚胺粉末; （b）将聚酰亚胺粉末放置在具有对应于透镜轮廓的一部分的图案的一对模具之间; （c）在模具之间热压聚酰亚胺粉末，以提供具有上述透镜轮廓部分的模制品; 和（d）加工模制件以形成透镜的其余部分，从而提供眼内透镜的整体形状。
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5.发明授权Process for producing contact lens with hydrophilic surface and contact lens obtained thereby 有权用于制造具有亲水性表面的隐形眼镜和由此获得的隐形眼镜的方法
公开(公告)号：US6018001A
公开(公告)日：2000-01-25
申请号：US155051
申请日：1998-09-23
IPC分类号： C08F212/14 , C08F220/22 , C08F220/30 , C08F230/08 , C08J7/12 , G02B1/04 , C08F8/12
CPC分类号： G02B1/043 , C08F212/14 , C08F220/22 , C08F220/30 , C08F230/08 , C08J7/12
摘要： A process for producing a contact lens having a hydrophilic surface comprising subjecting a contact lens material comprising a copolymer prepared by copolymerizing a monomer mixture containing a polymerizable monomer (A) which is at least one member selected from a sugar ketal-containing (meth)acrylate and a sugar glycerol ketal-containing (meth)acrylate, and a polymerizable monomer (B) which is copolymerizable with the polymerizable monomer (A) to acid treatment, wherein the polymerizable monomer (B) contains a hydrophobic monomer which is at least one member selected from a silicon-containing monomer, a fluorine-containing monomer and a silicon- and fluorine-containing monomer, and a contact lens which has high oxygen permeability and of which surface shows stably excellent hydrophilic property and which is excellent in deposit resistance at the same time.
摘要翻译： PCT No.PCT / JP98 / 00153 Sec。 371日期：1998年9月23日 102（e）1998年9月23日PCT 1998年1月19日PCT PCT。 第WO98 / 33089号公报 日本1998年7月30日一种具有亲水性表面的隐形眼镜的制造方法，其特征在于，使包含通过使含有聚合性单体（A）的单体混合物共聚而成的共聚物接触，所述聚合性单体（A）为选自糖缩酮 - 含有（甲基）丙烯酸酯和含糖甘油缩酮的（甲基）丙烯酸酯的聚合性单体（B）与可聚合单体（A）可共聚的可聚合单体（B）进行酸处理，其中可聚合单体（B） 是选自含硅单体，含氟单体和含硅和氟的单体中的至少一种，和具有高透氧性并且其表面显示出稳定优异的亲水性的隐形眼镜，并且其优异 同时存在抵押。
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公开(公告)号：US5869547A
公开(公告)日：1999-02-09
申请号：US997702
申请日：1997-12-23
申请人： Haruyuki Hiratani
发明人： Haruyuki Hiratani
摘要： An ocular lens material made of a polymer obtained by polymerizing polymerizable components comprising a monomer of the formula (I): ##STR1## wherein R.sup.1 is a group of the formula: ##STR2## wherein R.sup.2 is a C.sub.1-5 alkylene group, and R.sup.3 is a hydrogen atom or a methyl group, or a group of the formula: ##STR3## wherein R.sup.4 is a direct bond or a C.sub.1-5 alkylene group.
摘要翻译： 由通过聚合包含式（I）的单体的可聚合组分获得的聚合物制成的眼镜片材料：其中R1是下式的基团：其中R2是C1-5亚烷基 R 3为氢原子或甲基，或下式的基团：其中R 4为直接键或C 1-5亚烷基。
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公开(公告)号：US5811502A
公开(公告)日：1998-09-22
申请号：US965435
申请日：1997-11-06
申请人： Haruyuki Hiratani
发明人： Haruyuki Hiratani
摘要： An ocular lens material made of a polymer obtained by polymerizing polymerizable components comprising a monomer of the formula (I): ##STR1## wherein R.sup.1 is a group of the formula: ##STR2## wherein R.sup.3 is a hydrogen atom or a methyl group, or a group of the formula: ##STR3## R.sup.2 is a C.sub.1-5 alkylene group, and X is a group of the formula ##STR4## a group of the formula ##STR5## a group of the formula ##STR6## or a group of the formula ##STR7##
摘要翻译： 由通过聚合包含式（I）的单体的可聚合组分获得的聚合物制成的眼镜片材料：其中R1是下式的基团：其中R3是氢原子或甲基 基团或下式的基团：
R 2是C 1-5亚烷基，X是式“IMAGE”的式oup或式“IMAGE”的基团， -
公开(公告)号：US5502086A
公开(公告)日：1996-03-26
申请号：US262457
申请日：1994-06-20
申请人： Haruyuki Hiratani , Keiji Sugimoto
发明人： Haruyuki Hiratani , Keiji Sugimoto
IPC分类号： C08F290/00 , C08F265/04 , G02B1/04 , G02C7/04 , C08L29/00
CPC分类号： G02B1/043 , C08F265/04
摘要： A water-absorptive contact lens obtained by saponification of a copolymer composed essentially of (A) from 1 to 30% by weight of a (meth)acrylate polymer having at least one polymerizable group per molecule on an average obtained by copolymerizing (a) an alkyl (meth)acrylate and (b) a monomer having at least two polymerizable groups per molecule, as the main components; (B) from 45 to 95% by weight of a fatty acid vinyl ester; (C) from 0.02 to 10% by weight of a crosslinking agent which is not decomposable by saponification; and (D) from 0.1 to 20% by weight of a crosslinking agent which is decomposable by saponification.
摘要翻译： 通过基本上由（A）组成的共聚物皂化而获得的吸水性隐形眼镜，其平均得自1重量％至30重量％的每分子具有至少一个可聚合基团的（甲基）丙烯酸酯聚合物，其通过共聚合（a） （甲基）丙烯酸烷基酯和（b）每分子具有至少两个可聚合基团的单体作为主要成分; （B）45〜95重量％的脂肪酸乙烯基酯; （C）0.02〜10重量％的不能通过皂化分解的交联剂; 和（D）0.1〜20重量％的可通过皂化分解的交联剂。
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公开(公告)号：US6015874A
公开(公告)日：2000-01-18
申请号：US178427
申请日：1998-10-26
申请人： Haruyuki Hiratani
发明人： Haruyuki Hiratani
IPC分类号： G02C7/04 , C07C317/22 , C07C317/32 , C08F20/60 , C08F22/10 , C08F246/00 , C08F299/08 , C09K3/00 , G02B1/04 , C08G75/20
CPC分类号： C08F20/60 , C08F22/105 , G02B1/043
摘要： A novel crosslinkable compound of the formula (I): ##STR1## and an optical material prepared by employing such a crosslinkable compound, which is excellent in hydrophilicity, transparency, ultraviolet light absorbing property, deposit resistance and boiling resistance and yet has proper hardness and oxygen permeability.
摘要翻译： 通式（I）的新型交联性化合物：使用这样的交联性化合物制备的光学材料，其亲水性，透明性，紫外线吸收性，耐沉积性，耐沸腾性优异，并且具有适当的硬度和透氧性。
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