摘要:
Organometallic compounds and/or metal carbonyls are separated from their solutions in organic media with the aid of semi-permeable membranes made of aromatic polyamides.
摘要:
Organometallic compounds and/or metal carbonyls are separated from their solutions in organic media with the aid of semi-permeable membranes made of aromatic polyamides.
摘要:
A semipermeable membrane is described which comprises a homogeneously miscible polymer blend of an aromatic polyamide and polyvinylpyrrolidone. The aromatic polyamide is in particular formed of recurrent units of the formula I: ##STR1## wherein E.sup.1 and E.sup.2 are identical or different and are selected from the groupings ##STR2## --AR.sup.1 --, and --AR.sup.1 --X--AR.sup.2,where AR.sup.1 and Ar.sup.2 are the same or different 1,2-phenylene, 1,3-phenylene or 1,4-phenylene groups which may be substituted by (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy, --CF.sub.3 or halogen and X denotesa) a direct bond or one of the following divalent groups: --O--, --C(CF.sub.3).sub.2 --, --SO.sub.2 --, --C(R.sup.1).sub.2 --, with R.sup.1 being hydrogen, (C.sub.1 -C.sub.6)-alkyl or fluoroalkyl having from 1 to 4 carbon atoms in the alkyl group or--Z--AR.sup.1 --Z--, where Z is one of the groups --O-- and --C(CH.sub.3).sub.2 or--O--Ar.sup.1 --Y--Ar.sup.2 --O--, where Y has the meaning given under Xa) above.The membrane has pronouned hydrophilic properties and is moreover stable to hydrolyzing agents and oxidants and to the action of heat. It is also resistant to organic solvents and microorganisms and exhibits low adsorption of proteins. A process for producing the membrane and a process for modifying the retention capacity thereof are also described. The membrane is produced by spreading a solution of the homogeneously miscible polymer blend on a planar substrate and precipitating the blend. Retention capacity is modified by heat treatment.
摘要:
The present invention relates to a process for the preparation of oxymethylene polymers as well as oxymethylene polymers obtainable therefrom. The process includes polymerization of a monomer, which forms —CH2—O— units in the presence of an acetal of formaldehyde or a polyhydric alcohol and an initiator for cationic polymerization. The initiator may be a heteropoly acid or an acid salt thereof which is dissolved in an alkyl ester of a polybasic carboxylic acid.
摘要:
Oxymethylene polymers having a bimodal distribution or having a distribution of higher modality and having a targeted content of a low molecular weight fraction of from 1 to 5 percent by mass are described. Moldings of these polymers are distinguished by high low-temperature notched impact strength associated with a high modulus of elasticity.
摘要:
An apparatus is described for preparation of oxymethylene homo- and copolymers. This encompasses heterogeneous polymerization of a monomer which forms oxymethylene groups in the presence of an acetal of formaldehyde and of an initiator for cationic polymerization, followed by the deactivation of the polymer in a homogeneous phase via treatment with a basic aprotic solvent or with an aprotic solvent which comprises a base. Oxymethylene homopolymers with very high stability are also described.
摘要:
An apparatus for preparing formaldehyde from methanol by dehydrogenation in a reactor in the presence of a catalyst at a temperature in the range from 300 to 1000° C., a carrier gas stream which has a temperature above the dehydrogenation temperature is fed to the reactor.
摘要:
The invention concerns a process for preparing linear or branched sulphurous polymers such as polyarylene sulphides, in particular polyphenylene sulphide, from an aromatic dihalide compound and a sulphide in a solvent, wherein a) the aromatic dihalide compound and the sulphide are partially reacted; b) the resultant salt which is not dissolved in the reaction medium is separated off; and c) the reaction mixture largely freed of the salt is further polymerized.
摘要:
Oxymethylene polymers having a bimodal distribution or having a distribution of higher modality and having a targeted content of a low molecular weight fraction of from 1 to 5 percent by mass are described. Moldings of these polymers are distinguished by high low-temperature notched impact strength associated with a high modulus of elasticity.
摘要:
An initiator for cationic polymerization comprises a salt of a protic acid as well as a protic add. The molar ratio of protic acid to salt is in the range from 1:0.01 to 1:2000. The initiator is used for example for cationic homo- or copolymerization of trioxane, and permits stable and flexible operation of the polymerization.