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    Substituted 5-aminopyrazoles
    2.
    发明授权
    Substituted 5-aminopyrazoles 失效

    公开(公告)号：US5486618A

    公开(公告)日：1996-01-23

    申请号：US70386

    申请日：1993-06-07

    申请人： Helmut Hagen ,  Gerhard Nilz ,  Helmut Walter ,  Andreas Landes

    发明人： Helmut Hagen ,  Gerhard Nilz ,  Helmut Walter ,  Andreas Landes

    IPC分类号： A01N43/56 ,  A01N25/32 ,  C07D231/38 ,  C07D231/40 ,  C07D309/12 ,  C07D335/02 ,  C07D403/04 ,  C07D231/00

    CPC分类号： C07D403/04 ,  A01N25/32 ,  C07D231/40

    摘要： Substituted 5-aminopyrazoles I ##STR1## where R.sup.1 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -hydroxyalkyl, phenyl which may carry 1-3 of the following radicals: halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or --NR.sup.6 R.sup.7, and which may additionally carry a number of halogen atoms so that the total number of radicals is 5, R.sup.6 and R.sup.7 are each H or C.sub.1 -C.sub.4 -alkyl, R.sup.2 is H, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl, R.sup.3 is CN, --CO--R.sup.8 or --CS--R.sup.8, R.sup.8 is OH, C.sub.1 -C.sub.4 -alkoxy, NH.sub.2, C.sub.1 -C.sub.4 -alkylamino or di-C.sub.1 -C.sub.4 -alkylamino, R.sup.4 and R.sup.5 are each H, C.sub.1 -C.sub.4 -alkyl, PX(OR.sup.9).sub.2, --SO.sub.2 --R.sup.9, --CX--R.sup.10, --CX--NH--CY--R.sup.9 or CX--NH--SO.sub.2 --R.sup.11, X and Y are each O or S, R.sup.9 is one of the substituents R.sup.1, R.sup.10 is C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.4 -alkoxy, unsubstituted or substituted phenyl or unsubstituted or substituted NH.sub.2, R.sup.11 is NH.sub.2, C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, pyrrolidinyl, piperidinyl or morpholinyl, R.sup.4 and R.sup.5 together form a group .dbd.CR.sup.12 R.sup.13 or --CO--W--CO--, R.sup.12 is H, NH.sub.2, C.sub.1 -C.sub.4 -alkylamino or C.sub.3 -C.sub.8 -cycloalkylamino, R.sup.13 is NH.sub.2, C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.3 -C.sub.8 -cycloalkylamino, pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl and W is an unsubstituted or substituted ethylene or ethenylene bridge, an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded aromatic or heteroaromatic bridge, or an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge,and the basic salts of the compounds I in which R.sup.3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom,with the exception of 1-phenyl- and 1-methyl-4-cyano-5-acylaminopyrazole, 1-methyl-4-cyano-5-(chloromethylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(phenylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(p-chlorophenylcarbonylamino)-pyrazole and the compounds I in which R.sup.1 is methyl, phenyl, 4-chlorophenyl or 4-nitrophenyl, R.sup.2 is hydrogen, methyl or trifluoromethyl, R.sup.3 is cyano and R.sup.4 and R.sup.5 are simultaneously hydrogen, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and substituted 5-aminopyrazoles I' or, in the case of acidic terminal groups or basic nitrogen atoms, the salts of I' as antidotes.

    Herbicides containing substituted 2-aminothiophenes
    4.
    发明授权
    Herbicides containing substituted 2-aminothiophenes 失效

    公开(公告)号：US5422335A

    公开(公告)日：1995-06-06

    申请号：US70389

    申请日：1993-06-07

    申请人： Helmut Hagen ,  Gerhard Nilz ,  Helmut Walter ,  Andreas Landes

    发明人： Helmut Hagen ,  Gerhard Nilz ,  Helmut Walter ,  Andreas Landes

    IPC分类号： A01N25/32 ,  A01N35/06 ,  A01N39/02 ,  A01N43/10 ,  C07D333/38 ,  C07D333/68 ,  C07D333/70 ,  C07D409/04 ,  C07D409/12 ,  C07D417/12 ,  A01N43/12 ,  A01N47/24 ,  C07D333/54

    CPC分类号： C07D409/04 ,  A01N25/32 ,  C07D333/38 ,  C07D333/68 ,  C07D409/12 ,  C07D417/12

    摘要： A herbicidal composition containing one or more substituted 2-aminothiophenes of the formula I ##STR1## where R.sup.1 and R.sup.2 together from a C.sub.4 -alkylene chain to which a benzene ring may be fused,R.sup.3 is --CN or CX--R.sup.6, where R.sup.6 is hydroxyl, C.sub.1 -C.sub.4 -alkoxy or amino,R.sup.4 is hydrogen or a phenyl group which may carry one or two nitro radicals,--PO(OR.sup.8).sub.2, --CX--R.sup.9, --SO.sub.2 R.sup.10, --CX--N(H) --CO--R.sup.8 or --CX--N(R.sup.7)--SO.sub.2 --R.sup.11,whereR.sup.8 is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl groupR.sup.9 is C.sub.1 -C.sub.20 -alkyl, partially or completely halogenated C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.6 -cycloalkyl, or amino, C.sub.1 -C.sub.4 -alkylamino, C.sub.3 -C.sub.8 -cycloalkylamino, phenyl or phenylamino, where the aromatic moiety may carry at least one of nitro and halogen;R.sup.10 is C.sub.1 -C.sub.4 -alkyl or phenyl, which may carry one C.sub.1 -C.sub.4 -alkyl radical;R.sup.11 is pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl or piperazin-1-yl, where the heterocyclic structures may carry one C.sub.1 -C.sub.4 -group;R.sup.5 is hydrogen;orR.sup.4 and R.sup.5 together form a group .dbd.CR.sup.12 R.sup.13 or --CO--W--CO--, where R.sup.12 is hydrogen, amino, C.sub.1 -C.sub.4 -alkylamino or C.sub.3 -C.sub.8 -cycloalkylamino;R.sup.13 is amino, C.sub.3 -C.sub.8 -cycloalkylamino, phenyl or pyridyl, where the two last mentioned substituents may carry at least one halogen or nitro radicals;W is an ethylene or ethenylene bridge, or a 6-membered 1,2-C-bonded aromatic bridge where these bridge members may carry, on each substitutable carbon atom, at least one halogena 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge,and the basic salts of the compounds I in which R.sup.3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom, as antagonistic compoundsand one or more herbicidal active ingredients from the group consisting ofthe cyclohexenone derivatives of the formula III ##STR2##

    Cyanoquinoline compounds
    6.
    发明授权
    Cyanoquinoline compounds 失效
    氰基喹啉化合物

    公开(公告)号：US5565408A

    公开(公告)日：1996-10-15

    申请号：US423325

    申请日：1995-04-17

    申请人： Helmut Hagen ,  Juergen Pfister ,  Gunter Brill ,  Gerhard Nilz ,  Bruno Wuerzer ,  Karl-Otto Westphalen

    发明人： Helmut Hagen ,  Juergen Pfister ,  Gunter Brill ,  Gerhard Nilz ,  Bruno Wuerzer ,  Karl-Otto Westphalen

    IPC分类号： A01N43/42 ,  A01N25/32 ,  C07D215/48 ,  C07D215/50 ,  C07D215/54 ,  C07D215/56 ,  C07D401/04 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D413/04 ,  C07D413/14 ,  C07D417/04 ,  C07D215/28 ,  A01N43/40 ,  C07D215/26

    CPC分类号： C07D401/04 ,  A01N25/32 ,  C07D215/48 ,  C07D215/54 ,  C07D215/56 ,  C07D401/12

    摘要： Cyanoquinoline compounds Ia or Ib ##STR1## where R.sup.1 is CH.dbd.C(CN).sub.2 ; CH.dbd.N--N.dbd.CH--(5-quinolyl); methylsulfonyl; CH.dbd.NOH; halogen; hydroxyl; nitro; cyano; unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio, pyrrolidinyl; piperidinyl; morpholinyl; thiomorpholinyl; unsubstituted or substituted phenyl, phenoxy, phenylthio, phenyldithiolyl, phenylsulfonyl or pyrrolyl;m is 0, 1, 2 or 3;R.sup.2 is hydrogen; hydroxyl; halogen; C.sub.1 -C.sub.4 -alkoxy; --NR.sup.3 R.sup.4 ; --NR.sup.5 --CXR.sup.6 or --N.dbd.CR.sup.7 R.sup.8 ;R.sup.3 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl;R.sup.4 is a radical R.sup.3 ; C.sub.1 -C.sub.4 -alkylamino; di-C.sub.1 -C.sub.4 -alkylamino; substituted C.sub.1 -C.sub.4 -alkyl; CH.dbd.N--(3-cyano-2-quinolinyl); or R.sup.3 and R.sup.4 together form C.sub.4 - or C.sub.3 -alkylene which may be interrupted by a hetero atom, or unsubstituted or substituted 1,3-butadienyl;R.sup.5 and R.sup.7 are each hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.6 and R.sup.8 are each a radical R.sup.5 ; substituted C.sub.1 -C.sub.4 -alkyl; C.sub.3 -C.sub.7 -cycloalkyl; C.sub.1 -C.sub.4 -alkoxycarbonyl; unsubstituted or substituted phenyl or unsubstituted or substituted amino, andX is oxygen or sulfur,processes for their preparation and herbicides which contain them.

    摘要翻译： 氰基喹啉化合物Ia或Ib其中R 1是CH = C（CN）2; CH = N-N = CH-（5-喹啉基）; 甲基磺酰基; CH = NOH; 卤素; 羟; 硝基 氰基; 未取代或取代的C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷硫基，吡咯烷基; 哌啶基; 吗啉基 硫代吗啉基; 未取代或取代的苯基，苯氧基，苯硫基，苯基二硫代基，苯基磺酰基或吡咯基; m为0,1,2或3; R2是氢; 羟; 卤素; C1-C4-烷氧基; -NR3R4; -NR5-CXR6或-N = CR7R8; R3是氢或未取代的或取代的C1-C4-烷基; R4是一个基团R3; C 1 -C 4烷基氨基; 二-C 1 -C 4烷基氨基; 取代的C 1 -C 4 - 烷基; CH = N-（3-氰基-2-喹啉基）; 或者R 3和R 4一起形成可以被杂原子间隔的C4-或C3-亚烷基，或未取代或取代的1,3-丁二烯基; R5和R7各自为氢或C1-C4-烷基; R6和R8各自为基团R5; 取代的C 1 -C 4 - 烷基; C 3 -C 7 - 环烷基; C 1 -C 4烷氧基羰基; 未取代或取代的苯基或未取代或取代的氨基，X为氧或硫，其制备方法和含有它们的除草剂。

    2-amino-4-trichloropyridine derivatives
    7.
    发明授权
    2-amino-4-trichloropyridine derivatives 失效
    2-氨基-4-三氯吡啶衍生物

    公开(公告)号：US5216171A

    公开(公告)日：1993-06-01

    申请号：US681254

    申请日：1991-04-08

    申请人： Helmut Hagen ,  Hans Ziegler ,  Juergen Pfister ,  Gerhard Nilz ,  Gisela Lorenz ,  Juergen Dressel

    发明人： Helmut Hagen ,  Hans Ziegler ,  Juergen Pfister ,  Gerhard Nilz ,  Gisela Lorenz ,  Juergen Dressel

    IPC分类号： C05G3/08 ,  C07D213/74 ,  C07D213/75 ,  C07D213/76 ,  C07D401/04 ,  C07F9/58

    CPC分类号： C07D213/74 ,  C07D213/75 ,  C07D213/76 ,  C07D401/04 ,  C07F9/588 ,  Y02P60/218 ,  Y10S106/90

    摘要： 2-Amino-4-trichloromethylpyridines of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.2 is C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.4 -alkenyl or phenyl, benzyl or phenylsulfonyl,--CX--R.sup.3, --SO.sub.2 R.sup.3 or --PX(OR.sup.4).sub.2 orR.sup.1 and R.sup.2 together form .dbd.CR.sup.5 R.sup.6 or --CO--Z--CO--,X is oxygen or sulfur,R.sup.3 is C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.6 -alkenyl, amino, C.sub.1 -C.sub.6 -alkylamino, di-C.sub.1 -C.sub.6 -alkylamino, morpholino, piperidino, pyrazolidino or C.sub.1 -C.sub.8 -alkylcarbonylamino, substituted or unsubstituted phenylamino or benzylamino,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl or substituted or unsubstituted phenyl,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl, or substituted or unsubstituted phenyl,R.sup.6 is substituted or unsubstituted phenyl,Z is substituted or unsubstituted ethylene which may be part of a substituted or unsubstituted cycloalkyl or cycloalkylene radical, substituted or unsubstituted ethenylene which may be part of a substituted or unsubstituted aromatic or heteroaromatic ring, and Z is not part of an unsubstituted phenyl radical, agriculturally useful salts thereof, processes for their preparation and the use thereof as nitrification inhibitors.

    摘要翻译： 通式I的2-氨基-4-三氯甲基吡啶其中R1是氢或C1-C8-烷基，R2是C1-C8-烷基，C5-C8-环烷基，C2-C4-烯基或苯基，苄基 或苯基磺酰基，-CX-R3，-SO2R3或-PX（OR4）2或R1和R2一起形成= CR5R6或-CO-Z-CO-，X是氧或硫，R3是C1-C20-烷基，C2- C 1 -C 6 - 烯基，氨基，C 1 -C 6 - 烷基氨基，二-C 1 -C 6烷基氨基，吗啉代，哌啶子基，吡唑烷基或C 1 -C 8烷基羰基氨基，取代或未取代的苯基氨基或苄基氨基，R 4是C 1 -C 8烷基， 卤代烷基或取代或未取代的苯基，R 5是氢，C 1 -C 4烷基或取代或未取代的苯基，R 6是取代或未取代的苯基，Z是可以是取代或未取代的环烷基或环亚烷基的一部分的取代或未取代的乙烯 取代或未取代的亚乙烯基，其可以是取代或未取代的芳族或杂芳族环的一部分，Z不是未取代的苯基的一部分，农业 其文化上有用的盐，其制备方法及其作为硝化抑制剂的用途。