公开(公告)号：US20050142445A1

公开(公告)日：2005-06-30

申请号：US11068880

申请日：2005-03-02

申请人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

发明人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

IPC分类号： C01G51/00 ,  H01M4/52 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/36 ,  H01M4/50 ,  C01G51/04

CPC分类号： H01M4/525 ,  B82Y30/00 ,  C01G51/42 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01B1/02 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  Y10T428/2991

摘要： The present invention relates to cobalt oxide particles useful as a precursor of a cathode active material for a non-aqueous electrolyte secondary cell which is capable of showing a stable crystal structure by insertion reaction therein, and producing a non-aqueous electrolyte secondary cell having a high safety and especially a high heat stability, a process for producing the cobalt oxide particles, a cathode active material for a non-aqueous electrolyte secondary cell using the cobalt oxide particles, a process for producing the cathode active material, and a non-aqueous electrolyte secondary cell using the cathode active material.

摘要翻译： 本发明涉及可用作非水电解质二次电池用正极活性物质的前体的氧化钴颗粒，其能够通过其中的插入反应显示出稳定的晶体结构，并且制备具有 高安全性，特别是高热稳定性，制造氧化钴颗粒的方法，使用氧化钴颗粒的非水电解质二次电池用正极活性物质，正极活性物质的制造方法和非水性 使用正极活性物质的电解质二次电池。

公开(公告)号：US07192539B2

公开(公告)日：2007-03-20

申请号：US11359394

申请日：2006-02-23

申请人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

发明人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

IPC分类号： H01B1/08

CPC分类号： H01M4/525 ,  B82Y30/00 ,  C01G51/42 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01B1/02 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  Y10T428/2991

摘要： The present invention relates to cobalt oxide particles useful as a precursor of a cathode active material for a non-aqueous electrolyte secondary cell which is capable of showing a stable crystal structure by insertion reaction therein, and producing a non-aqueous electrolyte secondary cell having a high safety and especially a high heat stability, a process for producing the cobalt oxide particles, a cathode active material for a non-aqueous electrolyte secondary cell using the cobalt oxide particles, a process for producing the cathode active material, and a non-aqueous electrolyte secondary cell using the cathode active material.

摘要翻译： 本发明涉及可用作非水电解质二次电池用正极活性物质的前体的氧化钴颗粒，其能够通过其中的插入反应显示出稳定的晶体结构，并且制备具有 高安全性，特别是高热稳定性，制造氧化钴颗粒的方法，使用氧化钴颗粒的非水电解质二次电池用正极活性物质，正极活性物质的制造方法和非水性 使用正极活性物质的电解质二次电池。

公开(公告)号：US06998071B2

公开(公告)日：2006-02-14

申请号：US10210178

申请日：2002-08-02

申请人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

发明人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

IPC分类号： H01B1/08 ,  C01D1/02 ,  C01F5/00 ,  H01M4/52

CPC分类号： H01M4/525 ,  B82Y30/00 ,  C01G51/42 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01B1/02 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  Y10T428/2991

摘要： The present invention relates to cobalt oxide particles useful as a precursor of a cathode active material for a non-aqueous electrolyte secondary cell which is capable of showing a stable crystal structure by insertion reaction therein, and producing a non-aqueous electrolyte secondary cell having a high safety and especially a high heat stability, a process for producing the cobalt oxide particles, a cathode active material for a non-aqueous electrolyte secondary cell using the cobalt oxide particles, a process for producing the cathode active material, and a non-aqueous electrolyte secondary cell using the cathode active material.

摘要翻译： 本发明涉及可用作非水电解质二次电池用正极活性物质的前体的氧化钴颗粒，其能够通过其中的插入反应显示出稳定的晶体结构，并且制备具有 高安全性，特别是高热稳定性，制造氧化钴颗粒的方法，使用氧化钴颗粒的非水电解质二次电池用正极活性物质，正极活性物质的制造方法和非水性 使用正极活性物质的电解质二次电池。

公开(公告)号：US20060138390A1

公开(公告)日：2006-06-29

申请号：US11359394

申请日：2006-02-23

申请人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

发明人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

IPC分类号： H01B1/02

CPC分类号： H01M4/525 ,  B82Y30/00 ,  C01G51/42 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01B1/02 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  Y10T428/2991

摘要： The present invention relates to cobalt oxide particles useful as a precursor of a cathode active material for a non-aqueous electrolyte secondary cell which is capable of showing a stable crystal structure by insertion reaction therein, and producing a non-aqueous electrolyte secondary cell having a high safety and especially a high heat stability, a process for producing the cobalt oxide particles, a cathode active material for a non-aqueous electrolyte secondary cell using the cobalt oxide particles, a process for producing the cathode active material, and a non-aqueous electrolyte secondary cell using the cathode active material.

公开(公告)号：US06756154B2

公开(公告)日：2004-06-29

申请号：US09994903

申请日：2001-11-28

申请人： Hideaki Maeda ,  Shoichi Fujino ,  Mitsuaki Hatatani ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

发明人： Hideaki Maeda ,  Shoichi Fujino ,  Mitsuaki Hatatani ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

IPC分类号： H01M458

CPC分类号： C01G45/1228 ,  B82Y30/00 ,  C01G51/44 ,  C01G51/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01M4/02 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/028

摘要： A cathode active material for a non-aqueous electrolyte secondary cell having a c-axis length of lattice constant of 14.080 to 14.160 Å, an average particle size of 0.1 to 5.0 &mgr;m, and a composition represented by the formula: LiCo(1−x−y)MnxMgyO2 wherein x is a number of 0.008 to 0.18; and y is a number of 0 to 0.18. This cathode active material is capable of maintaining an initial discharge capacity required for secondary cells and showing improved charge/discharge cycle characteristics under high temperature conditions.

摘要翻译： 一种用于非晶质常数为14.080〜14.160，平均粒径为0.1〜5.0μm的非水电解质二次电池用正极活性物质，由下式表示的组成：其中x为数 为0.008〜0.18; y为0〜0.18的数。 这种阴极活性材料能够保持二次电池所需的初始放电容量，并且在高温条件下显示改善的充电/放电循环特性。

公开(公告)号：US07112291B2

公开(公告)日：2006-09-26

申请号：US11068880

申请日：2005-03-02

申请人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

发明人： Hideaki Maeda ,  Shoichi Fujino ,  Hiroyasu Watanabe ,  Norimiki Sugiyama ,  Hideaki Sadamura

IPC分类号： H01B1/08 ,  C01G51/04 ,  C01F7/02

CPC分类号： H01M4/525 ,  B82Y30/00 ,  C01G51/42 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01B1/02 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  Y10T428/2991

摘要： The present invention relates to cobalt oxide particles useful as a precursor of a cathode active material for a non-aqueous electrolyte secondary cell which is capable of showing a stable crystal structure by insertion reaction therein, and producing a non-aqueous electrolyte secondary cell having a high safety and especially a high heat stability, a process for producing the cobalt oxide particles, a cathode active material for a non-aqueous electrolyte secondary cell using the cobalt oxide particles, a process for producing the cathode active material, and a non-aqueous electrolyte secondary cell using the cathode active material.

公开(公告)号：US10161057B2

公开(公告)日：2018-12-25

申请号：US14007732

申请日：2011-12-26

申请人： Hiroyasu Watanabe ,  Daisuke Morita ,  Manabu Yamamoto ,  Kazumichi Koga ,  Akihisa Kajiyama ,  Hiroaki Masukuni ,  Hideaki Sadamura ,  Ryuta Masaki ,  Kazutoshi Matsumoto

发明人： Hiroyasu Watanabe ,  Daisuke Morita ,  Manabu Yamamoto ,  Kazumichi Koga ,  Akihisa Kajiyama ,  Hiroaki Masukuni ,  Hideaki Sadamura ,  Ryuta Masaki ,  Kazutoshi Matsumoto

IPC分类号： H01M4/48 ,  H01M4/52 ,  H01M4/525 ,  C30B1/10 ,  C01G45/12 ,  C01G51/00 ,  C01G53/00 ,  H01M4/505 ,  C30B1/02

摘要： The present invention provides a precursor of positive electrode active substance particles for non-aqueous electrolyte secondary batteries which have a high discharge voltage and a high discharge capacity, hardly suffer from side reactions with an electrolyte solution, and are excellent in cycle characteristics, positive electrode active substance particles for non-aqueous electrolyte secondary batteries, and processes for producing these particles, and a non-aqueous electrolyte secondary battery. The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries having a spinel structure with a composition represented by the following chemical formula (1), in which the positive electrode active substance particles satisfy the following characteristic (A) and/or characteristic (B) when indexed with Fd−3m in X-ray diffraction thereof: (A) when indexed with Fd−3m in X-ray diffraction of the positive electrode active substance particles, a ratio of I(311) to I(111) [I(311)/I(111)] is in the range of 35 to 43%, and/or (B) when indexed with Fd−3m in X-ray diffraction of the positive electrode active substance particles, a gradient of a straight line determined by a least square method in a graph prepared by plotting sin θ in an abscissa thereof and B cos θ in an ordinate thereof wherein B is a full-width at half maximum with respect to each peak position 2θ (10 to 90°) is in the range of 3.0×10−4 to 20.0×10−4; and Li1+xMn2−y−zNiyMzO4  Chemical Formula (1) wherein x, y, z fall within the range of −0.05≤x≤0.15, 0.4≤y≤0.6 and 0≤z≤0.20, respectively; and M is at least one element selected from the group consisting of Mg, Al, Si, Ca, Ti, Co, Zn, Sb, Ba, W and Bi.

公开(公告)号：US09764962B2

公开(公告)日：2017-09-19

申请号：US14111590

申请日：2012-04-12

申请人： Taiki Imahashi ,  Hiroyasu Watanabe ,  Kazuhiko Kikuya ,  Hideaki Sadamura

发明人： Taiki Imahashi ,  Hiroyasu Watanabe ,  Kazuhiko Kikuya ,  Hideaki Sadamura

IPC分类号： H01M4/525 ,  C01D15/02 ,  H01M4/505 ,  C01G53/00

CPC分类号： C01D15/02 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/04 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/80 ,  H01M4/505 ,  H01M4/525

摘要： The present invention provides lithium composite compound particles having good high-temperature storage property and excellent cycle characteristics as an active substance for a non-aqueous electrolyte secondary battery, and a secondary battery using the lithium composite compound particles. The Li—Ni composite oxide particles for a non-aqueous electrolyte secondary battery according to the present invention have a BET specific surface area of 0.05 to 0.8 m2/g; an atomic ratio (Ma/Ni) of a concentration of an amphoteric metal to a concentration of Ni on an outermost surface of the respective Li—Ni composite oxide particles is 2 to 6; and the concentration of the amphoteric metal on the outermost surface of the respective Li—Ni composite oxide particles is higher than a concentration of the amphoteric metal at a position spaced by 50 nm from the outermost surface toward a center of the respective Li—Ni composite oxide particles.

公开(公告)号：US09455444B2

公开(公告)日：2016-09-27

申请号：US13132495

申请日：2009-12-03

申请人： Hiroyasu Watanabe ,  Taiki Imahashi ,  Kazuhiko Kikuya ,  Nobuyuki Tagami ,  Hideaki Sadamura

发明人： Hiroyasu Watanabe ,  Taiki Imahashi ,  Kazuhiko Kikuya ,  Nobuyuki Tagami ,  Hideaki Sadamura

IPC分类号： H01M4/525 ,  C01G53/00 ,  H01M4/1391 ,  H01M10/052 ,  H01M10/0566

CPC分类号： H01M4/525 ,  C01G53/42 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01M4/1391 ,  H01M10/052 ,  H01M10/0566 ,  Y02E60/122 ,  Y02P70/54

摘要： The present invention relates to lithium composite compound particles having a composition represented by the formula: Li1+xNi1−y−zCoyMzO2 (M=B or Al), wherein the lithium composite compound particles have an ionic strength ratio A (LiO−/NiO2−) of not more than 0.3 and an ionic strength ratio B (Li3CO3+/Ni+) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer. The lithium composite compound particles of the present invention can be used as a positive electrode active substance of a secondary battery which has good cycle characteristics and an excellent high-temperature storage property.

摘要翻译： 本发明涉及具有由式Li1 + xNi1-y-zCoyMzO2（M = B或Al）表示的组成的锂复合化合物颗粒，其中锂复合化合物颗粒具有离子强度比A（LiO- / NiO 2 - ）不超过0.3，离子强度比B（Li 3 CO 3 + / Ni +）不超过20，在使用飞行时间二次离子质谱仪的各种锂复合化合物颗粒的表面上测量。 本发明的锂复合化合物颗粒可以用作具有良好的循环特性和优异的高温保存性能的二次电池的正极活性物质。

公开(公告)号：US20140087262A1

公开(公告)日：2014-03-27

申请号：US14111590

申请日：2012-04-12

申请人： Taiki Imahashi ,  Hiroyasu Watanabe ,  Kazuhiko Kikuya ,  Hideaki Sadamura

发明人： Taiki Imahashi ,  Hiroyasu Watanabe ,  Kazuhiko Kikuya ,  Hideaki Sadamura

IPC分类号： H01M4/525 ,  C01D15/02

CPC分类号： C01D15/02 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/04 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/80 ,  H01M4/505 ,  H01M4/525

摘要： The present invention provides lithium composite compound particles having good high-temperature storage property and excellent cycle characteristics as an active substance for a non-aqueous electrolyte secondary battery, and a secondary battery using the lithium composite compound particles. The Li—Ni composite oxide particles for a non-aqueous electrolyte secondary battery according to the present invention have a BET specific surface area of 0.05 to 0.8 m2/g; an atomic ratio (Ma/Ni) of a concentration of an amphoteric metal to a concentration of Ni on an outermost surface of the respective Li—Ni composite oxide particles is 2 to 6; and the concentration of the amphoteric metal on the outermost surface of the respective Li—Ni composite oxide particles is higher than a concentration of the amphoteric metal at a position spaced by 50 nm from the outermost surface toward a center of the respective Li—Ni composite oxide particles.

摘要翻译： 本发明提供了作为非水电解质二次电池的活性物质和使用该锂复合化合物粒子的二次电池，具有良好的高温保存性和优异的循环特性的锂复合化合物粒子。 本发明的非水电解质二次电池用Li-Ni复合氧化物粒子的BET比表面积为0.05〜0.8m 2 / g， Li-Ni复合氧化物粒子的最外表面的两性金属的浓度相对于Ni的浓度的原子比（Ma / Ni）为2〜6， 并且各Li-Ni复合氧化物粒子的最表面上的两性金属的浓度高于距离最外表面朝向Li-Ni复合物的中心间隔50nm的位置处的两性金属的浓度 氧化物颗粒。