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公开(公告)号：US4207386A
公开(公告)日：1980-06-10
申请号：US35269
申请日：1979-05-01
申请人： Henner Meinhold , Wilhelm Haar , Wilfried Fischer
发明人： Henner Meinhold , Wilhelm Haar , Wilfried Fischer
CPC分类号： H01M2/348 , H01M10/3909 , H01M2/34 , H01H37/761
摘要： Electrochemical storage cell of the alkali metal and chalcogen type with an anode and a cathode chamber separated by a solid electrolyte wall and confined by a metal wall. A first current collector has an outer sub-part which extends outside the reactant chamber enclosed by the solid electrolyte, and an inner sub-part which extends into the interior of this reactant chamber. The outer sub-part and the inner sub-part are connected to an electrically conducting contact element which melts at a predetermined temperature exceeding the operating temperature of the cell. A second current collector is formed by part of the metal wall which confines the other reactant chamber.
摘要翻译： 碱金属和硫族元素类型的电化学存储电池，阳极和阴极室由固体电解质壁隔开并被金属壁限制。 第一集电器具有外部子部分，其延伸到由固体电解质包围的反应物室的外部，以及延伸到该反应物室的内部的内部子部件。 外部子部分和内部子部分连接到导电接触元件，其在超过电池的工作温度的预定温度下熔化。 第二集电器由限定另一反应物室的金属壁的一部分形成。
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公开(公告)号：US4206272A
公开(公告)日：1980-06-03
申请号：US33808
申请日：1979-04-27
申请人： Wilfried Fischer , Wilhelm Haar , Henner Meinhold
发明人： Wilfried Fischer , Wilhelm Haar , Henner Meinhold
CPC分类号： H01M10/3909 , H01M10/42
摘要： Electrochemical storage cell with an anode chamber and a cathode chamber separated by a solid electrolyte. At least one of the chamber adjacent to the solid electrolyte and a supply chamber shield from both the solid electrolyte and the reaction chamber. At least one connected between the reaction chamber and the supply chamber for flow of reactants, and temperature controlled shut-off means for closing off the connection when a predetermined temperature above the operating temperature of the cell is reached.
摘要翻译： 具有由固体电解质分离的阳极室和阴极室的电化学蓄电池。 与固体电解质相邻的室中的至少一个和供应室与固体电解质和反应室两者屏蔽。 连接在反应室和供应室之间的至少一个用于反应物流动的温度控制关闭装置，用于当达到高于电池工作温度的预定温度时关闭连接。
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公开(公告)号：US4216275A
公开(公告)日：1980-08-05
申请号：US915132
申请日：1978-06-13
申请人： Bernd Hartmann , Wilhelm Haar , Wilfried Fischer , Roland Bauer
发明人： Bernd Hartmann , Wilhelm Haar , Wilfried Fischer , Roland Bauer
CPC分类号： H01M4/661 , H01M10/3909
摘要： An electrochemical storage cell or battery with one anode chamber containing molten alkali metal as the anolyte and one cathode chamber containing sulfur-containing catholyte substance, the anolyte and catholyte separated by an alkali-ion-conducting solid electrolyte. The cathode chamber is bounded by a cellwall having a protective layer of a light weight metal also serving as a current collector. The light weight metal in the regions in contact with the catholyte is coated with a metallic alloy which under conditions of operation has certain properties of adhesion, conduction, resistance, corrosion and solubility.
摘要翻译： 一种具有一个阳极室的电化学蓄电池或电池，其中含有熔融碱金属作为阳极电解液，一个阴极室含有含硫阴极电解质物质，阳极电解液和阴极电解液由碱 - 离子导电固体电解质分离。 阴极室由具有也用作集电器的轻质金属的保护层的电池墙限定。 在与阴极电解液接触的区域中的轻质金属涂覆有金属合金，其在操作条件下具有一定的粘附性，导电性，耐性，腐蚀性和溶解性。
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公开(公告)号：US4146684A
公开(公告)日：1979-03-27
申请号：US817491
申请日：1977-07-20
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： An electrochemical storage cell or battery based on an alkali metal and sulfur having at least one anode chamber and at least one cathode chamber separated from each other by an ion-conducting solid electrolyte, and felt with course-pores and/or low electric conductivity and felt with fine-pores and/or higher electric conductivity located in the cathode chamber, with the felt of coarse-pores and/or low conductivity disposed near the solid electrolyte and the felt of fine-pores and/or higher conductivity disposed further away from the solid electrolyte. This permits rapid and more complete recharging of the cell for covering peak loads in electrical networks.
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公开(公告)号：US4184013A
公开(公告)日：1980-01-15
申请号：US972285
申请日：1978-12-22
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： An electrochemical storage cell or battery with at least one anode filled with a molten alkali metal as the anolyte and at least one cathode chamber filled with a sulfur-containing catholyte substance with the anode chamber and the cathode chamber separated from each other by an alkali-ion-conducting solid electrolyte. To the catholyte substance is added an additive which converts the sulfur chains into an electrically charged state for obtaining electromigration of the sulfur phase. This induces mobilization of the sulfur phase in the cathode chamber and prevents major accumulation of liquid sulfur as an insulator. As a result the cell can be repeatedly recharged with large currents to a greater capacity. Additives are a dienophilic compound or a reaction product of a dienophilic compound and sulfur.
摘要翻译： 一种具有填充有作为阳极电解液的熔融碱金属的至少一个阳极和填充有含硫阴极电解质物质的至少一个阴极室的电化学蓄电池或电池，阳极室和阴极室通过碱 - 离子导电固体电解质。 向阴极电解质物质中加入一种将硫链转化为带电状态以获得硫相的电迁移的添加剂。 这导致硫相在阴极室中的动员并且防止液体硫作为绝缘体的主要积聚。 结果，电池可以用大电流反复充电到更大的容量。 添加剂是二亲性化合物或二亲性化合物和硫的反应产物。
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公开(公告)号：US4127705A
公开(公告)日：1978-11-28
申请号：US817379
申请日：1977-07-20
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： An electrochemical storage cell or battery based on an alkali metal and sulfur having at least one anode chamber and at least one cathode chamber separated from each other by an ion-conducting solid electrolyte, a felt fabric with capillary activity located in the cathode chamber, and an additive lowering the viscosity of the sulfur in the cathode chamber. Preferred additives are selenium, boron and iodine. Lowering the viscosity of the sulfur permits recharging the cell to a greater capacity.
摘要翻译： 一种基于碱金属和硫的电化学存储单元或电池，具有至少一个阳极室和至少一个阴离子室，所述至少一个阴极室由离子传导固体电解质彼此分开，毛细管活性位于阴极室中的毛毡织物，以及 降低阴极室中硫的粘度的添加剂。 优选的添加剂是硒，硼和碘。 降低硫的粘度允许将电池充电到更大的容量。
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公开(公告)号：US4029857A
公开(公告)日：1977-06-14
申请号：US638174
申请日：1975-12-05
CPC分类号： H01M10/3909
摘要： Electrochemical storage cell or battery based on sodium and sulfur having an anode chamber and a cathode chamber separated from each other by a dividing wall capable of conducting sodium ions, is provided with a screening electrode disposed in the chamber containing sulfur as a reactant between the dividing wall and the outer cell wall of said chamber to electrically screen the cell wall and thereby minimize corrosion of the cell wall.
摘要翻译： 具有通过能够进行钠离子的分隔壁彼此隔开的阳极室和阴极室的基于钠和硫的电化学储存电池或电池设置有设置在室内的屏蔽电极，其中含有作为反应物的硫分隔 壁和所述室的外细胞壁以电屏蔽细胞壁，从而使细胞壁的腐蚀最小化。
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公开(公告)号：US5141687A
公开(公告)日：1992-08-25
申请号：US534047
申请日：1990-06-06
申请人： Wilhelm Haar , Guido Weber , Alois Lechner
发明人： Wilhelm Haar , Guido Weber , Alois Lechner
CPC分类号： F27D5/00 , C04B35/44 , F27B21/04 , H01M10/3918
摘要： A sintering device for the production of cupular solid electrolytes, which are used to separate anode and cathode compartments in sodium-sulphur cells, is in the form of a jacket tube and is produced from two or more metal oxides or metal hydroxides. The device and method avoid the disadvantages of the prior art sintering devices that are costly to manufacture and in most cases destroy the uniform distribution of the sodium within the soilid electrolyte material.
摘要翻译： 用于制备用于分离钠 - 硫电池中的阳极和阴极隔室的杯状固体电解质的烧结装置是夹套管的形式，由两种或多种金属氧化物或金属氢氧化物制成。 该装置和方法避免了制造成本高的现有技术烧结装置的缺点，并且在大多数情况下破坏了钠在污垢电解质材料内的均匀分布。
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公开(公告)号：US4413043A
公开(公告)日：1983-11-01
申请号：US293886
申请日：1981-08-18
申请人： Gunther Steinleitner , Wilhelm Haar
发明人： Gunther Steinleitner , Wilhelm Haar
摘要： Electrochemical chemical storage cell or battery of the alkali metal and chalcogen type with an anode space and a cathode separated from each other by an alkali-ion conducting solid electrolyte. The cup-shaped solid electrolyte of beta-aluminum oxide is fastened at its open end in a force-locking manner by means of a joining material to an annular insulating body. The joining material contains a mixture of a glass powder and a ceramic powder suspended in a liquid with high viscosity.
摘要翻译： 具有碱金属和硫族元素型的电化学储存电池或电池，其阳极空间和阴极通过碱离子导电固体电解质彼此分离。 β-氧化铝的杯形固体电解质通过连接材料以一种力锁定的方式在其开口端固定到环形绝缘体上。 接合材料含有悬浮在高粘度液体中的玻璃粉末和陶瓷粉末的混合物。
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