2,3-substituted 1,8-naphthyridines, their preparation and their use as
antidotes
    1.
    发明授权
    2,3-substituted 1,8-naphthyridines, their preparation and their use as antidotes 失效
    2,3-取代的1,8-萘啶,其制备及其作为抗体使用

    公开(公告)号:US5059240A

    公开(公告)日:1991-10-22

    申请号:US486867

    申请日:1990-03-01

    摘要: 2,3-substituted 1,8-naphthyridines of the general formula I ##STR1## where: R is hydrogen or C.sub.1 -C.sub.4 -alkyl (n=1 or 2)R.sup.1 is amino or substituted amino,XR.sup.5, where X is oxygen or sulfur and R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-((C.sub.1 -C.sub.4)-alkyl, C.sub.5 -C.sub.8 -cycloakyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl-(C.sub.1 -C.sub.3)-alkyl,halogen,isothiorhonium halide,C.sub.1 -C.sub.12 -alkyl,C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.4 -alkyl,substituted or unsubstituted phenyl or phenyl-(C.sub.1 -C.sub.3)-alkyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, cyano, carboxyl or a group ##STR2## where X is oxygen or sulfur,B is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or alkylthio, amino, mono- or dialkylamino, where each alkyl radical is of 1 to 4 carbon atoms, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl,D is C.sub.1 -C.sub.4 alkyl or NH.sub.2 andR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or alkylcarbonyl,or R.sup.1 and R.sup.2 together are --NH--N.dbd.C(CH.sub.2)--,and their environmentally tolerated saltswith the proviso that R.sup.2 is not cyano, carboxyl or a carboxamido or carboxylic ester group when R.sup.1 is methyl, hydroxyl or amino (NH.sub.2), processes for their manufacture, and herbicidal agents containing a naphthyridine I as safener and at least one herbicidal active ingredient selected from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives andb) cyclohexenone derivatives.

    摘要翻译: 具有通式I的2,3-取代的1,8-萘啶,其中:R是氢或C 1 -C 4 - 烷基(n = 1或2)R 1是氨基或取代的氨基,XR 5,其中X是氧 或(C 1 -C 4) - 烷基,C 5 -C 8 - 环烷基,取代或未取代的苯基,取代或未取代的苯基 - (C 1 -C 3) - 烷基,卤素,异卤卤化物,C 1 -C 12 - 烷基,C 1 -C 4 - 烷氧基羰基-C 1 -C 4烷基,取代或未取代的苯基或苯基 - (C 1 -C 3) - 烷基,R 2为C 1 -C 4烷基,氰基, 羧基或基团,其中X为氧或硫,B为C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基或烷硫基,氨基,单或二烷基氨基,其中每个烷基为1至4个碳原子,吗啉代 ,哌啶基,氯,溴或取代或未取代的苯基,D是C 1 -C 4烷基或NH 2,R 6是氢,C 1 -C 8 - 烷基或烷基羰基,或者R 1和R 2一起是-NH-N = C(CH 2) 其环境耐受性盐,条件是R2不是氰基,羧基或a 当R1是甲基,羟基或氨基(NH2)时,羧酰胺基或羧酸酯基,其制备方法和含有萘啶I作为安全剂的除草剂和至少一种除草活性成分,其选自a)2-(4 - 杂芳氧基) - 或2-(4-芳氧基) - 苯氧基乙酸衍生物和b)环己烯酮衍生物。

    Novel 4'(benzisothiazo-5-yloxy)-phenylurea derivatives, their
preparation and their use as herbicides
    2.
    发明授权
    Novel 4'(benzisothiazo-5-yloxy)-phenylurea derivatives, their preparation and their use as herbicides 失效
    新型4'(苯并异噻唑-5-基氧基) - 苯基脲衍生物,其制备及其作为除草剂的用途

    公开(公告)号:US4589910A

    公开(公告)日:1986-05-20

    申请号:US727628

    申请日:1985-04-30

    CPC分类号: C07D275/04 A01N47/30

    摘要: A 4'-(Benzisothiazol-5-yloxy)-phenylureas of the formula ##STR1## where R.sup.1 and R.sup.2 are each a saturated straight-chain or branched aliphatic radical of 1 to 10 carbon atoms, an unsaturated straight-chain or branched aliphatic radical of 3 to 10 carbon atoms, or an araliphatic or aromatic radical which may be substituted by 1, 2 or 3 C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, cyano, halogen, nitro, monofluoromethyl or trifluoromethyl groups, or are each alkoxy of 1 to 6 carbon atoms, R.sup.2 may furthermore be hydrogen, or R.sup.1 and R.sup.2, together with the nitrogen atom, may be members of a 5-membered or 6-membered ring which may contain further nitrogen and/or oxygen atoms as heteroatoms, and X is hydrogen, trifluoromethyl or chlorine, processes for their preparation, and herbicides containing ureas of the formula I as active ingredients.

    摘要翻译: 式Ⅰ的4' - (苯并异噻唑-5-基氧基) - 苯基,其中R 1和R 2各自是1-10个碳原子的饱和直链或支链脂族基团,不饱和直链或支链脂族基 或可被1,2或3个C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,氰基,卤素,硝基,单氟甲基或三氟甲基取代的芳脂族或芳族基团,或各自为 具有1至6个碳原子的烷氧基,R 2还可以是氢,或者R 1和R 2与氮原子一起可以是可以含有另外的氮原子和/或氧原子作为杂原子的5元或6元环的成员 ,X为氢,三氟甲基或氯,其制备方法,以及含有式I的脲的除草剂作为活性成分。

    2-amino-4-trichloropyridine derivatives
    3.
    发明授权
    2-amino-4-trichloropyridine derivatives 失效
    2-氨基-4-三氯吡啶衍生物

    公开(公告)号:US5216171A

    公开(公告)日:1993-06-01

    申请号:US681254

    申请日:1991-04-08

    摘要: 2-Amino-4-trichloromethylpyridines of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.2 is C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.4 -alkenyl or phenyl, benzyl or phenylsulfonyl,--CX--R.sup.3, --SO.sub.2 R.sup.3 or --PX(OR.sup.4).sub.2 orR.sup.1 and R.sup.2 together form .dbd.CR.sup.5 R.sup.6 or --CO--Z--CO--,X is oxygen or sulfur,R.sup.3 is C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.6 -alkenyl, amino, C.sub.1 -C.sub.6 -alkylamino, di-C.sub.1 -C.sub.6 -alkylamino, morpholino, piperidino, pyrazolidino or C.sub.1 -C.sub.8 -alkylcarbonylamino, substituted or unsubstituted phenylamino or benzylamino,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl or substituted or unsubstituted phenyl,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl, or substituted or unsubstituted phenyl,R.sup.6 is substituted or unsubstituted phenyl,Z is substituted or unsubstituted ethylene which may be part of a substituted or unsubstituted cycloalkyl or cycloalkylene radical, substituted or unsubstituted ethenylene which may be part of a substituted or unsubstituted aromatic or heteroaromatic ring, and Z is not part of an unsubstituted phenyl radical, agriculturally useful salts thereof, processes for their preparation and the use thereof as nitrification inhibitors.

    摘要翻译: 通式I的2-氨基-4-三氯甲基吡啶其中R1是氢或C1-C8-烷基,R2是C1-C8-烷基,C5-C8-环烷基,C2-C4-烯基或苯基,苄基 或苯基磺酰基,-CX-R3,-SO2R3或-PX(OR4)2或R1和R2一起形成= CR5R6或-CO-Z-CO-,X是氧或硫,R3是C1-C20-烷基,C2- C 1 -C 6 - 烯基,氨基,C 1 -C 6 - 烷基氨基,二-C 1 -C 6烷基氨基,吗啉代,哌啶子基,吡唑烷基或C 1 -C 8烷基羰基氨基,取代或未取代的苯基氨基或苄基氨基,R 4是C 1 -C 8烷基, 卤代烷基或取代或未取代的苯基,R 5是氢,C 1 -C 4烷基或取代或未取代的苯基,R 6是取代或未取代的苯基,Z是可以是取代或未取代的环烷基或环亚烷基的一部分的取代或未取代的乙烯 取代或未取代的亚乙烯基,其可以是取代或未取代的芳族或杂芳族环的一部分,Z不是未取代的苯基的一部分,农业 其文化上有用的盐,其制备方法及其作为硝化抑制剂的用途。

    Thiolphosphoric acid-S-4-nitro-2-trichloromethylphenyl esters as
fungicides
    8.
    发明授权
    Thiolphosphoric acid-S-4-nitro-2-trichloromethylphenyl esters as fungicides 失效
    硫代磷酸-S-4-硝基-2-三氯甲基苯基酯作为杀真菌剂

    公开(公告)号:US4301157A

    公开(公告)日:1981-11-17

    申请号:US81060

    申请日:1979-10-02

    CPC分类号: A01N57/14 C07F9/18

    摘要: New thiolphosphoric acid-S-4-nitro-2-trichloromethylphenyl esters of the formula ##STR1## where X denotes oxygen or sulfur, and R.sup.1 and R.sup.2 are identical or different and each denotes a substituted or unsubstituted aliphatic radical of 1 to 18 carbon atoms or a substituted or unsubstituted alicyclic radical of 5 to 18 carbon atoms, processes for their manufacture, fungicides containing these compounds as active ingredients, their manufacture, and processes for combating fungi with these novel compounds.

    摘要翻译: 式中,X表示氧或硫的新型硫醇磷酸-S-4-硝基-2-三氯甲基苯基酯,R 1和R 2相同或不同,表示1〜18个碳原子的取代或未取代的脂肪族基团 或5〜18个碳原子的取代或未取代的脂环族基团,其制造方法,含有这些化合物作为活性成分的杀真菌剂,其制造方法以及使用这些新化合物对抗真菌的方法。