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公开(公告)号：US4289500A
公开(公告)日：1981-09-15
申请号：US142150
申请日：1980-04-21
申请人： Heinrich Weber , Horst Dungs , Karl-Heinz Wollenhaupt , Yves Brasseur , Henri Birscheidt , Franz Beckmann
发明人： Heinrich Weber , Horst Dungs , Karl-Heinz Wollenhaupt , Yves Brasseur , Henri Birscheidt , Franz Beckmann
CPC分类号： C10L5/04
摘要： A method of producing hot briquettes in a plurality of stages comprises heating inert components which do not soften by direct heat exchange with hot carrier gases which are generated in a combustor to a temperature of about from 550.degree. to 700.degree. C. Thereafter the heated inert components and the gases are directed to a first separator to separate the carrier gases from the heated inert components. A caking bituminous binder coal component is then preheated and dried to temperatures of either 60.degree. over or under 300.degree. C. with the separated carrier gas. The binder coal and the separated carrier gas is then directed to a second separator to provide a second separated carrier gas and the heated binder coal. The second heated carrier gas is directed into a third separator in direct heat exchange with a second inert component which is then heated by this to a temperature of from 350.degree. to 600.degree. C. The second inert component is then separated from the second separator carrier gas and directed back for heat exchange with the hot carrier gases in the first separator, both the inert components which are separated and the binder coal are then directed into a mixer for premixing and then subsequently into a roll press for forming them into briquettes.
摘要翻译： 在多个阶段中生产热压块的方法包括通过与在燃烧器中产生的热载气直接热交换至约550℃至700℃的温度而不使软化的惰性组分加热。然后加热的惰性 组分和气体被引导到第一分离器以将载气与加热的惰性组分分离。 然后将结块的沥青粘合剂煤组分预热，并用分离的载气将其干燥至60℃以上或在300℃以下的温度。 然后将粘合剂煤和分离的载气引导到第二分离器以提供第二分离的载气和加热的粘合剂煤。 第二加热的载气被引导到与第二惰性组分直接热交换的第三分离器中，然后将第二惰性组分加热至350℃至600℃的温度。然后将第二惰性组分与第二分离器载体 气体并引导回与第一分离器中的热载气进行热交换，然后将分离的惰性组分和粘结剂煤导入到用于预混合的混合器中，然后进入辊压机中以将它们形成为团块。
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公开(公告)号：US4601728A
公开(公告)日：1986-07-22
申请号：US732757
申请日：1985-04-30
申请人： Horst Dungs , Franz Beckmann , Henri Birscheidt
发明人： Horst Dungs , Franz Beckmann , Henri Birscheidt
摘要： The invention relates to a method of preparing material for hot briquetting by pyrolytic decomposition of bituminous coal in mixture with thermally widely stable substances at a temperature of 450.degree. to 530.degree. C., and to a suitable apparatus for carrying out this method. In a travelling bed reactor, the briquetting material is exposed to the pyrolytic decomposition of the bituminous coal component, and is held in continuous mixing and kneading motion. For this purpose, the briquetting material is moved initially in a rotational mixing and kneading motion predominantly at levels parallel to the plane of the axes of rollers of the briquetting press, during which motion it migrates downwardly by gravity at an average speed of less than 3 centimeters per second, whereupon, at the end of this motion, it is uniformly distributed by a rotational motion over the entire width of the rollers.
摘要翻译： PCT No.PCT / EP84 / 00266 Sec。 371日期：1985年4月30日 102（e）日期1985年4月30日PCT提交1984年9月4日PCT公布。 出版物WO85 / 01061 日期：1985年3月14日本发明涉及一种在450〜530℃的温度下与热稳定物质混合制备沥青煤热解分解材料的方法， 执行这种方法。 在移动床反应器中，压块材料暴露于烟煤组分的热解分解，并保持连续的混合和捏合运动。 为此目的，压块材料最初以旋转混合和捏合运动主要以平行于压块机的辊轴的平面的水平移动，在此期间，其运动通过重力向下移动，平均速度小于3 因此，在该运动结束时，通过辊的整个宽度上的旋转运动均匀分布。
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公开(公告)号：US4142941A
公开(公告)日：1979-03-06
申请号：US832365
申请日：1977-09-12
申请人： Heinrich Weber , Horst Dungs , Klaus Urbye , Franz Beckmann , Hugo Schmauch , Karl H. Flasche
发明人： Heinrich Weber , Horst Dungs , Klaus Urbye , Franz Beckmann , Hugo Schmauch , Karl H. Flasche
摘要： A method of producing blast furnace coke from bituminous coals, particularly coals having poor coking capacities in which the coal to be carbonized is ground, predried or preheated, mixed with binders, compressed or formed into briquets having small mechanical resistances and charged into oven chambers, is characterized by fine coals or fine coal mixtures having a swelling index in mixture according to DIN 51741, smaller than 7, and preferably, below 6, and comprising more than 50% of poorly or non-baking coal having a content of volatile matter in excess of 30% or less than 20% which coals or coal mixtures are ground up to attain asurface per unit mass, according to DIN 66145, of from 400 cm.sup.2 to 1200 cm.sup.2 per gram, and with from 3% to 8% by weight of organic binders, compressing the mixture to form it into a briquet at a temperature range of from 70.degree. C. to 300.degree. C. and charging the compressed briquet into the oven chambers without substantial intermediate cooling in order to carbonize it.
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4.发明授权Apparatus for cooling and dedusting degasification gases escaping from coal degasification chambers 失效用于从煤脱气室排出的除气除气气体的除尘装置
公开(公告)号：US4274924A
公开(公告)日：1981-06-23
申请号：US46619
申请日：1979-06-08
CPC分类号： C10K1/04
摘要： A method of cooling and dedusting degasification gases which escape from coal degasification chambers particularly gases which are obtained in high temperature or low temperature carbonization of bituminous and subbituminous coals and which pass from degasification chambers through risers and bends into collection mains and in the bends or in the collecting mains themselves which comprises directing crude tar having a temperature in excess of 50.degree. C. and lower than 170.degree. C. into the bends and collecting mains either alone or with water added which has a temperature and is of a quantity such that it completely evaporates in the collecting main. An apparatus for carrying out the method includes means for spraying either the tar or the tar plus water into the collecting main containing the degasification gases and passing the gases and the liquids from the main into a cooler to separate the gases and a liquid condensate and the tar oil from the condensate and which includes means for directing the crude tar through a separator for separating the heavy tar from a remaining portion of the tar and further directing the remaining portion through a supply tank and a centrifuge for removing solid matter therefrom.
摘要翻译： 一种从煤脱气室排出的冷却除尘气体的方法，特别是在沥青和次烟煤的高温或低温碳化中获得的气体，并且从脱气室通过立管和弯曲通过收集管和弯管或 收集管路本身，其包括将温度超过50℃并低于170℃的粗焦油引导到弯头中并单独收集干管，或者加入水，其温度和数量使得其 在收集主体中完全蒸发。 用于执行该方法的装置包括用于将焦油或焦油加水喷入含有脱气气体的收集主体中并将气体和液体从主体通入冷却器以分离气体和液体冷凝物的装置，以及 来自冷凝物的焦油，并且其包括用于将粗焦油引导通过分离器的装置，用于将焦油与剩余部分焦油分离，并进一步引导剩余部分通过供应罐和用于从其中除去固体物质的离心机。
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公开(公告)号：US4158550A
公开(公告)日：1979-06-19
申请号：US883512
申请日：1978-03-06
申请人： Heinrich Weber , Horst Dungs , Klaus Urbye , Franz Beckmann , Hugo Schmauch , Karl H. Flasche
发明人： Heinrich Weber , Horst Dungs , Klaus Urbye , Franz Beckmann , Hugo Schmauch , Karl H. Flasche
CPC分类号： C10L5/04
摘要： A method of producing blast furnace coke from bituminous coals, particularly coals having poor coking capacities in which the coal to be carbonized is ground, predried or preheated, mixed with binders, compressed or formed into briquets having small mechanical resistances and charged into oven chambers, is characterized by fine coals or fine coal mixtures having a swelling index in mixture according to DIN 51741, smaller than 7, and preferably, below 6, and comprising more than 50% of poorly or non-baking coal having a content of volatile matter in excess of 30% or less than 20% which coals or coal mixtures are ground up to attain a surface per unit mass, according to DIN 66145, of from 400 cm.sup.2 to 1200 cm.sup.2 per gram, with from 3% to 8% by weight of organic binders, compressing the mixture to form it into a briquet at a temperature range of from 70.degree. C. to 300.degree. C. and charging the compressed briquet into the oven chambers without substantial intermediate cooling in order to carbonize it.
摘要翻译： 一种从烟煤，特别是具有不良焦化能力的煤生产高炉焦炭的方法，其中将要被碳化的煤被研磨，预干燥或预热，与粘合剂混合，压制或形成具有小机械阻力的砖并装入烘箱中， 其特征在于具有根据DIN 51741的混合物的溶胀指数小于7，优选低于6的细煤或细煤混合物，并且包含超过50％的具有挥发性物质含量的不良或非烘焙煤 超过30％或小于20％，这种煤或煤混合物被研磨以达到根据DIN 66145的每单位质量的表面积为400cm 2至1200cm 2 / g，其中3％至8％重量的 有机粘合剂，压缩混合物以在70℃至300℃的温度范围内将其形成成团块，并将压缩的坯料装入烘箱中，而不需要大量的中间冷却，以将碳酸盐 是吧
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6.发明授权
公开(公告)号：US4247365A
公开(公告)日：1981-01-27
申请号：US856039
申请日：1977-12-16
CPC分类号： C10B27/00
摘要： A method of cooling and dedusting degasification gases which escape from coal degasification chambers particularly gases which are obtained in high temperature or low temperature carbonization of bituminous and subbituminous coals and which pass from degasification chambers through risers and bends into collection mains and in the bends or in the collecting mains themselves which comprises directing crude tar having a temperature in excess of 50.degree. C. and lower than 170.degree. C. into the bends and collecting mains either alone or with water added which has a temperature and is of a quantity such that it completely evaporates in the collecting main. An apparatus for carrying out the method includes means for spraying either the tar or the tar plus water into the collecting main containing the degasification gases and passing the gases and the liquids from the main into a cooler to separate the gases and a liquid condensate and the tar oil from the condensate and which includes means for directing the crude tar through a separator for separating the heavy tar from a remaining portion of the tar and further directing the remaining portion through a supply tank and a centrifuge for removing solid matter therefrom.
摘要翻译： 一种从煤脱气室排出的冷却除尘气体的方法，特别是在沥青和次烟煤的高温或低温碳化中获得的气体，并且从脱气室通过立管和弯曲通过收集管和弯管或 收集管路本身，其包括将温度超过50℃并低于170℃的粗焦油引导到弯头中并单独收集干管，或者加入水，其温度和数量使得其 在收集主体中完全蒸发。 用于执行该方法的装置包括用于将焦油或焦油加水喷入含有脱气气体的收集主体中并将气体和液体从主体通入冷却器以分离气体和液体冷凝物的装置，以及 来自冷凝物的焦油，并且其包括用于将粗焦油引导通过分离器的装置，用于将焦油与剩余部分焦油分离，并进一步引导剩余部分通过供应罐和用于从其中除去固体物质的离心机。
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公开(公告)号：US4181502A
公开(公告)日：1980-01-01
申请号：US957702
申请日：1978-11-06
申请人： Heinrich Weber , Horst Dungs , Franz Beckmann
发明人： Heinrich Weber , Horst Dungs , Franz Beckmann
CPC分类号： C10B53/08
摘要： A method of producing form coke, particularly metallurigical coke for a blast furnace, comprises, mixing at least two fine ground coal components, of which one is a non-caking component containing only little of volatile matter and comprises an oil coke, and the other is a caking bituminous coal, and at temperatures corresponding approximately to the softening point of the caking coal component. The mixture is carbonized and pressed to form a briquetted form coke, and the form coke is subsequently hardened.
摘要翻译： 一种生产焦炭，特别是用于高炉的冶金焦炭的方法，包括混合至少两种精细的研磨煤组分，其中一种是仅含少量挥发性物质的非结块组分，并且包含油焦炭，另一种 是一种结块烟煤，并且在大约相当于结块煤组分的软化点的温度下。 将混合物碳化并压制以形成压块型焦炭，随后硬化形式焦炭。
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公开(公告)号：US4908167A
公开(公告)日：1990-03-13
申请号：US323440
申请日：1989-03-14
申请人： Franz Beckmann , Armand Wagner
发明人： Franz Beckmann , Armand Wagner
CPC分类号： C22B1/245 , C04B35/013 , C10L5/06
摘要： Form or pressed bodies, such as briquettes, are made of a mixture including at least two components. A first component is formed by at least one fine grained solid material which does not soften below 800.degree. C. A second component is formed by at least one binding agent that is pyrolytically decomposable. Each of the components has a mean mixing and deformation temperature such that the mean temperature of the first component is above a standard mixing and deforming temperature while the mean temperature of the second component is below the standard temperature. The standard temperature is such that a pyrolysis and degassing performed at the standard temperature does not destroy the binding ability of the second component. The second component constitutes about 15% by weight to about 50% by weight of the total mixture. Further, the second component is at least partly a liquified bituminous material having a mean CCT-value above 20%. With these conditions satisfied, it is assured that solid, heat resistant, carbon containing form bodies can be made of the so prepared mixture without requiring the use of baking hard or bituminous coal and without the need for an expensive follow-up coking. The mixture is continuously maintained in motion while it is being subjected to distillation and pyrolysis, whereby gases are removed from the mixture. As soon as a solidification and coke formation is noticed in the pyrolytically decomposed bituminous material, the form bodies are produced by pressing at temperatures within the range of 460.degree. to 590.degree. C. at conventional pressures.
摘要翻译： 形式或压制体，例如团块，由包括至少两种组分的混合物制成。 第一组分由至少一种在800℃以下不软化的细粒固体材料形成。第二组分由至少一种可热分解的结合剂形成。 每个组件具有平均混合和变形温度，使得第一组分的平均温度高于标准混合和变形温度，而第二组分的平均温度低于标准温度。 标准温度使得在标准温度下进行的热解和脱气不会破坏第二组分的结合能力。 第二组分占总混合物的约15重量％至约50重量％。 此外，第二组分至少部分是具有高于20％的平均CCT值的液化沥青材料。 在满足这些条件的情况下，确保固体，耐热的含碳体形体可以由如此制备的混合物制成，而不需要使用烘烤硬质或烟煤，并且不需要昂贵的后续焦化。 混合物在进行蒸馏和热解时连续保持运动，从而从混合物中除去气体。 在热分解沥青材料中注意到凝固和焦炭形成一旦通过在常规压力下在460℃至590℃的温度下进行压制来制造成形体。
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公开(公告)号：US4846849A
公开(公告)日：1989-07-11
申请号：US104887
申请日：1987-10-06
申请人： Franz Beckmann , Matthias Ferner , Armand Wagner
发明人： Franz Beckmann , Matthias Ferner , Armand Wagner
CPC分类号： C10L5/04
摘要： Fine-grained substances which do not soften below 800.degree. C., such as oil coke, coking duff, pitch coke and/or fine-grained coal with less than 14% volatile constituents, sand, ores, metal oxides, metals or mixtures of such substances, are introduced in at least two places into a carrier gas stream and are thermally heated to 550-650.degree. C. in the solid discharge of a first cyclone. Then the same carrier gas stream heats coking coal amounting to 18-38% of the intended briquettable product material to 200-400.degree. C. in the solid discharge of a second cyclone. The two solid flows are mixed and treated, producing the briquettable material at 500.+-.50.degree. C. The carrier gas stream is produced by the combustion of liquid and/or gaseous fuels with an excess air factor of 2 or more. Thermally inert, low-ash solid fuels, such as oil coke, pitch coke and/or low-ash, fine-grained, low-volatility coal, amounting to 20-40% of the briquetting material, are initially introduced. The oxygen of the excess air is reacted mainly with these initally introduced low-ash solid fuels and their volatile pyrolysis products. Then additional fine-grained, thermally inert substances are introduced into at least one position of the flue stream situated downstream, and are heated before being separated in the first cyclone, while the carrier gas is cooled to a temperature of 750.+-.75.degree. C. before the introduction of the coking coal.
摘要翻译： 未在800℃以下软化的细粒物质，例如油焦炭，焦化渣，沥青焦炭和/或具有少于14％挥发组分的细粒煤，沙，矿石，金属氧化物，金属或混合物 这种物质在至少两个地方被引入载气流中，并且在第一旋风分离器的固体排放物中被热加热至550-650℃。 然后在第二旋风分离器的固体排放物中，同样的载气流将焦炭煤的含量达到预定压块产品材料的18-38％至200-400℃。 将两个固体流混合并处理，在500 +/- 50℃下生产压块材料。通过燃烧具有2或更大的过量空气因子的液体和/或气体燃料来产生载气流。 最初引入了热惰性，低灰分固体燃料，例如油焦炭，沥青焦炭和/或低灰分，细粒度，低挥发性煤，占压块材料的20-40％。 过量空气的氧气主要与这些初始引入的低灰分固体燃料及其挥发性热解产物反应。 然后将另外的细粒度的热惰性物质引入位于下游的烟道的至少一个位置，并在第一旋风分离器之前加热，同时将载气冷却至750 +/- 75℃ C.在引进焦煤之前。
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公开(公告)号：US4765829A
公开(公告)日：1988-08-23
申请号：US905270
申请日：1986-09-08
申请人： Franz Beckmann , Romain Schmit , Armand Wagner
发明人： Franz Beckmann , Romain Schmit , Armand Wagner
摘要： According to the instant invention fine and very fine granular zinc- and lead-containing oxidic byproducts are mixed with thermally inert additives and are hot briquetted with caking coal as a binder at a temperature of 490.degree..+-.40.degree. C. using sufficient carbon to reduce all of the metallic components in the byproducts. Then this mixture is briquetted and heated to more than 700.degree. C. and is maintained at this high temperature for a predetermined time to reduce, that is deoxidize, most of the oxidic components of the briquets, especially zinc, lead, and iron oxides. When the byproducts are not dry, which is standard with a wet scrubbing system for cleaning stack gases, the resultant slurry must be dried before it can be treated according to this invention. The carbon according to the invention is added as fine-granular caking coal in portions of at least 20% by weight. Preferably the portion is between 25% and 35% and up to 40%.
摘要翻译： 根据本发明，将精细且非常细的颗粒状含锌和铅的氧化副产物与热惰性添加剂混合，并在490℃至40℃的温度下用结块煤热压块，使用足够的碳 以减少副产物中的所有金属成分。 然后将该混合物压块并加热至700℃以上，并保持在该高温下预定时间以减少（即，脱氧）砖的大部分氧化组分，特别是锌，铅和氧化铁。 当副产物不干燥时，这是用于清洁堆积气体的湿式洗涤系统的标准配置，所得浆料必须在根据本发明进行处理之前进行干燥。 根据本发明的碳以至少20重量％的部分作为细颗粒结块煤加入。 优选地，该部分在25％至35％和至多40％之间。
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